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Dimethyltin dichloride-dibenzyl sulfoxide, a compound crystallizing with seven molecules in the asymmetric unit

Dimethyltin dichloride dibenzyl sulfoxide, ((CH(3))(2)SnCl(2)center dot O=S(CH(2)C(6)H(5))(2)), crystallizes in the orthorhombic space group P2(1)2(1)2(1) with a superstructure of. dimensions a = 11.9290(1), b = 19.50490(1), c = 55.7390(6) angstrom; Z = 28. The geometry of the five-coordinated tin a...

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Main Author: Ng, S.W.
Format: Article
Published: Chinese Journal Structural Chemistry 2010
Subjects:
Q Science (General)
Online Access:http://eprints.um.edu.my/15361/
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spelling my.um.eprints.153612015-12-28T08:41:18Z http://eprints.um.edu.my/15361/ Dimethyltin dichloride-dibenzyl sulfoxide, a compound crystallizing with seven molecules in the asymmetric unit Ng, S.W. Q Science (General) Dimethyltin dichloride dibenzyl sulfoxide, ((CH(3))(2)SnCl(2)center dot O=S(CH(2)C(6)H(5))(2)), crystallizes in the orthorhombic space group P2(1)2(1)2(1) with a superstructure of. dimensions a = 11.9290(1), b = 19.50490(1), c = 55.7390(6) angstrom; Z = 28. The geometry of the five-coordinated tin atom in each of the seven independent adduct molecules is a square pyramid that is displaced towards a cis-trigonal bipyramid; the extent of displacement along the Berry pseudorotation pathway ranges from 20 to 45%. Chinese Journal Structural Chemistry 2010 Article PeerReviewed Ng, S.W. (2010) Dimethyltin dichloride-dibenzyl sulfoxide, a compound crystallizing with seven molecules in the asymmetric unit. Chinese Journal of Structural Chemistry, 29 (10). pp. 1584-1586.
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic Q Science (General)
spellingShingle Q Science (General)
Ng, S.W.
Dimethyltin dichloride-dibenzyl sulfoxide, a compound crystallizing with seven molecules in the asymmetric unit
description Dimethyltin dichloride dibenzyl sulfoxide, ((CH(3))(2)SnCl(2)center dot O=S(CH(2)C(6)H(5))(2)), crystallizes in the orthorhombic space group P2(1)2(1)2(1) with a superstructure of. dimensions a = 11.9290(1), b = 19.50490(1), c = 55.7390(6) angstrom; Z = 28. The geometry of the five-coordinated tin atom in each of the seven independent adduct molecules is a square pyramid that is displaced towards a cis-trigonal bipyramid; the extent of displacement along the Berry pseudorotation pathway ranges from 20 to 45%.
format Article
author Ng, S.W.
author_facet Ng, S.W.
author_sort Ng, S.W.
title Dimethyltin dichloride-dibenzyl sulfoxide, a compound crystallizing with seven molecules in the asymmetric unit
title_short Dimethyltin dichloride-dibenzyl sulfoxide, a compound crystallizing with seven molecules in the asymmetric unit
title_full Dimethyltin dichloride-dibenzyl sulfoxide, a compound crystallizing with seven molecules in the asymmetric unit
title_fullStr Dimethyltin dichloride-dibenzyl sulfoxide, a compound crystallizing with seven molecules in the asymmetric unit
title_full_unstemmed Dimethyltin dichloride-dibenzyl sulfoxide, a compound crystallizing with seven molecules in the asymmetric unit
title_sort dimethyltin dichloride-dibenzyl sulfoxide, a compound crystallizing with seven molecules in the asymmetric unit
publisher Chinese Journal Structural Chemistry
publishDate 2010
url http://eprints.um.edu.my/15361/
_version_ 1643690038487154688
score 13.211869

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