Kinetics of superoxide ion in dimethyl sulfoxide containing ionic liquids
The chemical generation of superoxide ion (O-2 (aEuro cent a')) by dissolving potassium superoxide was investigated. The chemically generated O-2 (aEuro cent a') was then used to study the long-term stability of O-2 (aEuro cent a') in dimethyl sulfoxide (DMSO) containing ionic liquids...
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| التنسيق: | مقال |
| اللغة: | English |
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Springer Verlag (Germany)
2015
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| الوصول للمادة أونلاين: | http://eprints.um.edu.my/14014/1/Kinetics_of_superoxide_ion_in_dimethyl_sulfoxide_containing_ionic.pdf http://eprints.um.edu.my/14014/ http://link.springer.com/article/10.1007%2Fs11581-014-1224-y |
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my.um.eprints.140142015-09-01T08:06:59Z http://eprints.um.edu.my/14014/ Kinetics of superoxide ion in dimethyl sulfoxide containing ionic liquids Hayyan, M. Hashim, M.A. AlNashef, I.M. T Technology (General) TA Engineering (General). Civil engineering (General) TP Chemical technology The chemical generation of superoxide ion (O-2 (aEuro cent a')) by dissolving potassium superoxide was investigated. The chemically generated O-2 (aEuro cent a') was then used to study the long-term stability of O-2 (aEuro cent a') in dimethyl sulfoxide (DMSO) containing ionic liquids (ILs) and determine the rate constants based on pseudo 1st- and 2nd-order reactions between the IL and O-2 (aEuro cent a') generated in DMSO. O-2 (aEuro cent a') was unstable in DMSO containing S-222TFSI, DMImMS, BDMImTfO, EMImTFSI, EMImMS, P-14,P-666TPTP, P-14,P-666TFSI, and all pyridinium-based ILs. In contrast, O-2 (aEuro cent a') was very stable in DMSO containing MOPMPipTFSI, BMPyrrDCA, BMPyrrTFSI, BMPyrrTfO, HMPyrrTFSI, MOEMPipTPTP, BMPyrrTFA, N-112,1O(2)TFSI, and MOEMMorTFSI. This shows that these ILs can be used for different applications involving O-2 (aEuro cent a'). The reaction rate constant, total consumption, and consumption rate of O-2 (aEuro cent a') were determined. The rate constants of O-2 (aEuro cent a') in some ILs were found to follow pseudo 1st-order reaction, while in others, pseudo 2nd-order reaction kinetics were observed. Springer Verlag (Germany) 2015-03 Article PeerReviewed application/pdf en http://eprints.um.edu.my/14014/1/Kinetics_of_superoxide_ion_in_dimethyl_sulfoxide_containing_ionic.pdf Hayyan, M. and Hashim, M.A. and AlNashef, I.M. (2015) Kinetics of superoxide ion in dimethyl sulfoxide containing ionic liquids. Ionics, 21 (3). pp. 719-728. ISSN 0947-7047 http://link.springer.com/article/10.1007%2Fs11581-014-1224-y DOI: 10.1007/s11581-014-1224-y |
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| language |
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| topic |
T Technology (General) TA Engineering (General). Civil engineering (General) TP Chemical technology |
| spellingShingle |
T Technology (General) TA Engineering (General). Civil engineering (General) TP Chemical technology Hayyan, M. Hashim, M.A. AlNashef, I.M. Kinetics of superoxide ion in dimethyl sulfoxide containing ionic liquids |
| description |
The chemical generation of superoxide ion (O-2 (aEuro cent a')) by dissolving potassium superoxide was investigated. The chemically generated O-2 (aEuro cent a') was then used to study the long-term stability of O-2 (aEuro cent a') in dimethyl sulfoxide (DMSO) containing ionic liquids (ILs) and determine the rate constants based on pseudo 1st- and 2nd-order reactions between the IL and O-2 (aEuro cent a') generated in DMSO. O-2 (aEuro cent a') was unstable in DMSO containing S-222TFSI, DMImMS, BDMImTfO, EMImTFSI, EMImMS, P-14,P-666TPTP, P-14,P-666TFSI, and all pyridinium-based ILs. In contrast, O-2 (aEuro cent a') was very stable in DMSO containing MOPMPipTFSI, BMPyrrDCA, BMPyrrTFSI, BMPyrrTfO, HMPyrrTFSI, MOEMPipTPTP, BMPyrrTFA, N-112,1O(2)TFSI, and MOEMMorTFSI. This shows that these ILs can be used for different applications involving O-2 (aEuro cent a'). The reaction rate constant, total consumption, and consumption rate of O-2 (aEuro cent a') were determined. The rate constants of O-2 (aEuro cent a') in some ILs were found to follow pseudo 1st-order reaction, while in others, pseudo 2nd-order reaction kinetics were observed. |
| format |
Article |
| author |
Hayyan, M. Hashim, M.A. AlNashef, I.M. |
| author_facet |
Hayyan, M. Hashim, M.A. AlNashef, I.M. |
| author_sort |
Hayyan, M. |
| title |
Kinetics of superoxide ion in dimethyl sulfoxide containing ionic liquids |
| title_short |
Kinetics of superoxide ion in dimethyl sulfoxide containing ionic liquids |
| title_full |
Kinetics of superoxide ion in dimethyl sulfoxide containing ionic liquids |
| title_fullStr |
Kinetics of superoxide ion in dimethyl sulfoxide containing ionic liquids |
| title_full_unstemmed |
Kinetics of superoxide ion in dimethyl sulfoxide containing ionic liquids |
| title_sort |
kinetics of superoxide ion in dimethyl sulfoxide containing ionic liquids |
| publisher |
Springer Verlag (Germany) |
| publishDate |
2015 |
| url |
http://eprints.um.edu.my/14014/1/Kinetics_of_superoxide_ion_in_dimethyl_sulfoxide_containing_ionic.pdf http://eprints.um.edu.my/14014/ http://link.springer.com/article/10.1007%2Fs11581-014-1224-y |
| _version_ |
1643689711992045568 |
| score |
13.250246 |