Cover Image

Synthesis, characterization and anti corrosion screening of bi(III) thiacetazone complex / Lailatul Izidah Hanim Abdul Latif

Bi(III) thiacetazone complex, [Bi(TAC)Cl]Ch was successfully synthesis by using reflux method with methanol solvent. The complex was characterized by melting point, Fourier Transform Infrared (FTIR), Ultraviolet-Visible (UV-Vis), elemental analysis (CHNS), gravimetric analysis and molar conductivity...

Full description

Saved in:
Bibliographic Details
Main Author: Abdul Latif, Lailatul Izidah Hanim
Format: Student Project
Language:English
Published: 2017
Subjects:
Laboratories. General works
Organic chemistry
Schiff bases
Chemical elements
Online Access:http://ir.uitm.edu.my/id/eprint/41585/1/41585.pdf
http://ir.uitm.edu.my/id/eprint/41585/
Tags: Add Tag
No Tags, Be the first to tag this record!
id my.uitm.ir.41585
record_format eprints
spelling my.uitm.ir.415852021-02-11T05:42:15Z http://ir.uitm.edu.my/id/eprint/41585/ Synthesis, characterization and anti corrosion screening of bi(III) thiacetazone complex / Lailatul Izidah Hanim Abdul Latif Abdul Latif, Lailatul Izidah Hanim Laboratories. General works Organic chemistry Schiff bases Chemical elements Bi(III) thiacetazone complex, [Bi(TAC)Cl]Ch was successfully synthesis by using reflux method with methanol solvent. The complex was characterized by melting point, Fourier Transform Infrared (FTIR), Ultraviolet-Visible (UV-Vis), elemental analysis (CHNS), gravimetric analysis and molar conductivity. The complex formed was bright yellow colour and the melting point of complex is 231-233 °C. While, the percentage yield of complex is 79%. The colour changes from light yellow to bright yellow showed the reaction between ligand and metal. From the characterization, the ligand was coordinated to Bi(III) ion through azomethine N and carbonyl O as the stretching band of FTIR were shifting to the higher wavenumber compared with the ligand. The percentage of metal in gravimetric analysis calculated was 39. 7% and the molar conductivity conducted was 1: 1. The UV-Vis absorption, hv showed two types of transition, TC - TC* and n - TC* which are proved there was coordination occurred between TAC and Bi(III) ion since there are shifting. TAC and [Bi(TAC)Cl]Ch was used in the corrosion inhibitor study and found that the ligand are more suitable as corrosion inhibitor for mild steel compare to the complex synthesis. The inhibition increased as the concentration of inhibition increased. 2017 Student Project NonPeerReviewed text en http://ir.uitm.edu.my/id/eprint/41585/1/41585.pdf Abdul Latif, Lailatul Izidah Hanim (2017) Synthesis, characterization and anti corrosion screening of bi(III) thiacetazone complex / Lailatul Izidah Hanim Abdul Latif. [Student Project] (Unpublished)
institution Universiti Teknologi Mara
building Tun Abdul Razak Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Teknologi Mara
content_source UiTM Institutional Repository
url_provider http://ir.uitm.edu.my/
language English
topic Laboratories. General works
Organic chemistry
Schiff bases
Chemical elements
spellingShingle Laboratories. General works
Organic chemistry
Schiff bases
Chemical elements
Abdul Latif, Lailatul Izidah Hanim
Synthesis, characterization and anti corrosion screening of bi(III) thiacetazone complex / Lailatul Izidah Hanim Abdul Latif
description Bi(III) thiacetazone complex, [Bi(TAC)Cl]Ch was successfully synthesis by using reflux method with methanol solvent. The complex was characterized by melting point, Fourier Transform Infrared (FTIR), Ultraviolet-Visible (UV-Vis), elemental analysis (CHNS), gravimetric analysis and molar conductivity. The complex formed was bright yellow colour and the melting point of complex is 231-233 °C. While, the percentage yield of complex is 79%. The colour changes from light yellow to bright yellow showed the reaction between ligand and metal. From the characterization, the ligand was coordinated to Bi(III) ion through azomethine N and carbonyl O as the stretching band of FTIR were shifting to the higher wavenumber compared with the ligand. The percentage of metal in gravimetric analysis calculated was 39. 7% and the molar conductivity conducted was 1: 1. The UV-Vis absorption, hv showed two types of transition, TC - TC* and n - TC* which are proved there was coordination occurred between TAC and Bi(III) ion since there are shifting. TAC and [Bi(TAC)Cl]Ch was used in the corrosion inhibitor study and found that the ligand are more suitable as corrosion inhibitor for mild steel compare to the complex synthesis. The inhibition increased as the concentration of inhibition increased.
format Student Project
author Abdul Latif, Lailatul Izidah Hanim
author_facet Abdul Latif, Lailatul Izidah Hanim
author_sort Abdul Latif, Lailatul Izidah Hanim
title Synthesis, characterization and anti corrosion screening of bi(III) thiacetazone complex / Lailatul Izidah Hanim Abdul Latif
title_short Synthesis, characterization and anti corrosion screening of bi(III) thiacetazone complex / Lailatul Izidah Hanim Abdul Latif
title_full Synthesis, characterization and anti corrosion screening of bi(III) thiacetazone complex / Lailatul Izidah Hanim Abdul Latif
title_fullStr Synthesis, characterization and anti corrosion screening of bi(III) thiacetazone complex / Lailatul Izidah Hanim Abdul Latif
title_full_unstemmed Synthesis, characterization and anti corrosion screening of bi(III) thiacetazone complex / Lailatul Izidah Hanim Abdul Latif
title_sort synthesis, characterization and anti corrosion screening of bi(iii) thiacetazone complex / lailatul izidah hanim abdul latif
publishDate 2017
url http://ir.uitm.edu.my/id/eprint/41585/1/41585.pdf
http://ir.uitm.edu.my/id/eprint/41585/
_version_ 1691735811681157120
score 13.211869

Similar Items