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1,5-Bis[(E)-1-(2-hydroxyphenyl)ethylidene]thiocarbonohydrazide monohydrate

In the title compound, C17H18N4O2S center dot H2O, the thiourea derivative is almost planar, with an r.m.s. deviation for the non-H atoms of 0.057 angstrom. The hydroxyl groups lie to the same side of the molecule as the thione S atom, a conformation that allows the formation of intramolecular O-H c...

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Main Authors: Abu Affan, M., Chee, D.N.A., Ahmad, F.B., Tiekink, E.R.T.
Format: Article
Published: International Union of Crystallography 2010
Subjects:
QC Physics
Online Access:http://eprints.um.edu.my/15016/
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spelling my.um.eprints.150162019-01-31T01:37:54Z http://eprints.um.edu.my/15016/ 1,5-Bis[(E)-1-(2-hydroxyphenyl)ethylidene]thiocarbonohydrazide monohydrate Abu Affan, M. Chee, D.N.A. Ahmad, F.B. Tiekink, E.R.T. QC Physics In the title compound, C17H18N4O2S center dot H2O, the thiourea derivative is almost planar, with an r.m.s. deviation for the non-H atoms of 0.057 angstrom. The hydroxyl groups lie to the same side of the molecule as the thione S atom, a conformation that allows the formation of intramolecular O-H center dot center dot center dot S and O-H center dot center dot center dot N hydrogen bonds. In the crystal structure, the thiourea and water molecules self-assemble into a two-dimensional array by a combination of O-(water)-H center dot center dot center dot O-hydroxyl, N-H center dot center dot center dot O-water and O-water-H center dot center dot center dot S hydrogen bonds and C-H center dot center dot center dot pi interactions. International Union of Crystallography 2010 Article PeerReviewed Abu Affan, M. and Chee, D.N.A. and Ahmad, F.B. and Tiekink, E.R.T. (2010) 1,5-Bis[(E)-1-(2-hydroxyphenyl)ethylidene]thiocarbonohydrazide monohydrate. Acta Crystallographica Section E: Structure Reports Online, 66 (3). O555-U4471. ISSN 1600-5368
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic QC Physics
spellingShingle QC Physics
Abu Affan, M.
Chee, D.N.A.
Ahmad, F.B.
Tiekink, E.R.T.
1,5-Bis[(E)-1-(2-hydroxyphenyl)ethylidene]thiocarbonohydrazide monohydrate
description In the title compound, C17H18N4O2S center dot H2O, the thiourea derivative is almost planar, with an r.m.s. deviation for the non-H atoms of 0.057 angstrom. The hydroxyl groups lie to the same side of the molecule as the thione S atom, a conformation that allows the formation of intramolecular O-H center dot center dot center dot S and O-H center dot center dot center dot N hydrogen bonds. In the crystal structure, the thiourea and water molecules self-assemble into a two-dimensional array by a combination of O-(water)-H center dot center dot center dot O-hydroxyl, N-H center dot center dot center dot O-water and O-water-H center dot center dot center dot S hydrogen bonds and C-H center dot center dot center dot pi interactions.
format Article
author Abu Affan, M.
Chee, D.N.A.
Ahmad, F.B.
Tiekink, E.R.T.
author_facet Abu Affan, M.
Chee, D.N.A.
Ahmad, F.B.
Tiekink, E.R.T.
author_sort Abu Affan, M.
title 1,5-Bis[(E)-1-(2-hydroxyphenyl)ethylidene]thiocarbonohydrazide monohydrate
title_short 1,5-Bis[(E)-1-(2-hydroxyphenyl)ethylidene]thiocarbonohydrazide monohydrate
title_full 1,5-Bis[(E)-1-(2-hydroxyphenyl)ethylidene]thiocarbonohydrazide monohydrate
title_fullStr 1,5-Bis[(E)-1-(2-hydroxyphenyl)ethylidene]thiocarbonohydrazide monohydrate
title_full_unstemmed 1,5-Bis[(E)-1-(2-hydroxyphenyl)ethylidene]thiocarbonohydrazide monohydrate
title_sort 1,5-bis[(e)-1-(2-hydroxyphenyl)ethylidene]thiocarbonohydrazide monohydrate
publisher International Union of Crystallography
publishDate 2010
url http://eprints.um.edu.my/15016/
_version_ 1643689957089345536
score 13.211869

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