Bis[N `-(2-oxo-1H-indol-3-ylidene)furan2-carbohydrazidato-kappa O-3,N `,O `]manganese(II) N,N-dimethylformide monosolvate monohydrate
In the title compound, [Mn(C13H8N3O3)(2)]center dot C3H7NO center dot H2O, the metal atom is O,N,O'-chelated by two deprotonated Schiff bases and exists in a distorted octahedral geometry. The N-H groups, the carbonyl group of the DMF molecule and the uncoordinated water molecule engage in N-H...
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| Main Authors: | , , |
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| Format: | Article |
| Published: |
International Union of Crystallography
2010
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| Subjects: | |
| Online Access: | http://eprints.um.edu.my/11989/ |
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| Summary: | In the title compound, [Mn(C13H8N3O3)(2)]center dot C3H7NO center dot H2O, the metal atom is O,N,O'-chelated by two deprotonated Schiff bases and exists in a distorted octahedral geometry. The N-H groups, the carbonyl group of the DMF molecule and the uncoordinated water molecule engage in N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen-bonding interactions, generating a hydrogen-bonded ribbon that propagates along [110]. |
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