Bis(mu-4-hydroxybenzoato-kappa O-2:O `)bis[triaquabis(4-hydroxybenzoato)-kappa O;kappa O-2,O `-terbium(III)] decahydrate
The title dinuclear compound, [Tb-2(C7H5O3)(6)(H2O)(6)]center dot 10H(2)O, lies on a center of inversion and the two Tb-III atoms are bridged by two 4-hydroxybenzoate anions; each metal atom is further coordinated by one monodentate anion and chelated by the third anion. The eight-coordinate geometr...
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my.um.eprints.152822019-01-30T08:15:49Z http://eprints.um.edu.my/15282/ Bis(mu-4-hydroxybenzoato-kappa O-2:O `)bis[triaquabis(4-hydroxybenzoato)-kappa O;kappa O-2,O `-terbium(III)] decahydrate Zhu, Y.M. Feng, P.P. Yang, Y.Y. Ng, S.W. Q Science (General) The title dinuclear compound, [Tb-2(C7H5O3)(6)(H2O)(6)]center dot 10H(2)O, lies on a center of inversion and the two Tb-III atoms are bridged by two 4-hydroxybenzoate anions; each metal atom is further coordinated by one monodentate anion and chelated by the third anion. The eight-coordinate geometry approximates a square antiprism. Hydrogen bonds of the O-H center dot center dot center dot O type connect the uncoordinated water molecules to the dinuclear species, forming a three-dimensional network. International Union of Crystallography 2010 Article PeerReviewed Zhu, Y.M. and Feng, P.P. and Yang, Y.Y. and Ng, S.W. (2010) Bis(mu-4-hydroxybenzoato-kappa O-2:O `)bis[triaquabis(4-hydroxybenzoato)-kappa O;kappa O-2,O `-terbium(III)] decahydrate. Acta Crystallographica Section E: Structure Reports Online, 66 (1). M54-U617. ISSN 1600-5368 |
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Q Science (General) Zhu, Y.M. Feng, P.P. Yang, Y.Y. Ng, S.W. Bis(mu-4-hydroxybenzoato-kappa O-2:O `)bis[triaquabis(4-hydroxybenzoato)-kappa O;kappa O-2,O `-terbium(III)] decahydrate |
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The title dinuclear compound, [Tb-2(C7H5O3)(6)(H2O)(6)]center dot 10H(2)O, lies on a center of inversion and the two Tb-III atoms are bridged by two 4-hydroxybenzoate anions; each metal atom is further coordinated by one monodentate anion and chelated by the third anion. The eight-coordinate geometry approximates a square antiprism. Hydrogen bonds of the O-H center dot center dot center dot O type connect the uncoordinated water molecules to the dinuclear species, forming a three-dimensional network. |
format |
Article |
author |
Zhu, Y.M. Feng, P.P. Yang, Y.Y. Ng, S.W. |
author_facet |
Zhu, Y.M. Feng, P.P. Yang, Y.Y. Ng, S.W. |
author_sort |
Zhu, Y.M. |
title |
Bis(mu-4-hydroxybenzoato-kappa O-2:O `)bis[triaquabis(4-hydroxybenzoato)-kappa O;kappa O-2,O `-terbium(III)] decahydrate |
title_short |
Bis(mu-4-hydroxybenzoato-kappa O-2:O `)bis[triaquabis(4-hydroxybenzoato)-kappa O;kappa O-2,O `-terbium(III)] decahydrate |
title_full |
Bis(mu-4-hydroxybenzoato-kappa O-2:O `)bis[triaquabis(4-hydroxybenzoato)-kappa O;kappa O-2,O `-terbium(III)] decahydrate |
title_fullStr |
Bis(mu-4-hydroxybenzoato-kappa O-2:O `)bis[triaquabis(4-hydroxybenzoato)-kappa O;kappa O-2,O `-terbium(III)] decahydrate |
title_full_unstemmed |
Bis(mu-4-hydroxybenzoato-kappa O-2:O `)bis[triaquabis(4-hydroxybenzoato)-kappa O;kappa O-2,O `-terbium(III)] decahydrate |
title_sort |
bis(mu-4-hydroxybenzoato-kappa o-2:o `)bis[triaquabis(4-hydroxybenzoato)-kappa o;kappa o-2,o `-terbium(iii)] decahydrate |
publisher |
International Union of Crystallography |
publishDate |
2010 |
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http://eprints.um.edu.my/15282/ |
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1643690020462133248 |
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13.211869 |