Cover Image

Effect of metals compatibility on fluorine-doped tin oxide catalyst for glycerol conversion to 1,2-Propanediol

The effect of metals on support material fluorine-doped tin oxide (FTO), were studied. A series of metals such as ruthenium (Ru), osmium (Os), palladium (Pd), and copper (Cu) on FTO support were prepared by a simple wet mixture method, and attempted as a heterogeneous catalyst to enhance the hydroge...

Full description

Saved in:
Bibliographic Details
Main Authors: Samad, Wan Zurina, Wan Isahak, Wan Nor Roslam, Hamzah, Noraini, Yarmo, Mohd Ambar, Yusop, Muhammad Rahimi
Format: Conference or Workshop Item
Language:English
English
Published: Trans Tech. Publications 2017
Subjects:
Q Science (General)
Online Access:http://irep.iium.edu.my/56699/13/56699_Effect%20of%20metals%20compatibility%20on%20fluorine-doped.pdf
http://irep.iium.edu.my/56699/24/56699-Effect%20of%20metals%20compatibility%20on%20fluorine-doped%20tin-SCOPUS.pdf
http://irep.iium.edu.my/56699/
https://www.scientific.net/MSF.888.496
Tags: Add Tag
No Tags, Be the first to tag this record!
id my.iium.irep.56699
record_format dspace
spelling my.iium.irep.566992018-03-15T09:33:24Z http://irep.iium.edu.my/56699/ Effect of metals compatibility on fluorine-doped tin oxide catalyst for glycerol conversion to 1,2-Propanediol Samad, Wan Zurina Wan Isahak, Wan Nor Roslam Hamzah, Noraini Yarmo, Mohd Ambar Yusop, Muhammad Rahimi Q Science (General) The effect of metals on support material fluorine-doped tin oxide (FTO), were studied. A series of metals such as ruthenium (Ru), osmium (Os), palladium (Pd), and copper (Cu) on FTO support were prepared by a simple wet mixture method, and attempted as a heterogeneous catalyst to enhance the hydrogenolysis of glycerol converted to 1,2-propanediol (1,2-PDO). The physicochemical properties of the catalysts were characterized by XRD, XPS, BET, FESEM, TEM, TPR, and TPD techniques. In particular, the catalyst of Ru-FTO was recorded as a good catalyst with an optimum glycerol conversion of 100% and 1,2-PDO selectivity of 94% respectively. It was suggesting that the acid an basic properties of the catalyst could achieved the C-O and C-H bond dissociation by formation of different intermediates of acetol and acetaldehyde to become 1,2-PDO. Despite that, some reaction parameters were evaluated and optimized reaction condition were established Trans Tech. Publications 2017-03 Conference or Workshop Item REM application/pdf en http://irep.iium.edu.my/56699/13/56699_Effect%20of%20metals%20compatibility%20on%20fluorine-doped.pdf application/pdf en http://irep.iium.edu.my/56699/24/56699-Effect%20of%20metals%20compatibility%20on%20fluorine-doped%20tin-SCOPUS.pdf Samad, Wan Zurina and Wan Isahak, Wan Nor Roslam and Hamzah, Noraini and Yarmo, Mohd Ambar and Yusop, Muhammad Rahimi (2017) Effect of metals compatibility on fluorine-doped tin oxide catalyst for glycerol conversion to 1,2-Propanediol. In: International Conference on X-Rays and Related Techniques in Research and Industry, ICXRI 2016, 17th-18th August, 2016, Dorsett Hotel, Putrajaya. https://www.scientific.net/MSF.888.496 10.4028/www.scientific.net/MSF.888.496
institution Universiti Islam Antarabangsa Malaysia
building IIUM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider International Islamic University Malaysia
content_source IIUM Repository (IREP)
url_provider http://irep.iium.edu.my/
language English
English
topic Q Science (General)
spellingShingle Q Science (General)
Samad, Wan Zurina
Wan Isahak, Wan Nor Roslam
Hamzah, Noraini
Yarmo, Mohd Ambar
Yusop, Muhammad Rahimi
Effect of metals compatibility on fluorine-doped tin oxide catalyst for glycerol conversion to 1,2-Propanediol
description The effect of metals on support material fluorine-doped tin oxide (FTO), were studied. A series of metals such as ruthenium (Ru), osmium (Os), palladium (Pd), and copper (Cu) on FTO support were prepared by a simple wet mixture method, and attempted as a heterogeneous catalyst to enhance the hydrogenolysis of glycerol converted to 1,2-propanediol (1,2-PDO). The physicochemical properties of the catalysts were characterized by XRD, XPS, BET, FESEM, TEM, TPR, and TPD techniques. In particular, the catalyst of Ru-FTO was recorded as a good catalyst with an optimum glycerol conversion of 100% and 1,2-PDO selectivity of 94% respectively. It was suggesting that the acid an basic properties of the catalyst could achieved the C-O and C-H bond dissociation by formation of different intermediates of acetol and acetaldehyde to become 1,2-PDO. Despite that, some reaction parameters were evaluated and optimized reaction condition were established
format Conference or Workshop Item
author Samad, Wan Zurina
Wan Isahak, Wan Nor Roslam
Hamzah, Noraini
Yarmo, Mohd Ambar
Yusop, Muhammad Rahimi
author_facet Samad, Wan Zurina
Wan Isahak, Wan Nor Roslam
Hamzah, Noraini
Yarmo, Mohd Ambar
Yusop, Muhammad Rahimi
author_sort Samad, Wan Zurina
title Effect of metals compatibility on fluorine-doped tin oxide catalyst for glycerol conversion to 1,2-Propanediol
title_short Effect of metals compatibility on fluorine-doped tin oxide catalyst for glycerol conversion to 1,2-Propanediol
title_full Effect of metals compatibility on fluorine-doped tin oxide catalyst for glycerol conversion to 1,2-Propanediol
title_fullStr Effect of metals compatibility on fluorine-doped tin oxide catalyst for glycerol conversion to 1,2-Propanediol
title_full_unstemmed Effect of metals compatibility on fluorine-doped tin oxide catalyst for glycerol conversion to 1,2-Propanediol
title_sort effect of metals compatibility on fluorine-doped tin oxide catalyst for glycerol conversion to 1,2-propanediol
publisher Trans Tech. Publications
publishDate 2017
url http://irep.iium.edu.my/56699/13/56699_Effect%20of%20metals%20compatibility%20on%20fluorine-doped.pdf
http://irep.iium.edu.my/56699/24/56699-Effect%20of%20metals%20compatibility%20on%20fluorine-doped%20tin-SCOPUS.pdf
http://irep.iium.edu.my/56699/
https://www.scientific.net/MSF.888.496
_version_ 1643614979433168896
score 13.211869

Similar Items