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Syntheses, crystal structures, and luminescent properties of three metal coordination polymers based on adipic acid and 2-(pyridine-3-yl)-(1H)-benzimidazole

Three new metal coordination polymers constructed from adipic acid and 2-(pyridin-3-yl)-(1H)-benzimidazole ligands, [M(ADP)(3PBI)2(H2O)2]·2H2O (M = Ni and Co for 1 and 2, respectively) and [Cd(ADP)(3PBI)(H2O)] (3) [ADP = adipic acid dianion; 3PBI = 2-(pyridin-3-yl)-(1H)-benzimidazole], have been syn...

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Main Authors:	Wang, C.C., Wang, J.H., Tang, G.M., Wang, Y.T., Cui, Y.Z., Ng, S.W.
Format:	Article
Published:	Taylor & Francis 2015
Subjects:	QD Chemistry TP Chemical technology
Online Access:	http://eprints.um.edu.my/19477/ http://dx.doi.org/10.1080/00958972.2015.1084418
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spelling	my.um.eprints.194772018-09-28T08:32:56Z http://eprints.um.edu.my/19477/ Syntheses, crystal structures, and luminescent properties of three metal coordination polymers based on adipic acid and 2-(pyridine-3-yl)-(1H)-benzimidazole Wang, C.C. Wang, J.H. Tang, G.M. Wang, Y.T. Cui, Y.Z. Ng, S.W. QD Chemistry TP Chemical technology Three new metal coordination polymers constructed from adipic acid and 2-(pyridin-3-yl)-(1H)-benzimidazole ligands, [M(ADP)(3PBI)2(H2O)2]·2H2O (M = Ni and Co for 1 and 2, respectively) and [Cd(ADP)(3PBI)(H2O)] (3) [ADP = adipic acid dianion; 3PBI = 2-(pyridin-3-yl)-(1H)-benzimidazole], have been synthesized by hydrothermal reactions and were characterized by X-ray single-crystal diffraction, elemental analyses, IR, powder X-ray diffraction, and thermogravimetry. Complexes 1 and 2 are isostructural. Both form a 1-D linear chain structure, which is further assembled into a 3-D supramolecular framework by ππ stacking and hydrogen bonding interactions. Complex 3 possesses a binuclear unit and displays a 2-D layer which is further extended to a 3-D supramolecular architecture via hydrogen bonding and other weak packing interactions. The luminescent properties of 3 were investigated in the solid state at room temperature. Taylor & Francis 2015 Article PeerReviewed Wang, C.C. and Wang, J.H. and Tang, G.M. and Wang, Y.T. and Cui, Y.Z. and Ng, S.W. (2015) Syntheses, crystal structures, and luminescent properties of three metal coordination polymers based on adipic acid and 2-(pyridine-3-yl)-(1H)-benzimidazole. Journal of Coordination Chemistry, 68 (21). pp. 3918-3931. ISSN 0095-8972 http://dx.doi.org/10.1080/00958972.2015.1084418 doi:10.1080/00958972.2015.1084418
institution	Universiti Malaya
building	UM Library
collection	Institutional Repository
continent	Asia
country	Malaysia
content_provider	Universiti Malaya
content_source	UM Research Repository
url_provider	http://eprints.um.edu.my/
topic	QD Chemistry TP Chemical technology
spellingShingle	QD Chemistry TP Chemical technology Wang, C.C. Wang, J.H. Tang, G.M. Wang, Y.T. Cui, Y.Z. Ng, S.W. Syntheses, crystal structures, and luminescent properties of three metal coordination polymers based on adipic acid and 2-(pyridine-3-yl)-(1H)-benzimidazole
description	Three new metal coordination polymers constructed from adipic acid and 2-(pyridin-3-yl)-(1H)-benzimidazole ligands, [M(ADP)(3PBI)2(H2O)2]·2H2O (M = Ni and Co for 1 and 2, respectively) and [Cd(ADP)(3PBI)(H2O)] (3) [ADP = adipic acid dianion; 3PBI = 2-(pyridin-3-yl)-(1H)-benzimidazole], have been synthesized by hydrothermal reactions and were characterized by X-ray single-crystal diffraction, elemental analyses, IR, powder X-ray diffraction, and thermogravimetry. Complexes 1 and 2 are isostructural. Both form a 1-D linear chain structure, which is further assembled into a 3-D supramolecular framework by ππ stacking and hydrogen bonding interactions. Complex 3 possesses a binuclear unit and displays a 2-D layer which is further extended to a 3-D supramolecular architecture via hydrogen bonding and other weak packing interactions. The luminescent properties of 3 were investigated in the solid state at room temperature.
format	Article
author	Wang, C.C. Wang, J.H. Tang, G.M. Wang, Y.T. Cui, Y.Z. Ng, S.W.
author_facet	Wang, C.C. Wang, J.H. Tang, G.M. Wang, Y.T. Cui, Y.Z. Ng, S.W.
author_sort	Wang, C.C.
title	Syntheses, crystal structures, and luminescent properties of three metal coordination polymers based on adipic acid and 2-(pyridine-3-yl)-(1H)-benzimidazole
title_short	Syntheses, crystal structures, and luminescent properties of three metal coordination polymers based on adipic acid and 2-(pyridine-3-yl)-(1H)-benzimidazole
title_full	Syntheses, crystal structures, and luminescent properties of three metal coordination polymers based on adipic acid and 2-(pyridine-3-yl)-(1H)-benzimidazole
title_fullStr	Syntheses, crystal structures, and luminescent properties of three metal coordination polymers based on adipic acid and 2-(pyridine-3-yl)-(1H)-benzimidazole
title_full_unstemmed	Syntheses, crystal structures, and luminescent properties of three metal coordination polymers based on adipic acid and 2-(pyridine-3-yl)-(1H)-benzimidazole
title_sort	syntheses, crystal structures, and luminescent properties of three metal coordination polymers based on adipic acid and 2-(pyridine-3-yl)-(1h)-benzimidazole
publisher	Taylor & Francis
publishDate	2015
url	http://eprints.um.edu.my/19477/ http://dx.doi.org/10.1080/00958972.2015.1084418
_version_	1643690999981015040
score	13.211869

Syntheses, crystal structures, and luminescent properties of three metal coordination polymers based on adipic acid and 2-(pyridine-3-yl)-(1H)-benzimidazole

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