3-(2-Hydroxyethyl)-3-methyl-1-(4-methylbenzoyl)thiourea
The title thiourea derivative, C12H16N2O2S, has a twisted conformation with the dihedral angle between the NC(=S)N and O=CC6 planes being 35.45 (5)°. The observed conformation allows for an intramolecular N-H...O hydrogen bond. In the molecular packing, supramolecular aggregation is based on hy...
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| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2016
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| Subjects: | |
| Online Access: | http://eprints.sunway.edu.my/663/1/IUCrData%202016%201%20x152457.pdf http://eprints.sunway.edu.my/663/ http://dx.doi.org/10.1107/S2414314615024578 |
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| Summary: | The title thiourea derivative, C12H16N2O2S, has a twisted conformation with the dihedral angle between the NC(=S)N and O=CC6 planes being 35.45 (5)°. The observed conformation allows for an intramolecular N-H...O hydrogen bond. In the molecular packing, supramolecular aggregation is based on hydroxy-O-H...O(carbonyl) hydrogen bonding and leads to supramolecular helical chains along the a axis; chains are reinforced by N-methylene-C-H...S and N-methyl-C-H...[pi](arene) interactions. Supramolecular layers in the ab plane are formed as a result of tolyl-methyl-C-H...[pi](arene) interactions. |
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