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(2-Carboxyacetato-kappa O-2(1),O-1 `)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-kappa N-4,N `,N `',N `'')nickel(II) perchlorate acetonitrile solvate

In the crystal structure of the title salt, [Ni(C3H3O4)-(C16H36N4)]ClO4 center dot CH3CN, the macrocycle folds around the Ni-II atom, which is also chelated by the carboxylate monoanion. The geometry is a distorted NiN4O2 octahedron. The formula units are connected by N-H center dot center dot cente...

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Main Authors: Ou, Guang-Chuan, Ng, S.W.
Format: Article
Published: International Union of Crystallography 2010
Subjects:
Q Science (General)
Online Access:http://eprints.um.edu.my/11997/
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spelling my.um.eprints.119972019-01-31T05:10:59Z http://eprints.um.edu.my/11997/ (2-Carboxyacetato-kappa O-2(1),O-1 `)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-kappa N-4,N `,N `',N `'')nickel(II) perchlorate acetonitrile solvate Ou, Guang-Chuan Ng, S.W. Q Science (General) In the crystal structure of the title salt, [Ni(C3H3O4)-(C16H36N4)]ClO4 center dot CH3CN, the macrocycle folds around the Ni-II atom, which is also chelated by the carboxylate monoanion. The geometry is a distorted NiN4O2 octahedron. The formula units are connected by N-H center dot center dot center dot O hydrogen bonds into centrosymmetric dimers. Further N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds link the complex molecules and the perchlorate ions. International Union of Crystallography 2010 Article PeerReviewed Ou, Guang-Chuan and Ng, S.W. (2010) (2-Carboxyacetato-kappa O-2(1),O-1 `)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-kappa N-4,N `,N `',N `'')nickel(II) perchlorate acetonitrile solvate. Acta Crystallographica Section E: Structure Reports Online, 66 (11). M1468-U1223. ISSN 1600-5368
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic Q Science (General)
spellingShingle Q Science (General)
Ou, Guang-Chuan
Ng, S.W.
(2-Carboxyacetato-kappa O-2(1),O-1 `)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-kappa N-4,N `,N `',N `'')nickel(II) perchlorate acetonitrile solvate
description In the crystal structure of the title salt, [Ni(C3H3O4)-(C16H36N4)]ClO4 center dot CH3CN, the macrocycle folds around the Ni-II atom, which is also chelated by the carboxylate monoanion. The geometry is a distorted NiN4O2 octahedron. The formula units are connected by N-H center dot center dot center dot O hydrogen bonds into centrosymmetric dimers. Further N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds link the complex molecules and the perchlorate ions.
format Article
author Ou, Guang-Chuan
Ng, S.W.
author_facet Ou, Guang-Chuan
Ng, S.W.
author_sort Ou, Guang-Chuan
title (2-Carboxyacetato-kappa O-2(1),O-1 `)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-kappa N-4,N `,N `',N `'')nickel(II) perchlorate acetonitrile solvate
title_short (2-Carboxyacetato-kappa O-2(1),O-1 `)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-kappa N-4,N `,N `',N `'')nickel(II) perchlorate acetonitrile solvate
title_full (2-Carboxyacetato-kappa O-2(1),O-1 `)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-kappa N-4,N `,N `',N `'')nickel(II) perchlorate acetonitrile solvate
title_fullStr (2-Carboxyacetato-kappa O-2(1),O-1 `)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-kappa N-4,N `,N `',N `'')nickel(II) perchlorate acetonitrile solvate
title_full_unstemmed (2-Carboxyacetato-kappa O-2(1),O-1 `)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-kappa N-4,N `,N `',N `'')nickel(II) perchlorate acetonitrile solvate
title_sort (2-carboxyacetato-kappa o-2(1),o-1 `)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-kappa n-4,n `,n `',n `'')nickel(ii) perchlorate acetonitrile solvate
publisher International Union of Crystallography
publishDate 2010
url http://eprints.um.edu.my/11997/
_version_ 1643689192998305792
score 13.211869

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