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Dichlorido{2-morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κN,N',N''}zinc(II).

In the title compound, [ZnCl(2)(C(13)H(19)N(3)O)], the Schiff base ligand acts as an N,N',N''-tridentate chelating agent, making two five-membered rings with the Zn(II) ion. The metal atom is five-coordinated by the Schiff base ligand and two Cl atoms in a distorted square-pyramidal g...

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Main Authors: Ikmal Hisham, Nurul Azimah, Suleiman Gwaram, Nura, Khaledi, Hamid, Ali, Hapipah Mohd
Format: Article
Published: International Union of Crystallography 2010
Subjects:
QD Chemistry
R Medicine
Online Access:http://eprints.um.edu.my/1190/
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050202/
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spelling my.um.eprints.11902019-01-31T02:29:25Z http://eprints.um.edu.my/1190/ Dichlorido{2-morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κN,N',N''}zinc(II). Ikmal Hisham, Nurul Azimah Suleiman Gwaram, Nura Khaledi, Hamid Ali, Hapipah Mohd QD Chemistry R Medicine In the title compound, [ZnCl(2)(C(13)H(19)N(3)O)], the Schiff base ligand acts as an N,N',N''-tridentate chelating agent, making two five-membered rings with the Zn(II) ion. The metal atom is five-coordinated by the Schiff base ligand and two Cl atoms in a distorted square-pyramidal geometry. An intra-molecular C-H⋯Cl inter-action occurs. In the crystal, adjacent mol-ecules are linked together via C-H⋯Cl hydrogen-bonding and long range C-H⋯O and C-H⋯Cl inter-actions into a three-dimensional network. International Union of Crystallography 2010 Article PeerReviewed Ikmal Hisham, Nurul Azimah and Suleiman Gwaram, Nura and Khaledi, Hamid and Ali, Hapipah Mohd (2010) Dichlorido{2-morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κN,N',N''}zinc(II). Acta Crystallographica Section E: Structure Reports Online, 67 (Pt 1). m55. ISSN 1600-5368 http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050202/ 21522573
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic QD Chemistry
R Medicine
spellingShingle QD Chemistry
R Medicine
Ikmal Hisham, Nurul Azimah
Suleiman Gwaram, Nura
Khaledi, Hamid
Ali, Hapipah Mohd
Dichlorido{2-morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κN,N',N''}zinc(II).
description In the title compound, [ZnCl(2)(C(13)H(19)N(3)O)], the Schiff base ligand acts as an N,N',N''-tridentate chelating agent, making two five-membered rings with the Zn(II) ion. The metal atom is five-coordinated by the Schiff base ligand and two Cl atoms in a distorted square-pyramidal geometry. An intra-molecular C-H⋯Cl inter-action occurs. In the crystal, adjacent mol-ecules are linked together via C-H⋯Cl hydrogen-bonding and long range C-H⋯O and C-H⋯Cl inter-actions into a three-dimensional network.
format Article
author Ikmal Hisham, Nurul Azimah
Suleiman Gwaram, Nura
Khaledi, Hamid
Ali, Hapipah Mohd
author_facet Ikmal Hisham, Nurul Azimah
Suleiman Gwaram, Nura
Khaledi, Hamid
Ali, Hapipah Mohd
author_sort Ikmal Hisham, Nurul Azimah
title Dichlorido{2-morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κN,N',N''}zinc(II).
title_short Dichlorido{2-morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κN,N',N''}zinc(II).
title_full Dichlorido{2-morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κN,N',N''}zinc(II).
title_fullStr Dichlorido{2-morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κN,N',N''}zinc(II).
title_full_unstemmed Dichlorido{2-morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κN,N',N''}zinc(II).
title_sort dichlorido{2-morpholino-n-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κn,n',n''}zinc(ii).
publisher International Union of Crystallography
publishDate 2010
url http://eprints.um.edu.my/1190/
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050202/
_version_ 1643686687204704256
score 13.211869

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