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Aquachlorido{2-[2-(cyclohexylcarbamothioyl-kappa S)hydrazinylidene-kappa N-1]propanoato(2-)}phenyltin(IV)

In the title organotin compound, [Sn(C6H5)(C10H15N3O2S) Cl(H2O)], the Sn atom is coordinated by the S, O, and imine N atoms of the dinegative tridentate ligand, a chloride ligand, the ipso-C atom of a phenyl ligand and by a water molecule in a distorted octahedral coordination environment. Coordinat...

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Main Authors: Abu Affan, M., Salam, M.A., Jusoh, I., Ng, S.W., Tiekink, E.R.T.
Format: Article
Published: International Union of Crystallography 2010
Subjects:
Q Science (General)
Online Access:http://eprints.um.edu.my/12405/
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spelling my.um.eprints.124052019-01-31T01:38:44Z http://eprints.um.edu.my/12405/ Aquachlorido{2-[2-(cyclohexylcarbamothioyl-kappa S)hydrazinylidene-kappa N-1]propanoato(2-)}phenyltin(IV) Abu Affan, M. Salam, M.A. Jusoh, I. Ng, S.W. Tiekink, E.R.T. Q Science (General) In the title organotin compound, [Sn(C6H5)(C10H15N3O2S) Cl(H2O)], the Sn atom is coordinated by the S, O, and imine N atoms of the dinegative tridentate ligand, a chloride ligand, the ipso-C atom of a phenyl ligand and by a water molecule in a distorted octahedral coordination environment. Coordinated water molecules link the organotin molecules by forming O-H center dot center dot center dot O hydrogen bonds with both carbonyl and carboxylate O atoms, leading to 12-membered {center dot center dot center dot OCO center dot center dot center dot HOH center dot center dot center dot}(2) synthons. This results in the formation of supramolecular chains along the c axis. The chains pack in the ac plane and stack along the b axis with links between layers afforded by N-H center dot center dot center dot Cl hydrogen bonds. International Union of Crystallography 2010 Article PeerReviewed Abu Affan, M. and Salam, M.A. and Jusoh, I. and Ng, S.W. and Tiekink, E.R.T. (2010) Aquachlorido{2-[2-(cyclohexylcarbamothioyl-kappa S)hydrazinylidene-kappa N-1]propanoato(2-)}phenyltin(IV). Acta Crystallographica Section E: Structure Reports Online, 66 (9). M1112-U670. ISSN 1600-5368
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic Q Science (General)
spellingShingle Q Science (General)
Abu Affan, M.
Salam, M.A.
Jusoh, I.
Ng, S.W.
Tiekink, E.R.T.
Aquachlorido{2-[2-(cyclohexylcarbamothioyl-kappa S)hydrazinylidene-kappa N-1]propanoato(2-)}phenyltin(IV)
description In the title organotin compound, [Sn(C6H5)(C10H15N3O2S) Cl(H2O)], the Sn atom is coordinated by the S, O, and imine N atoms of the dinegative tridentate ligand, a chloride ligand, the ipso-C atom of a phenyl ligand and by a water molecule in a distorted octahedral coordination environment. Coordinated water molecules link the organotin molecules by forming O-H center dot center dot center dot O hydrogen bonds with both carbonyl and carboxylate O atoms, leading to 12-membered {center dot center dot center dot OCO center dot center dot center dot HOH center dot center dot center dot}(2) synthons. This results in the formation of supramolecular chains along the c axis. The chains pack in the ac plane and stack along the b axis with links between layers afforded by N-H center dot center dot center dot Cl hydrogen bonds.
format Article
author Abu Affan, M.
Salam, M.A.
Jusoh, I.
Ng, S.W.
Tiekink, E.R.T.
author_facet Abu Affan, M.
Salam, M.A.
Jusoh, I.
Ng, S.W.
Tiekink, E.R.T.
author_sort Abu Affan, M.
title Aquachlorido{2-[2-(cyclohexylcarbamothioyl-kappa S)hydrazinylidene-kappa N-1]propanoato(2-)}phenyltin(IV)
title_short Aquachlorido{2-[2-(cyclohexylcarbamothioyl-kappa S)hydrazinylidene-kappa N-1]propanoato(2-)}phenyltin(IV)
title_full Aquachlorido{2-[2-(cyclohexylcarbamothioyl-kappa S)hydrazinylidene-kappa N-1]propanoato(2-)}phenyltin(IV)
title_fullStr Aquachlorido{2-[2-(cyclohexylcarbamothioyl-kappa S)hydrazinylidene-kappa N-1]propanoato(2-)}phenyltin(IV)
title_full_unstemmed Aquachlorido{2-[2-(cyclohexylcarbamothioyl-kappa S)hydrazinylidene-kappa N-1]propanoato(2-)}phenyltin(IV)
title_sort aquachlorido{2-[2-(cyclohexylcarbamothioyl-kappa s)hydrazinylidene-kappa n-1]propanoato(2-)}phenyltin(iv)
publisher International Union of Crystallography
publishDate 2010
url http://eprints.um.edu.my/12405/
_version_ 1643689289120219136
score 13.211869

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