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Synthesis and characterization of hydrolysis palm kernel oil-based polyurethane / Nursyashabillah Nor

This study was conducted to investigate the hydrolysis reaction of rigid palmbased polyurethane. Rigid polyurethane (PU) was synthesized by using monoester-OH kernel oil (polyol). The resulting PU sample was immersed in an aqueous solution of sodium hydroxide (NaOH) concentrations of 0%, 10%, 20%, 3...

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Main Author: Nor, Nursyashabillah
Format: Student Project
Language:English
Published: Faculty of Applied Sciences 2017
Subjects:
QD Chemistry
Chemical elements
Online Access:http://ir.uitm.edu.my/id/eprint/25370/1/PPb_NURSYASHABILLAH%20NOR%20AS%20N%2017_5.pdf
http://ir.uitm.edu.my/id/eprint/25370/
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spelling my.uitm.ir.253702019-09-06T07:23:04Z http://ir.uitm.edu.my/id/eprint/25370/ Synthesis and characterization of hydrolysis palm kernel oil-based polyurethane / Nursyashabillah Nor Nor, Nursyashabillah QD Chemistry Chemical elements This study was conducted to investigate the hydrolysis reaction of rigid palmbased polyurethane. Rigid polyurethane (PU) was synthesized by using monoester-OH kernel oil (polyol). The resulting PU sample was immersed in an aqueous solution of sodium hydroxide (NaOH) concentrations of 0%, 10%, 20%, 30% and 40%. NaOH alkaline aqueous solution can accelerate the rate of hydrolysis. Samples of PU cake were hydrolysable and filtrate every 7, 14, 21 and 28 days. Weights taken showed mass of PU hydrolysable were rise when wet. It showed the PU swelled caused by the absorption of NaOH solution. After the sample is dried, cakes PU hydrolysable were taken its mass, and found its mass was reduced lower than the mass before the hydrolysis reaction is carried out. It showed part of the structure of the PU was degraded as a result of hydrolysis reaction. The higher the concentration of NaOH aqueous solution, the higher the mass of the material decomposes. FTIR spectroscopic analysis showed the decomposition of PU structure through loss absorption peak of C=O, C-O-C and C-N. Image analyzer optical microscope showed the structure of PU particle is reduced and the bond between the particles was damaged. SEM analysis also conducted towards PU control. The morphology of PU structures was porous after the reaction. Despite from that, it was concluded that the decomposition of PU through hydrolysis reaction causes termination chain of PU, in which the soft segment monoester-OH degrade, while the hard segment with cross-linked remained in the structure of the PU. Faculty of Applied Sciences 2017 Student Project NonPeerReviewed text en http://ir.uitm.edu.my/id/eprint/25370/1/PPb_NURSYASHABILLAH%20NOR%20AS%20N%2017_5.pdf Nor, Nursyashabillah (2017) Synthesis and characterization of hydrolysis palm kernel oil-based polyurethane / Nursyashabillah Nor. [Student Project] (Unpublished)
institution Universiti Teknologi Mara
building Tun Abdul Razak Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Teknologi Mara
content_source UiTM Institutional Repository
url_provider http://ir.uitm.edu.my/
language English
topic QD Chemistry
Chemical elements
spellingShingle QD Chemistry
Chemical elements
Nor, Nursyashabillah
Synthesis and characterization of hydrolysis palm kernel oil-based polyurethane / Nursyashabillah Nor
description This study was conducted to investigate the hydrolysis reaction of rigid palmbased polyurethane. Rigid polyurethane (PU) was synthesized by using monoester-OH kernel oil (polyol). The resulting PU sample was immersed in an aqueous solution of sodium hydroxide (NaOH) concentrations of 0%, 10%, 20%, 30% and 40%. NaOH alkaline aqueous solution can accelerate the rate of hydrolysis. Samples of PU cake were hydrolysable and filtrate every 7, 14, 21 and 28 days. Weights taken showed mass of PU hydrolysable were rise when wet. It showed the PU swelled caused by the absorption of NaOH solution. After the sample is dried, cakes PU hydrolysable were taken its mass, and found its mass was reduced lower than the mass before the hydrolysis reaction is carried out. It showed part of the structure of the PU was degraded as a result of hydrolysis reaction. The higher the concentration of NaOH aqueous solution, the higher the mass of the material decomposes. FTIR spectroscopic analysis showed the decomposition of PU structure through loss absorption peak of C=O, C-O-C and C-N. Image analyzer optical microscope showed the structure of PU particle is reduced and the bond between the particles was damaged. SEM analysis also conducted towards PU control. The morphology of PU structures was porous after the reaction. Despite from that, it was concluded that the decomposition of PU through hydrolysis reaction causes termination chain of PU, in which the soft segment monoester-OH degrade, while the hard segment with cross-linked remained in the structure of the PU.
format Student Project
author Nor, Nursyashabillah
author_facet Nor, Nursyashabillah
author_sort Nor, Nursyashabillah
title Synthesis and characterization of hydrolysis palm kernel oil-based polyurethane / Nursyashabillah Nor
title_short Synthesis and characterization of hydrolysis palm kernel oil-based polyurethane / Nursyashabillah Nor
title_full Synthesis and characterization of hydrolysis palm kernel oil-based polyurethane / Nursyashabillah Nor
title_fullStr Synthesis and characterization of hydrolysis palm kernel oil-based polyurethane / Nursyashabillah Nor
title_full_unstemmed Synthesis and characterization of hydrolysis palm kernel oil-based polyurethane / Nursyashabillah Nor
title_sort synthesis and characterization of hydrolysis palm kernel oil-based polyurethane / nursyashabillah nor
publisher Faculty of Applied Sciences
publishDate 2017
url http://ir.uitm.edu.my/id/eprint/25370/1/PPb_NURSYASHABILLAH%20NOR%20AS%20N%2017_5.pdf
http://ir.uitm.edu.my/id/eprint/25370/
_version_ 1685649988487479296
score 13.211869

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