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3-Hydroxy-2-[(2-hydroxy-4,4-dimethyl-6-oxocyclohex-1-en-1-yl)(3-nitrop henyl)methyl]-5,5-dimethylcyclohex-2-en-1-one

Each of the cyclohexenone rings in the title compound, C23H27NO6, adopts a half-chair (envelope) conformation with the C atom carrying the methyl groups lying out of the plane defined by the five remaining C atoms; the O atoms lie to the same side of the molecule as the respective >C(CH3)(2) atom...

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Main Authors: Reddy, B.P., Vijayakumar, V., Sarveswari, S., Ng, S.W., Tiekink, E.R.T.
Format: Article
Published: International Union of Crystallography 2010
Subjects:
Q Science (General)
Online Access:http://eprints.um.edu.my/12035/
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spelling my.um.eprints.120352019-01-31T05:17:13Z http://eprints.um.edu.my/12035/ 3-Hydroxy-2-[(2-hydroxy-4,4-dimethyl-6-oxocyclohex-1-en-1-yl)(3-nitrop henyl)methyl]-5,5-dimethylcyclohex-2-en-1-one Reddy, B.P. Vijayakumar, V. Sarveswari, S. Ng, S.W. Tiekink, E.R.T. Q Science (General) Each of the cyclohexenone rings in the title compound, C23H27NO6, adopts a half-chair (envelope) conformation with the C atom carrying the methyl groups lying out of the plane defined by the five remaining C atoms; the O atoms lie to the same side of the molecule as the respective >C(CH3)(2) atoms. The hydroxy and carbonyl O atoms face each other and are orientated to allow for the formation of two intramolecular O-H center dot center dot center dot O hydrogen bonds. In the crystal, the presence of C-H center dot center dot center dot O contacts leads to the formation of supramolecular chains along the b axis. These aggregate into layers that stack along c. International Union of Crystallography 2010 Article PeerReviewed Reddy, B.P. and Vijayakumar, V. and Sarveswari, S. and Ng, S.W. and Tiekink, E.R.T. (2010) 3-Hydroxy-2-[(2-hydroxy-4,4-dimethyl-6-oxocyclohex-1-en-1-yl)(3-nitrop henyl)methyl]-5,5-dimethylcyclohex-2-en-1-one. Acta Crystallographica Section E: Structure Reports Online, 66 (11). O2806-U120. ISSN 1600-5368
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic Q Science (General)
spellingShingle Q Science (General)
Reddy, B.P.
Vijayakumar, V.
Sarveswari, S.
Ng, S.W.
Tiekink, E.R.T.
3-Hydroxy-2-[(2-hydroxy-4,4-dimethyl-6-oxocyclohex-1-en-1-yl)(3-nitrop henyl)methyl]-5,5-dimethylcyclohex-2-en-1-one
description Each of the cyclohexenone rings in the title compound, C23H27NO6, adopts a half-chair (envelope) conformation with the C atom carrying the methyl groups lying out of the plane defined by the five remaining C atoms; the O atoms lie to the same side of the molecule as the respective >C(CH3)(2) atoms. The hydroxy and carbonyl O atoms face each other and are orientated to allow for the formation of two intramolecular O-H center dot center dot center dot O hydrogen bonds. In the crystal, the presence of C-H center dot center dot center dot O contacts leads to the formation of supramolecular chains along the b axis. These aggregate into layers that stack along c.
format Article
author Reddy, B.P.
Vijayakumar, V.
Sarveswari, S.
Ng, S.W.
Tiekink, E.R.T.
author_facet Reddy, B.P.
Vijayakumar, V.
Sarveswari, S.
Ng, S.W.
Tiekink, E.R.T.
author_sort Reddy, B.P.
title 3-Hydroxy-2-[(2-hydroxy-4,4-dimethyl-6-oxocyclohex-1-en-1-yl)(3-nitrop henyl)methyl]-5,5-dimethylcyclohex-2-en-1-one
title_short 3-Hydroxy-2-[(2-hydroxy-4,4-dimethyl-6-oxocyclohex-1-en-1-yl)(3-nitrop henyl)methyl]-5,5-dimethylcyclohex-2-en-1-one
title_full 3-Hydroxy-2-[(2-hydroxy-4,4-dimethyl-6-oxocyclohex-1-en-1-yl)(3-nitrop henyl)methyl]-5,5-dimethylcyclohex-2-en-1-one
title_fullStr 3-Hydroxy-2-[(2-hydroxy-4,4-dimethyl-6-oxocyclohex-1-en-1-yl)(3-nitrop henyl)methyl]-5,5-dimethylcyclohex-2-en-1-one
title_full_unstemmed 3-Hydroxy-2-[(2-hydroxy-4,4-dimethyl-6-oxocyclohex-1-en-1-yl)(3-nitrop henyl)methyl]-5,5-dimethylcyclohex-2-en-1-one
title_sort 3-hydroxy-2-[(2-hydroxy-4,4-dimethyl-6-oxocyclohex-1-en-1-yl)(3-nitrop henyl)methyl]-5,5-dimethylcyclohex-2-en-1-one
publisher International Union of Crystallography
publishDate 2010
url http://eprints.um.edu.my/12035/
_version_ 1643689203811221504
score 13.211869

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