Evaluating the efficiency of nano-sized Cu doped TiO2/ZnO photocatalyst under visible light irradiation

A visible light responsive photocatalyst, nano-sized copper doped TiO2/ZnO, was synthesized by sol gel method. It was characterized in terms of thermal stability, crystalline phase, crystal size, morphology, surface area, UV–Vis DRS and band gap. The results showed that the synergistic effect of cop...

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Main Authors: Delsouz Khaki, Mohammad Reza, Shafeeyan, Mohammad Saleh, Abdul Raman, Abdul Aziz, Daud, Wan Mohd Ashri Wan
Format: Article
Published: Elsevier 2018
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Online Access:http://eprints.um.edu.my/22151/
https://doi.org/10.1016/j.molliq.2017.11.030
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spelling my.um.eprints.221512019-08-30T03:59:39Z http://eprints.um.edu.my/22151/ Evaluating the efficiency of nano-sized Cu doped TiO2/ZnO photocatalyst under visible light irradiation Delsouz Khaki, Mohammad Reza Shafeeyan, Mohammad Saleh Abdul Raman, Abdul Aziz Daud, Wan Mohd Ashri Wan TP Chemical technology A visible light responsive photocatalyst, nano-sized copper doped TiO2/ZnO, was synthesized by sol gel method. It was characterized in terms of thermal stability, crystalline phase, crystal size, morphology, surface area, UV–Vis DRS and band gap. The results showed that the synergistic effect of copper ions considerably narrowed the band gap of the synthesized photocatalyst compared to TiO2/ZnO. Its photoactivity was then evaluated by measuring degradation efficiency of methyl orange (MO) and methylene blue (MB) in terms of colour, COD and TOC removal. The synergistic or antagonistic effects of different combinations of dye and catalyst concentrations, pH, intensity of light irradiation and reaction time on photoactivity of Cu-TiO2/ZnO were also investigated. The highest photoactivity achieved was 85.45% of colour, 70.56% of COD and 48.70% of TOC removal for MO and 73.20% of colour, 59.92% of COD and 38.77% of TOC removal for MB under optimal conditions. Elsevier 2018 Article PeerReviewed Delsouz Khaki, Mohammad Reza and Shafeeyan, Mohammad Saleh and Abdul Raman, Abdul Aziz and Daud, Wan Mohd Ashri Wan (2018) Evaluating the efficiency of nano-sized Cu doped TiO2/ZnO photocatalyst under visible light irradiation. Journal of Molecular Liquids, 258. pp. 354-365. ISSN 0167-7322 https://doi.org/10.1016/j.molliq.2017.11.030 doi:10.1016/j.molliq.2017.11.030
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic TP Chemical technology
spellingShingle TP Chemical technology
Delsouz Khaki, Mohammad Reza
Shafeeyan, Mohammad Saleh
Abdul Raman, Abdul Aziz
Daud, Wan Mohd Ashri Wan
Evaluating the efficiency of nano-sized Cu doped TiO2/ZnO photocatalyst under visible light irradiation
description A visible light responsive photocatalyst, nano-sized copper doped TiO2/ZnO, was synthesized by sol gel method. It was characterized in terms of thermal stability, crystalline phase, crystal size, morphology, surface area, UV–Vis DRS and band gap. The results showed that the synergistic effect of copper ions considerably narrowed the band gap of the synthesized photocatalyst compared to TiO2/ZnO. Its photoactivity was then evaluated by measuring degradation efficiency of methyl orange (MO) and methylene blue (MB) in terms of colour, COD and TOC removal. The synergistic or antagonistic effects of different combinations of dye and catalyst concentrations, pH, intensity of light irradiation and reaction time on photoactivity of Cu-TiO2/ZnO were also investigated. The highest photoactivity achieved was 85.45% of colour, 70.56% of COD and 48.70% of TOC removal for MO and 73.20% of colour, 59.92% of COD and 38.77% of TOC removal for MB under optimal conditions.
format Article
author Delsouz Khaki, Mohammad Reza
Shafeeyan, Mohammad Saleh
Abdul Raman, Abdul Aziz
Daud, Wan Mohd Ashri Wan
author_facet Delsouz Khaki, Mohammad Reza
Shafeeyan, Mohammad Saleh
Abdul Raman, Abdul Aziz
Daud, Wan Mohd Ashri Wan
author_sort Delsouz Khaki, Mohammad Reza
title Evaluating the efficiency of nano-sized Cu doped TiO2/ZnO photocatalyst under visible light irradiation
title_short Evaluating the efficiency of nano-sized Cu doped TiO2/ZnO photocatalyst under visible light irradiation
title_full Evaluating the efficiency of nano-sized Cu doped TiO2/ZnO photocatalyst under visible light irradiation
title_fullStr Evaluating the efficiency of nano-sized Cu doped TiO2/ZnO photocatalyst under visible light irradiation
title_full_unstemmed Evaluating the efficiency of nano-sized Cu doped TiO2/ZnO photocatalyst under visible light irradiation
title_sort evaluating the efficiency of nano-sized cu doped tio2/zno photocatalyst under visible light irradiation
publisher Elsevier
publishDate 2018
url http://eprints.um.edu.my/22151/
https://doi.org/10.1016/j.molliq.2017.11.030
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score 13.211869