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Decaaqua-1 kappa O-5,4 kappa O-5-bis(mu-nitrilotriacetate)-1:2 kappa O-5:N,O `,O `',O `'';3:4 kappa N-5,O,O `,O `':O `''-mu-oxido-2:3 kappa O-2:O-diperoxido-2 kappa O-2,O `;3 kappa O-2,O `-1,4-dicopper(II)-2,3-dititanium(IV) heptahydrate

The tetranuclear title compound, [Cu2Ti2(C6H6NO6)(2)O(O-2)(2)(H2O)(10)]center dot 7H(2)O, lies about a twofold rotation axis that passes through the bridging oxide atom. The titanium atom is N,O,O',O `'-chelated by the nitrilotriacetate and O,O'-chelated by the peroidxo group and is c...

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Main Authors: Xie, X.H., Wang, B.M., Ng, S.W.
Format: Article
Published: International Union of Crystallography 2010
Subjects:
QC Physics
Online Access:http://eprints.um.edu.my/15015/
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spelling my.um.eprints.150152019-01-30T08:29:11Z http://eprints.um.edu.my/15015/ Decaaqua-1 kappa O-5,4 kappa O-5-bis(mu-nitrilotriacetate)-1:2 kappa O-5:N,O `,O `',O `'';3:4 kappa N-5,O,O `,O `':O `''-mu-oxido-2:3 kappa O-2:O-diperoxido-2 kappa O-2,O `;3 kappa O-2,O `-1,4-dicopper(II)-2,3-dititanium(IV) heptahydrate Xie, X.H. Wang, B.M. Ng, S.W. QC Physics The tetranuclear title compound, [Cu2Ti2(C6H6NO6)(2)O(O-2)(2)(H2O)(10)]center dot 7H(2)O, lies about a twofold rotation axis that passes through the bridging oxide atom. The titanium atom is N,O,O',O `'-chelated by the nitrilotriacetate and O,O'-chelated by the peroidxo group and is coordinated to the bridging O atom in an overall pentagonal-bipyramidal geometry. The O atom of one of the carboxylate -CO2 groups binds to the water-coordinated Cu atom, whose coordination polyhedron is an elongated octahedron. Adjacent tetranuclear molecules are linked through the coordinated and uncoordinated water molecules by O-H center dot center dot center dot O hydrogen bonds into a three-dimensional network. International Union of Crystallography 2010 Article PeerReviewed Xie, X.H. and Wang, B.M. and Ng, S.W. (2010) Decaaqua-1 kappa O-5,4 kappa O-5-bis(mu-nitrilotriacetate)-1:2 kappa O-5:N,O `,O `',O `'';3:4 kappa N-5,O,O `,O `':O `''-mu-oxido-2:3 kappa O-2:O-diperoxido-2 kappa O-2,O `;3 kappa O-2,O `-1,4-dicopper(II)-2,3-dititanium(IV) heptahydrate. Acta Crystallographica Section E: Structure Reports Online, 66 (3). M271-U3287. ISSN 1600-5368
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic QC Physics
spellingShingle QC Physics
Xie, X.H.
Wang, B.M.
Ng, S.W.
Decaaqua-1 kappa O-5,4 kappa O-5-bis(mu-nitrilotriacetate)-1:2 kappa O-5:N,O `,O `',O `'';3:4 kappa N-5,O,O `,O `':O `''-mu-oxido-2:3 kappa O-2:O-diperoxido-2 kappa O-2,O `;3 kappa O-2,O `-1,4-dicopper(II)-2,3-dititanium(IV) heptahydrate
description The tetranuclear title compound, [Cu2Ti2(C6H6NO6)(2)O(O-2)(2)(H2O)(10)]center dot 7H(2)O, lies about a twofold rotation axis that passes through the bridging oxide atom. The titanium atom is N,O,O',O `'-chelated by the nitrilotriacetate and O,O'-chelated by the peroidxo group and is coordinated to the bridging O atom in an overall pentagonal-bipyramidal geometry. The O atom of one of the carboxylate -CO2 groups binds to the water-coordinated Cu atom, whose coordination polyhedron is an elongated octahedron. Adjacent tetranuclear molecules are linked through the coordinated and uncoordinated water molecules by O-H center dot center dot center dot O hydrogen bonds into a three-dimensional network.
format Article
author Xie, X.H.
Wang, B.M.
Ng, S.W.
author_facet Xie, X.H.
Wang, B.M.
Ng, S.W.
author_sort Xie, X.H.
title Decaaqua-1 kappa O-5,4 kappa O-5-bis(mu-nitrilotriacetate)-1:2 kappa O-5:N,O `,O `',O `'';3:4 kappa N-5,O,O `,O `':O `''-mu-oxido-2:3 kappa O-2:O-diperoxido-2 kappa O-2,O `;3 kappa O-2,O `-1,4-dicopper(II)-2,3-dititanium(IV) heptahydrate
title_short Decaaqua-1 kappa O-5,4 kappa O-5-bis(mu-nitrilotriacetate)-1:2 kappa O-5:N,O `,O `',O `'';3:4 kappa N-5,O,O `,O `':O `''-mu-oxido-2:3 kappa O-2:O-diperoxido-2 kappa O-2,O `;3 kappa O-2,O `-1,4-dicopper(II)-2,3-dititanium(IV) heptahydrate
title_full Decaaqua-1 kappa O-5,4 kappa O-5-bis(mu-nitrilotriacetate)-1:2 kappa O-5:N,O `,O `',O `'';3:4 kappa N-5,O,O `,O `':O `''-mu-oxido-2:3 kappa O-2:O-diperoxido-2 kappa O-2,O `;3 kappa O-2,O `-1,4-dicopper(II)-2,3-dititanium(IV) heptahydrate
title_fullStr Decaaqua-1 kappa O-5,4 kappa O-5-bis(mu-nitrilotriacetate)-1:2 kappa O-5:N,O `,O `',O `'';3:4 kappa N-5,O,O `,O `':O `''-mu-oxido-2:3 kappa O-2:O-diperoxido-2 kappa O-2,O `;3 kappa O-2,O `-1,4-dicopper(II)-2,3-dititanium(IV) heptahydrate
title_full_unstemmed Decaaqua-1 kappa O-5,4 kappa O-5-bis(mu-nitrilotriacetate)-1:2 kappa O-5:N,O `,O `',O `'';3:4 kappa N-5,O,O `,O `':O `''-mu-oxido-2:3 kappa O-2:O-diperoxido-2 kappa O-2,O `;3 kappa O-2,O `-1,4-dicopper(II)-2,3-dititanium(IV) heptahydrate
title_sort decaaqua-1 kappa o-5,4 kappa o-5-bis(mu-nitrilotriacetate)-1:2 kappa o-5:n,o `,o `',o `'';3:4 kappa n-5,o,o `,o `':o `''-mu-oxido-2:3 kappa o-2:o-diperoxido-2 kappa o-2,o `;3 kappa o-2,o `-1,4-dicopper(ii)-2,3-dititanium(iv) heptahydrate
publisher International Union of Crystallography
publishDate 2010
url http://eprints.um.edu.my/15015/
_version_ 1643689956803084288
score 13.211869

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