Tetra-mu-acetato-kappa O-8:O `-bis{[N-(4-chlorophenyl)-4-methylpyridin-2-amine-kappa N-1]-copper(II)}
In the crystal structure of the title complex, [Cu-2(CH3COO)(4)(-)( C12H11ClN2)(2)], the complete binuclear molecule is generated by a crystallographic centre of inversion; the four acetate groups each bridge a pair of Cu-II atoms. The coordination of the metal atom is distorted octahedral within a...
Saved in:
| Main Authors: | , , , , |
|---|---|
| 格式: | Article |
| 出版: |
International Union of Crystallography
2010
|
| 主題: | |
| 在線閱讀: | http://eprints.um.edu.my/12410/ |
| 標簽: |
添加標簽
沒有標簽, 成為第一個標記此記錄!
|
| 總結: | In the crystal structure of the title complex, [Cu-2(CH3COO)(4)(-)( C12H11ClN2)(2)], the complete binuclear molecule is generated by a crystallographic centre of inversion; the four acetate groups each bridge a pair of Cu-II atoms. The coordination of the metal atom is distorted octahedral within a donor set defined by four O atoms, the heterocyclic N atom and the second Cu atom. The pyridine ring is twisted with respect to the benzene ring, forming a dihedral angle of 33.9 (2)degrees. An intramolecular N-H center dot center dot center dot O hydrogen bond is present between the amino group and a carboxyl O atom. Intermolecular interactions of the C-H center dot center dot center dot pi type link molecules in the crystal structure. |
|---|