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catena-Poly[[tris(4-fluorobenzyl)tin(IV)]-mu-2-[(piperidin-1-yl)ca rbothioylsulfanyl]acetato-kappa O-2/O `]

Adjacent units of the title polymeric complex, [Sn(C7H6F)(3)(C8H12NO2S2)], are bridged by the carboxylate ion into a helical chain running along the b axis. The Sn(IV) atom shows a distorted trans-C3SnO2 trigonal-bipyramidal coordination and is displaced by 0.113 (2) A out of the C3Sn girdle in the...

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Main Authors: Keng, C.T., Lo, K.M., Ng, S.W.
Format: Article
Published: International Union of Crystallography 2010
Subjects:
Q Science (General)
Online Access:http://eprints.um.edu.my/12532/
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spelling my.um.eprints.125322019-01-31T04:30:27Z http://eprints.um.edu.my/12532/ catena-Poly[[tris(4-fluorobenzyl)tin(IV)]-mu-2-[(piperidin-1-yl)ca rbothioylsulfanyl]acetato-kappa O-2/O `] Keng, C.T. Lo, K.M. Ng, S.W. Q Science (General) Adjacent units of the title polymeric complex, [Sn(C7H6F)(3)(C8H12NO2S2)], are bridged by the carboxylate ion into a helical chain running along the b axis. The Sn(IV) atom shows a distorted trans-C3SnO2 trigonal-bipyramidal coordination and is displaced by 0.113 (2) A out of the C3Sn girdle in the direction of the covalently bonded O atom. The ring is disordered of two positions with an occupancy of 0.631 (4) for the major occupied site. International Union of Crystallography 2010 Article PeerReviewed Keng, C.T. and Lo, K.M. and Ng, S.W. (2010) catena-Poly[[tris(4-fluorobenzyl)tin(IV)]-mu-2-[(piperidin-1-yl)ca rbothioylsulfanyl]acetato-kappa O-2/O `]. Acta Crystallographica Section E: Structure Reports Online, 66 (8). M978-U1100. ISSN 1600-5368
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic Q Science (General)
spellingShingle Q Science (General)
Keng, C.T.
Lo, K.M.
Ng, S.W.
catena-Poly[[tris(4-fluorobenzyl)tin(IV)]-mu-2-[(piperidin-1-yl)ca rbothioylsulfanyl]acetato-kappa O-2/O `]
description Adjacent units of the title polymeric complex, [Sn(C7H6F)(3)(C8H12NO2S2)], are bridged by the carboxylate ion into a helical chain running along the b axis. The Sn(IV) atom shows a distorted trans-C3SnO2 trigonal-bipyramidal coordination and is displaced by 0.113 (2) A out of the C3Sn girdle in the direction of the covalently bonded O atom. The ring is disordered of two positions with an occupancy of 0.631 (4) for the major occupied site.
format Article
author Keng, C.T.
Lo, K.M.
Ng, S.W.
author_facet Keng, C.T.
Lo, K.M.
Ng, S.W.
author_sort Keng, C.T.
title catena-Poly[[tris(4-fluorobenzyl)tin(IV)]-mu-2-[(piperidin-1-yl)ca rbothioylsulfanyl]acetato-kappa O-2/O `]
title_short catena-Poly[[tris(4-fluorobenzyl)tin(IV)]-mu-2-[(piperidin-1-yl)ca rbothioylsulfanyl]acetato-kappa O-2/O `]
title_full catena-Poly[[tris(4-fluorobenzyl)tin(IV)]-mu-2-[(piperidin-1-yl)ca rbothioylsulfanyl]acetato-kappa O-2/O `]
title_fullStr catena-Poly[[tris(4-fluorobenzyl)tin(IV)]-mu-2-[(piperidin-1-yl)ca rbothioylsulfanyl]acetato-kappa O-2/O `]
title_full_unstemmed catena-Poly[[tris(4-fluorobenzyl)tin(IV)]-mu-2-[(piperidin-1-yl)ca rbothioylsulfanyl]acetato-kappa O-2/O `]
title_sort catena-poly[[tris(4-fluorobenzyl)tin(iv)]-mu-2-[(piperidin-1-yl)ca rbothioylsulfanyl]acetato-kappa o-2/o `]
publisher International Union of Crystallography
publishDate 2010
url http://eprints.um.edu.my/12532/
_version_ 1643689318251757568
score 13.211869

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