The effect of au-seeded thickness to the gas sensing properties of ZnO nanostructures obtained by mist-atomization on heated substrates / Nurul Afaah Abdullah … [et al.]

Zinc oxide (ZnO) is an n-type semiconductor with a wide direct band-gap of 3.37 eV at room temperature. ZnO exhibit high-transparency in the visible region, near-UV emission, magnetic, piezo-electric, high-conductivity [1] and piezoelectric dual properties [2]. Its properties can be adjusted by cont...

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Main Authors: Abdullah, Nurul Afaah, Mohd Asib, Nur Amierah, Abd Aziz, Noor Aadila, Khusaimi, Zuraida, Mahmood, Mohamad Rusop
Format: Book Section
Language:English
Published: Research Innovation Business Unit 2014
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Online Access:https://ir.uitm.edu.my/id/eprint/73398/1/73398.pdf
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spelling my.uitm.ir.733982023-03-30T07:04:31Z https://ir.uitm.edu.my/id/eprint/73398/ The effect of au-seeded thickness to the gas sensing properties of ZnO nanostructures obtained by mist-atomization on heated substrates / Nurul Afaah Abdullah … [et al.] Abdullah, Nurul Afaah Mohd Asib, Nur Amierah Abd Aziz, Noor Aadila Khusaimi, Zuraida Mahmood, Mohamad Rusop TP Chemical technology Measurement Nanotechnology Zinc oxide (ZnO) is an n-type semiconductor with a wide direct band-gap of 3.37 eV at room temperature. ZnO exhibit high-transparency in the visible region, near-UV emission, magnetic, piezo-electric, high-conductivity [1] and piezoelectric dual properties [2]. Its properties can be adjusted by controlling size and morphology [3]. Wide application of ZnO has been found such as varistor, gas sensor [4], UV photoconductive sensor [5], high-efficient green phosphor, field emission displays and solar cell [3]. ZnO also display a strong bonding energy of 60 meV, much larger than gallium nitride (GaN, 25 meV). Zinc oxide (ZnO) nanostructure is very responsive and sensitive towards the synthesis methods. Low-dimensional ZnO nanostructures like nanowires, nanorods, and nanotubes may be selectively formed to be considered for usage in new application areas and developing existing applications in nanoelectronics and nanophotonics due to their efficient transport of electrons and excitons [6], large surfaceto-volume ratio and quantum confinement effects [7]. The synthesis methods often face limitations in terms of sample uniformity, substrate selection, and low product yield. On the contrary, approaches using solution-based are attractive because of the low temperature growth, potential for scaling up and much easier operation in fabricating high-density ZnO arrays [8], however vapor method give better results in synthesizing ZnO nanostructures in room temperature (RT). In this paper, we focus on the synthesis of ZnO nanostructures were obtained by a simple and low-cost synthesis method; mist-atomization. The starting materials for this synthesizing method are zinc nitrate hexahydrate as precursor solution and hexamethylenetetramine (HMTA) as the stabiliser. ZnO nanostructures were deposited by mist-atomization with applied heat from substrates’ downside. The glass substrates first seeded with gold (Au) with 0, 6 and 12 nm thickness. The gas sensing properties of the samples were examined by UV-Vis (UV-Visible) spectroscopy, Field Emission Scanning Electron Microscope (FESEM) micrograph and I-V (Current-Voltage) measurement. FESEM micrographs show the different morphology of ZnO nanostructures obtained on different Au-seeded thickness glass substrate. There is improvement in UV region analysed from ZnO nanostructure growth on 6 nm Au-seeded glasses. I-V measurements also show some improvement in gas sensing properties of ZnO on different Au-seeded glass substrate. The optical, morphological properties and I-V (IV) measurement of sprayed ZnO nanostructures growth on different Au-seeded glass substrate largely depend on the substrates temperature during spraying the zinc acetate solution and on the Au-seeded glass substrates. Research Innovation Business Unit 2014 Book Section NonPeerReviewed text en https://ir.uitm.edu.my/id/eprint/73398/1/73398.pdf The effect of au-seeded thickness to the gas sensing properties of ZnO nanostructures obtained by mist-atomization on heated substrates / Nurul Afaah Abdullah … [et al.]. (2014) In: IIDEX 2014: invention, innovation & design exposition. Research Innovation Business Unit, Shah Alam, Selangor, p. 128. (Submitted) http://www.iidex.com.my
institution Universiti Teknologi Mara
building Tun Abdul Razak Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Teknologi Mara
content_source UiTM Institutional Repository
url_provider http://ir.uitm.edu.my/
language English
topic TP Chemical technology
Measurement
Nanotechnology
spellingShingle TP Chemical technology
Measurement
Nanotechnology
Abdullah, Nurul Afaah
Mohd Asib, Nur Amierah
Abd Aziz, Noor Aadila
Khusaimi, Zuraida
Mahmood, Mohamad Rusop
The effect of au-seeded thickness to the gas sensing properties of ZnO nanostructures obtained by mist-atomization on heated substrates / Nurul Afaah Abdullah … [et al.]
description Zinc oxide (ZnO) is an n-type semiconductor with a wide direct band-gap of 3.37 eV at room temperature. ZnO exhibit high-transparency in the visible region, near-UV emission, magnetic, piezo-electric, high-conductivity [1] and piezoelectric dual properties [2]. Its properties can be adjusted by controlling size and morphology [3]. Wide application of ZnO has been found such as varistor, gas sensor [4], UV photoconductive sensor [5], high-efficient green phosphor, field emission displays and solar cell [3]. ZnO also display a strong bonding energy of 60 meV, much larger than gallium nitride (GaN, 25 meV). Zinc oxide (ZnO) nanostructure is very responsive and sensitive towards the synthesis methods. Low-dimensional ZnO nanostructures like nanowires, nanorods, and nanotubes may be selectively formed to be considered for usage in new application areas and developing existing applications in nanoelectronics and nanophotonics due to their efficient transport of electrons and excitons [6], large surfaceto-volume ratio and quantum confinement effects [7]. The synthesis methods often face limitations in terms of sample uniformity, substrate selection, and low product yield. On the contrary, approaches using solution-based are attractive because of the low temperature growth, potential for scaling up and much easier operation in fabricating high-density ZnO arrays [8], however vapor method give better results in synthesizing ZnO nanostructures in room temperature (RT). In this paper, we focus on the synthesis of ZnO nanostructures were obtained by a simple and low-cost synthesis method; mist-atomization. The starting materials for this synthesizing method are zinc nitrate hexahydrate as precursor solution and hexamethylenetetramine (HMTA) as the stabiliser. ZnO nanostructures were deposited by mist-atomization with applied heat from substrates’ downside. The glass substrates first seeded with gold (Au) with 0, 6 and 12 nm thickness. The gas sensing properties of the samples were examined by UV-Vis (UV-Visible) spectroscopy, Field Emission Scanning Electron Microscope (FESEM) micrograph and I-V (Current-Voltage) measurement. FESEM micrographs show the different morphology of ZnO nanostructures obtained on different Au-seeded thickness glass substrate. There is improvement in UV region analysed from ZnO nanostructure growth on 6 nm Au-seeded glasses. I-V measurements also show some improvement in gas sensing properties of ZnO on different Au-seeded glass substrate. The optical, morphological properties and I-V (IV) measurement of sprayed ZnO nanostructures growth on different Au-seeded glass substrate largely depend on the substrates temperature during spraying the zinc acetate solution and on the Au-seeded glass substrates.
format Book Section
author Abdullah, Nurul Afaah
Mohd Asib, Nur Amierah
Abd Aziz, Noor Aadila
Khusaimi, Zuraida
Mahmood, Mohamad Rusop
author_facet Abdullah, Nurul Afaah
Mohd Asib, Nur Amierah
Abd Aziz, Noor Aadila
Khusaimi, Zuraida
Mahmood, Mohamad Rusop
author_sort Abdullah, Nurul Afaah
title The effect of au-seeded thickness to the gas sensing properties of ZnO nanostructures obtained by mist-atomization on heated substrates / Nurul Afaah Abdullah … [et al.]
title_short The effect of au-seeded thickness to the gas sensing properties of ZnO nanostructures obtained by mist-atomization on heated substrates / Nurul Afaah Abdullah … [et al.]
title_full The effect of au-seeded thickness to the gas sensing properties of ZnO nanostructures obtained by mist-atomization on heated substrates / Nurul Afaah Abdullah … [et al.]
title_fullStr The effect of au-seeded thickness to the gas sensing properties of ZnO nanostructures obtained by mist-atomization on heated substrates / Nurul Afaah Abdullah … [et al.]
title_full_unstemmed The effect of au-seeded thickness to the gas sensing properties of ZnO nanostructures obtained by mist-atomization on heated substrates / Nurul Afaah Abdullah … [et al.]
title_sort effect of au-seeded thickness to the gas sensing properties of zno nanostructures obtained by mist-atomization on heated substrates / nurul afaah abdullah … [et al.]
publisher Research Innovation Business Unit
publishDate 2014
url https://ir.uitm.edu.my/id/eprint/73398/1/73398.pdf
https://ir.uitm.edu.my/id/eprint/73398/
http://www.iidex.com.my
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score 13.244745