Poly[(mu(3)-4-carboxypyridine-3-carboxylato-kappa N-3:O-3:O-4)(triphenylphosphine-kappa P)silver(I)]
In the title 1:1 silver(I) 4-carboxypyridine-3-carboxylate adduct with triphenylphosphine, [Ag(C7H4NO4)(C18H15P)](n), the carboxylate anion bridges the phosphine-coordinated Ag atoms through its N and O atoms, generating a coordination polymer forming layers in the bc plane. The Ag atom exists in a...
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| Main Authors: | , , |
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| Format: | Article |
| Published: |
International Union of Crystallography
2010
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| Subjects: | |
| Online Access: | http://eprints.um.edu.my/12416/ |
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| Summary: | In the title 1:1 silver(I) 4-carboxypyridine-3-carboxylate adduct with triphenylphosphine, [Ag(C7H4NO4)(C18H15P)](n), the carboxylate anion bridges the phosphine-coordinated Ag atoms through its N and O atoms, generating a coordination polymer forming layers in the bc plane. The Ag atom exists in a distorted tetrahedral geometry. The H atom of the carboxylate is midway between two O atoms of the two carboxyl groups, thus forming a strong intramolecular hydrogen bond. |
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