Persistence of C–H⋯π(chelate ring) interactions in the crystal structures of Pd(S2COR)2. The utility of Pd(S2COR)2 as precursors for palladium sulphide materials
The crystallographic structures of 12 palladium xanthates, PdIJS2COR)2 (R = alkyl) show a uniform adoption of square-planar PdS4 geometries. Supramolecular aggregation in 1 (R = Me), 2 (Et) and 3 (n-Pr) is based on secondary Pd⋯S interactions, which are “turned off” when the bulk of R increases. In...
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| Main Authors: | , , , , , |
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| Format: | Article |
| Published: |
Royal Society of Chemistry
2016
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| Subjects: | |
| Online Access: | http://eprints.sunway.edu.my/615/ http://dx.doi.org/10.1039/c5ce02126j |
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