The remarkable propensity for the formation of C–H⋯π(chelate ring) interactions in the crystals of the first-row transition metal dithiocarbamates and the supramolecular architectures they sustain.
The Cambridge Crystallographic Database has been searched for the presence of intermolecular C– H⋯π(chelate ring) interactions, known to be stabilising, in the crystals of the first-row transition metal dithiocarbamates, i.e. containing anionic ligands of the type −S2CNR2, R = H, alkyl and aryl. A s...
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Royal Society of Chemistry
2020
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| Online Access: | http://eprints.sunway.edu.my/1529/ http://doi.org/10.1039/d0ce00289e |
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