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Isotherm, kinetic and adsorption study of malachite green dye on Carbon Nanotubes Immobilized Biomass (CNTIB)

This study tries to assess wastewater quality in textile industry, one of the critical issues to be well thought-out is the exposure to chemicals substances, as it might represent a health concern in textile industry and is subject to different health occupational limits. This paper attempts to desc...

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Main Authors:	Kabbashi, Nassereldeen Ahmed, Alam, Md. Zahangir, Al-Khatib, Ma'an Fahmi Rashid
Format:	Proceeding Paper
Language:	English
Published:	2017
Subjects:	TP155 Chemical engineering
Online Access:	http://irep.iium.edu.my/61363/1/Spain_Conference.pdf http://irep.iium.edu.my/61363/ http://wcce10.org/index.php/wcce10-ecce11-ecab4/welcome
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spelling	my.iium.irep.613632024-05-06T07:03:29Z http://irep.iium.edu.my/61363/ Isotherm, kinetic and adsorption study of malachite green dye on Carbon Nanotubes Immobilized Biomass (CNTIB) Kabbashi, Nassereldeen Ahmed Alam, Md. Zahangir Al-Khatib, Ma'an Fahmi Rashid TP155 Chemical engineering This study tries to assess wastewater quality in textile industry, one of the critical issues to be well thought-out is the exposure to chemicals substances, as it might represent a health concern in textile industry and is subject to different health occupational limits. This paper attempts to describe the factors which might have an impact in the textile industry as high concentration of non-biodegradable compounds contributes to increased biochemical oxygen demand (BOD) and chemical oxygen demand (COD) of the wastewater bodies. Dyes found in wastewater from textile industries are carcinogenic, mutagenic or teratogenic. Biological processes involving certain bacteria, fungi, activated carbon and carbon nanotubes (CNTs) are promising methods for treating waste water but these methods are either inefficient or ineffective. These complexities necessitates search for new approaches that will offset all the shortcomings of the present solutions to the challenges faced with textile wastewater management. Furthermore, the study produced a new biosorbent by the immobilization of fungal biomass on carbon nanotubes. The new biosorbent is called “carbon nanotubes immobilized biomass (CNTIB)”. The biosorbent was produced by immobilization technique. A potential fungal strain, Aspergillus niger was selected on the basis of biomass production. Aspergillus niger was immobilized on carbon nanotubes. Isotherm studies showed that the experimental data better fitted with the Langmuir isotherm for CNTIB (R2= 0.919) when compared to Freundlich isotherm (R2= 0.892). Notwithstanding the aforementioned information, the kinetic study however indicated that the biosorption followed the pseudo-second order kinetic model which suggests that chemisorption is most likely the process through which biosorption took place. The kinetics models include the pseudo-first-order and pseudo-second-order kinetic models and they have been applied to study the kinetics of the adsorption process in this study. To study the kinetic of Malachite green dye onto CNTIB, its experimental data were fitted using the pseudo-first order and pseudo-second order kinetic models. At all the concentrations studied, comparing all R2 values, those of the pseudo second-order kinetics were found to be more than 0.90. According to (Wang and Chen)Bayramoglu et al., (2002), pseudo-second order assumed that the rate limiting step was biosorption. There must be sharing or exchange of electrons between the biosorbent and the biosorbate. The study investigated the equilibrium and adsorption of Malachite green on CNTIB at various concentrations. The results of biosorption evaluation using the active biosorbent for dye removal showed that the dye was decolorized with a dye uptake of 98% at a dye concentration of 60mg/L. Isotherm studies showed that the experimental data better fitted with the Langmuir isotherm for CNTIB when compared to Freundlich isotherm. 2017-10-05 Proceeding Paper NonPeerReviewed application/pdf en http://irep.iium.edu.my/61363/1/Spain_Conference.pdf Kabbashi, Nassereldeen Ahmed and Alam, Md. Zahangir and Al-Khatib, Ma'an Fahmi Rashid (2017) Isotherm, kinetic and adsorption study of malachite green dye on Carbon Nanotubes Immobilized Biomass (CNTIB). In: 10th World Congress of Chemical Engineering (WCCCE10), 1st-5th October 2017, Barcelona, Spain. http://wcce10.org/index.php/wcce10-ecce11-ecab4/welcome
institution	Universiti Islam Antarabangsa Malaysia
building	IIUM Library
collection	Institutional Repository
continent	Asia
country	Malaysia
content_provider	International Islamic University Malaysia
content_source	IIUM Repository (IREP)
url_provider	http://irep.iium.edu.my/
language	English
topic	TP155 Chemical engineering
spellingShingle	TP155 Chemical engineering Kabbashi, Nassereldeen Ahmed Alam, Md. Zahangir Al-Khatib, Ma'an Fahmi Rashid Isotherm, kinetic and adsorption study of malachite green dye on Carbon Nanotubes Immobilized Biomass (CNTIB)
description	This study tries to assess wastewater quality in textile industry, one of the critical issues to be well thought-out is the exposure to chemicals substances, as it might represent a health concern in textile industry and is subject to different health occupational limits. This paper attempts to describe the factors which might have an impact in the textile industry as high concentration of non-biodegradable compounds contributes to increased biochemical oxygen demand (BOD) and chemical oxygen demand (COD) of the wastewater bodies. Dyes found in wastewater from textile industries are carcinogenic, mutagenic or teratogenic. Biological processes involving certain bacteria, fungi, activated carbon and carbon nanotubes (CNTs) are promising methods for treating waste water but these methods are either inefficient or ineffective. These complexities necessitates search for new approaches that will offset all the shortcomings of the present solutions to the challenges faced with textile wastewater management. Furthermore, the study produced a new biosorbent by the immobilization of fungal biomass on carbon nanotubes. The new biosorbent is called “carbon nanotubes immobilized biomass (CNTIB)”. The biosorbent was produced by immobilization technique. A potential fungal strain, Aspergillus niger was selected on the basis of biomass production. Aspergillus niger was immobilized on carbon nanotubes. Isotherm studies showed that the experimental data better fitted with the Langmuir isotherm for CNTIB (R2= 0.919) when compared to Freundlich isotherm (R2= 0.892). Notwithstanding the aforementioned information, the kinetic study however indicated that the biosorption followed the pseudo-second order kinetic model which suggests that chemisorption is most likely the process through which biosorption took place. The kinetics models include the pseudo-first-order and pseudo-second-order kinetic models and they have been applied to study the kinetics of the adsorption process in this study. To study the kinetic of Malachite green dye onto CNTIB, its experimental data were fitted using the pseudo-first order and pseudo-second order kinetic models. At all the concentrations studied, comparing all R2 values, those of the pseudo second-order kinetics were found to be more than 0.90. According to (Wang and Chen)Bayramoglu et al., (2002), pseudo-second order assumed that the rate limiting step was biosorption. There must be sharing or exchange of electrons between the biosorbent and the biosorbate. The study investigated the equilibrium and adsorption of Malachite green on CNTIB at various concentrations. The results of biosorption evaluation using the active biosorbent for dye removal showed that the dye was decolorized with a dye uptake of 98% at a dye concentration of 60mg/L. Isotherm studies showed that the experimental data better fitted with the Langmuir isotherm for CNTIB when compared to Freundlich isotherm.
format	Proceeding Paper
author	Kabbashi, Nassereldeen Ahmed Alam, Md. Zahangir Al-Khatib, Ma'an Fahmi Rashid
author_facet	Kabbashi, Nassereldeen Ahmed Alam, Md. Zahangir Al-Khatib, Ma'an Fahmi Rashid
author_sort	Kabbashi, Nassereldeen Ahmed
title	Isotherm, kinetic and adsorption study of malachite green dye on Carbon Nanotubes Immobilized Biomass (CNTIB)
title_short	Isotherm, kinetic and adsorption study of malachite green dye on Carbon Nanotubes Immobilized Biomass (CNTIB)
title_full	Isotherm, kinetic and adsorption study of malachite green dye on Carbon Nanotubes Immobilized Biomass (CNTIB)
title_fullStr	Isotherm, kinetic and adsorption study of malachite green dye on Carbon Nanotubes Immobilized Biomass (CNTIB)
title_full_unstemmed	Isotherm, kinetic and adsorption study of malachite green dye on Carbon Nanotubes Immobilized Biomass (CNTIB)
title_sort	isotherm, kinetic and adsorption study of malachite green dye on carbon nanotubes immobilized biomass (cntib)
publishDate	2017
url	http://irep.iium.edu.my/61363/1/Spain_Conference.pdf http://irep.iium.edu.my/61363/ http://wcce10.org/index.php/wcce10-ecce11-ecab4/welcome
_version_	1800081743989964800
score	13.211869

Isotherm, kinetic and adsorption study of malachite green dye on Carbon Nanotubes Immobilized Biomass (CNTIB)

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