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Bis(2-aminopyrimidine-[kappa]N1)aqua(nitrato-[kappa]O)(nitrato-[kappa]2O,O')zinc(II)

The water-coordinated Zn atom in the title monoaqua zinc nitrate adduct of 2-aminopyrimidine, [Zn(NO3)(2)(C4H5N3)(2)-(H2O)], is bonded to a monodentate nitrate ion and is chelated by the other nitrate ion. The heterocyclic ligands coordinate through ring N-donor sites. The coordination geometry abou...

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Main Authors: Gao, S., Ng, S.W.
Format: Article
Published: International Union of Crystallography 2010
Subjects:
Q Science (General)
Online Access:http://eprints.um.edu.my/12192/
http://journals.iucr.org/e/issues/2010/10/00/jh2204/jh2204bdy.html
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spelling my.um.eprints.121922015-01-20T04:43:16Z http://eprints.um.edu.my/12192/ Bis(2-aminopyrimidine-[kappa]N1)aqua(nitrato-[kappa]O)(nitrato-[kappa]2O,O')zinc(II) Gao, S. Ng, S.W. Q Science (General) The water-coordinated Zn atom in the title monoaqua zinc nitrate adduct of 2-aminopyrimidine, [Zn(NO3)(2)(C4H5N3)(2)-(H2O)], is bonded to a monodentate nitrate ion and is chelated by the other nitrate ion. The heterocyclic ligands coordinate through ring N-donor sites. The coordination geometry about the Zn(II) atom is a distorted octahedron. Intramolecular N-H center dot center dot center dot O hydrogen bonds occur. In the crystal, adjacent adduct molecules are linked by O- H center dot center dot center dot O, O-H center dot center dot center dot N and N-H center dot center dot center dot O hydrogen bonds into a layer motif parallel to ( 001). International Union of Crystallography 2010 Article PeerReviewed Gao, S. and Ng, S.W. (2010) Bis(2-aminopyrimidine-[kappa]N1)aqua(nitrato-[kappa]O)(nitrato-[kappa]2O,O')zinc(II). Acta Crystallographica Section E: Structure Reports Online, 66 (10). M1279-U1034. ISSN 1600-5368 http://journals.iucr.org/e/issues/2010/10/00/jh2204/jh2204bdy.html
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic Q Science (General)
spellingShingle Q Science (General)
Gao, S.
Ng, S.W.
Bis(2-aminopyrimidine-[kappa]N1)aqua(nitrato-[kappa]O)(nitrato-[kappa]2O,O')zinc(II)
description The water-coordinated Zn atom in the title monoaqua zinc nitrate adduct of 2-aminopyrimidine, [Zn(NO3)(2)(C4H5N3)(2)-(H2O)], is bonded to a monodentate nitrate ion and is chelated by the other nitrate ion. The heterocyclic ligands coordinate through ring N-donor sites. The coordination geometry about the Zn(II) atom is a distorted octahedron. Intramolecular N-H center dot center dot center dot O hydrogen bonds occur. In the crystal, adjacent adduct molecules are linked by O- H center dot center dot center dot O, O-H center dot center dot center dot N and N-H center dot center dot center dot O hydrogen bonds into a layer motif parallel to ( 001).
format Article
author Gao, S.
Ng, S.W.
author_facet Gao, S.
Ng, S.W.
author_sort Gao, S.
title Bis(2-aminopyrimidine-[kappa]N1)aqua(nitrato-[kappa]O)(nitrato-[kappa]2O,O')zinc(II)
title_short Bis(2-aminopyrimidine-[kappa]N1)aqua(nitrato-[kappa]O)(nitrato-[kappa]2O,O')zinc(II)
title_full Bis(2-aminopyrimidine-[kappa]N1)aqua(nitrato-[kappa]O)(nitrato-[kappa]2O,O')zinc(II)
title_fullStr Bis(2-aminopyrimidine-[kappa]N1)aqua(nitrato-[kappa]O)(nitrato-[kappa]2O,O')zinc(II)
title_full_unstemmed Bis(2-aminopyrimidine-[kappa]N1)aqua(nitrato-[kappa]O)(nitrato-[kappa]2O,O')zinc(II)
title_sort bis(2-aminopyrimidine-[kappa]n1)aqua(nitrato-[kappa]o)(nitrato-[kappa]2o,o')zinc(ii)
publisher International Union of Crystallography
publishDate 2010
url http://eprints.um.edu.my/12192/
http://journals.iucr.org/e/issues/2010/10/00/jh2204/jh2204bdy.html
_version_ 1643689241355485184
score 13.211869

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