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Artificial hydrogenases: Assembly of an H-cluster analogue within a functionalised poly(pyrrole) matrix

We show that a redox active {Fe(4)S(4)}(2+)-cubane assembly covalently bound within a cysteinyl-alkylammonium functionalised polypyrrole can be modified with a diiron dithiolate carbonyl unit to give an artificial hydrogenase H-cluster framework confined within the polymer matrix.

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Main Authors: Ibrahim, S., Woi, P.M., Alias, Y., Pickett, C.J.
Format: Article
Published: Royal Society of Chemistry 2010
Subjects:
R Medicine
Online Access:http://eprints.um.edu.my/15354/
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spelling my.um.eprints.153542017-07-03T08:57:31Z http://eprints.um.edu.my/15354/ Artificial hydrogenases: Assembly of an H-cluster analogue within a functionalised poly(pyrrole) matrix Ibrahim, S. Woi, P.M. Alias, Y. Pickett, C.J. R Medicine We show that a redox active {Fe(4)S(4)}(2+)-cubane assembly covalently bound within a cysteinyl-alkylammonium functionalised polypyrrole can be modified with a diiron dithiolate carbonyl unit to give an artificial hydrogenase H-cluster framework confined within the polymer matrix. Royal Society of Chemistry 2010 Article PeerReviewed Ibrahim, S. and Woi, P.M. and Alias, Y. and Pickett, C.J. (2010) Artificial hydrogenases: Assembly of an H-cluster analogue within a functionalised poly(pyrrole) matrix. Chemical Communications, 46 (43). pp. 8189-8191.
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic R Medicine
spellingShingle R Medicine
Ibrahim, S.
Woi, P.M.
Alias, Y.
Pickett, C.J.
Artificial hydrogenases: Assembly of an H-cluster analogue within a functionalised poly(pyrrole) matrix
description We show that a redox active {Fe(4)S(4)}(2+)-cubane assembly covalently bound within a cysteinyl-alkylammonium functionalised polypyrrole can be modified with a diiron dithiolate carbonyl unit to give an artificial hydrogenase H-cluster framework confined within the polymer matrix.
format Article
author Ibrahim, S.
Woi, P.M.
Alias, Y.
Pickett, C.J.
author_facet Ibrahim, S.
Woi, P.M.
Alias, Y.
Pickett, C.J.
author_sort Ibrahim, S.
title Artificial hydrogenases: Assembly of an H-cluster analogue within a functionalised poly(pyrrole) matrix
title_short Artificial hydrogenases: Assembly of an H-cluster analogue within a functionalised poly(pyrrole) matrix
title_full Artificial hydrogenases: Assembly of an H-cluster analogue within a functionalised poly(pyrrole) matrix
title_fullStr Artificial hydrogenases: Assembly of an H-cluster analogue within a functionalised poly(pyrrole) matrix
title_full_unstemmed Artificial hydrogenases: Assembly of an H-cluster analogue within a functionalised poly(pyrrole) matrix
title_sort artificial hydrogenases: assembly of an h-cluster analogue within a functionalised poly(pyrrole) matrix
publisher Royal Society of Chemistry
publishDate 2010
url http://eprints.um.edu.my/15354/
_version_ 1643690036760150016
score 13.211869

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