Kinetics of superoxide ion in dimethyl sulfoxide containing ionic liquids

The chemical generation of superoxide ion (O-2 (aEuro cent a')) by dissolving potassium superoxide was investigated. The chemically generated O-2 (aEuro cent a') was then used to study the long-term stability of O-2 (aEuro cent a') in dimethyl sulfoxide (DMSO) containing ionic liquids...

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Main Authors: Hayyan, M., Hashim, M.A., AlNashef, I.M.
格式: Article
语言:English
出版: Springer Verlag (Germany) 2015
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在线阅读:http://eprints.um.edu.my/14014/1/Kinetics_of_superoxide_ion_in_dimethyl_sulfoxide_containing_ionic.pdf
http://eprints.um.edu.my/14014/
http://link.springer.com/article/10.1007%2Fs11581-014-1224-y
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spelling my.um.eprints.140142015-09-01T08:06:59Z http://eprints.um.edu.my/14014/ Kinetics of superoxide ion in dimethyl sulfoxide containing ionic liquids Hayyan, M. Hashim, M.A. AlNashef, I.M. T Technology (General) TA Engineering (General). Civil engineering (General) TP Chemical technology The chemical generation of superoxide ion (O-2 (aEuro cent a')) by dissolving potassium superoxide was investigated. The chemically generated O-2 (aEuro cent a') was then used to study the long-term stability of O-2 (aEuro cent a') in dimethyl sulfoxide (DMSO) containing ionic liquids (ILs) and determine the rate constants based on pseudo 1st- and 2nd-order reactions between the IL and O-2 (aEuro cent a') generated in DMSO. O-2 (aEuro cent a') was unstable in DMSO containing S-222TFSI, DMImMS, BDMImTfO, EMImTFSI, EMImMS, P-14,P-666TPTP, P-14,P-666TFSI, and all pyridinium-based ILs. In contrast, O-2 (aEuro cent a') was very stable in DMSO containing MOPMPipTFSI, BMPyrrDCA, BMPyrrTFSI, BMPyrrTfO, HMPyrrTFSI, MOEMPipTPTP, BMPyrrTFA, N-112,1O(2)TFSI, and MOEMMorTFSI. This shows that these ILs can be used for different applications involving O-2 (aEuro cent a'). The reaction rate constant, total consumption, and consumption rate of O-2 (aEuro cent a') were determined. The rate constants of O-2 (aEuro cent a') in some ILs were found to follow pseudo 1st-order reaction, while in others, pseudo 2nd-order reaction kinetics were observed. Springer Verlag (Germany) 2015-03 Article PeerReviewed application/pdf en http://eprints.um.edu.my/14014/1/Kinetics_of_superoxide_ion_in_dimethyl_sulfoxide_containing_ionic.pdf Hayyan, M. and Hashim, M.A. and AlNashef, I.M. (2015) Kinetics of superoxide ion in dimethyl sulfoxide containing ionic liquids. Ionics, 21 (3). pp. 719-728. ISSN 0947-7047 http://link.springer.com/article/10.1007%2Fs11581-014-1224-y DOI: 10.1007/s11581-014-1224-y
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
language English
topic T Technology (General)
TA Engineering (General). Civil engineering (General)
TP Chemical technology
spellingShingle T Technology (General)
TA Engineering (General). Civil engineering (General)
TP Chemical technology
Hayyan, M.
Hashim, M.A.
AlNashef, I.M.
Kinetics of superoxide ion in dimethyl sulfoxide containing ionic liquids
description The chemical generation of superoxide ion (O-2 (aEuro cent a')) by dissolving potassium superoxide was investigated. The chemically generated O-2 (aEuro cent a') was then used to study the long-term stability of O-2 (aEuro cent a') in dimethyl sulfoxide (DMSO) containing ionic liquids (ILs) and determine the rate constants based on pseudo 1st- and 2nd-order reactions between the IL and O-2 (aEuro cent a') generated in DMSO. O-2 (aEuro cent a') was unstable in DMSO containing S-222TFSI, DMImMS, BDMImTfO, EMImTFSI, EMImMS, P-14,P-666TPTP, P-14,P-666TFSI, and all pyridinium-based ILs. In contrast, O-2 (aEuro cent a') was very stable in DMSO containing MOPMPipTFSI, BMPyrrDCA, BMPyrrTFSI, BMPyrrTfO, HMPyrrTFSI, MOEMPipTPTP, BMPyrrTFA, N-112,1O(2)TFSI, and MOEMMorTFSI. This shows that these ILs can be used for different applications involving O-2 (aEuro cent a'). The reaction rate constant, total consumption, and consumption rate of O-2 (aEuro cent a') were determined. The rate constants of O-2 (aEuro cent a') in some ILs were found to follow pseudo 1st-order reaction, while in others, pseudo 2nd-order reaction kinetics were observed.
format Article
author Hayyan, M.
Hashim, M.A.
AlNashef, I.M.
author_facet Hayyan, M.
Hashim, M.A.
AlNashef, I.M.
author_sort Hayyan, M.
title Kinetics of superoxide ion in dimethyl sulfoxide containing ionic liquids
title_short Kinetics of superoxide ion in dimethyl sulfoxide containing ionic liquids
title_full Kinetics of superoxide ion in dimethyl sulfoxide containing ionic liquids
title_fullStr Kinetics of superoxide ion in dimethyl sulfoxide containing ionic liquids
title_full_unstemmed Kinetics of superoxide ion in dimethyl sulfoxide containing ionic liquids
title_sort kinetics of superoxide ion in dimethyl sulfoxide containing ionic liquids
publisher Springer Verlag (Germany)
publishDate 2015
url http://eprints.um.edu.my/14014/1/Kinetics_of_superoxide_ion_in_dimethyl_sulfoxide_containing_ionic.pdf
http://eprints.um.edu.my/14014/
http://link.springer.com/article/10.1007%2Fs11581-014-1224-y
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score 13.250246