Kinetics and mechanism of tertiary amine-catalyzed cleavage of N `-morpholino-N-(2 `-methoxyphenyl)phthalamide: Kinetic evidence for the presence of a reactive intermediate on the reaction path
Pseudo-first-order rate constants (k(obs)) for tertiary amine (DABCO and Me(3)N) buffer-catalyzed cyclization of N'-morpholino-N-(2'-methoxyphenyl)phthalamide (1) to N-(2'-methoxyphenyl)phthalimide (2) reveal saturation (nonlinear) plots of k(obs) versus vertical bar Buf vertical bar(...
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| Main Authors: | , |
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| Format: | Article |
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John Wiley & Sons
2010
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| Online Access: | http://eprints.um.edu.my/14713/ |
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