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[2,6-Bis(p-tolyliminomethyl)pyridine-kappa N-3,N `,N `']dichloridocopper(II)

The title compound, [CuCl2(C21H19N3)], lies on a twofold rotation axis that passes through the N-pyridyl-Cu bond; this symmetry element relates one half of the organic ligand to the other as well as one Cl ligand to the other. The three N atoms span the axial-equatorial-axial sites of the trigonal-b...

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Main Authors: Li, Xiao-Ping, Zhao, Jian-She, Ng, S.W.
Format: Article
Published: International Union of Crystallography 2010
Subjects:
Q Science (General)
Online Access:http://eprints.um.edu.my/12196/
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spelling my.um.eprints.121962019-01-31T04:39:01Z http://eprints.um.edu.my/12196/ [2,6-Bis(p-tolyliminomethyl)pyridine-kappa N-3,N `,N `']dichloridocopper(II) Li, Xiao-Ping Zhao, Jian-She Ng, S.W. Q Science (General) The title compound, [CuCl2(C21H19N3)], lies on a twofold rotation axis that passes through the N-pyridyl-Cu bond; this symmetry element relates one half of the organic ligand to the other as well as one Cl ligand to the other. The three N atoms span the axial-equatorial-axial sites of the trigonal-bipyramidal coordination polyhedron; the geometry of the Cu-II atom is 31% distorted from trigonal-bipyramidal (towards square-pyramidal along the Berry pseudorotation pathway). International Union of Crystallography 2010 Article PeerReviewed Li, Xiao-Ping and Zhao, Jian-She and Ng, S.W. (2010) [2,6-Bis(p-tolyliminomethyl)pyridine-kappa N-3,N `,N `']dichloridocopper(II). Acta Crystallographica Section E: Structure Reports Online, 66 (10). M1297-U1175. ISSN 1600-5368
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic Q Science (General)
spellingShingle Q Science (General)
Li, Xiao-Ping
Zhao, Jian-She
Ng, S.W.
[2,6-Bis(p-tolyliminomethyl)pyridine-kappa N-3,N `,N `']dichloridocopper(II)
description The title compound, [CuCl2(C21H19N3)], lies on a twofold rotation axis that passes through the N-pyridyl-Cu bond; this symmetry element relates one half of the organic ligand to the other as well as one Cl ligand to the other. The three N atoms span the axial-equatorial-axial sites of the trigonal-bipyramidal coordination polyhedron; the geometry of the Cu-II atom is 31% distorted from trigonal-bipyramidal (towards square-pyramidal along the Berry pseudorotation pathway).
format Article
author Li, Xiao-Ping
Zhao, Jian-She
Ng, S.W.
author_facet Li, Xiao-Ping
Zhao, Jian-She
Ng, S.W.
author_sort Li, Xiao-Ping
title [2,6-Bis(p-tolyliminomethyl)pyridine-kappa N-3,N `,N `']dichloridocopper(II)
title_short [2,6-Bis(p-tolyliminomethyl)pyridine-kappa N-3,N `,N `']dichloridocopper(II)
title_full [2,6-Bis(p-tolyliminomethyl)pyridine-kappa N-3,N `,N `']dichloridocopper(II)
title_fullStr [2,6-Bis(p-tolyliminomethyl)pyridine-kappa N-3,N `,N `']dichloridocopper(II)
title_full_unstemmed [2,6-Bis(p-tolyliminomethyl)pyridine-kappa N-3,N `,N `']dichloridocopper(II)
title_sort [2,6-bis(p-tolyliminomethyl)pyridine-kappa n-3,n `,n `']dichloridocopper(ii)
publisher International Union of Crystallography
publishDate 2010
url http://eprints.um.edu.my/12196/
_version_ 1643689243219853312
score 13.211869

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