Study of solvent system for biodiesel production from Sludge Palm Oil (SPO) by enzymatic transesterification

Biodiesel is a non-toxic renewable fuel that has been highly demanded because it reduces the emission of air pollutants, thus a good alternative for the petroleum-derived fuel which is now having depletion, unstable price escalation and causes environmental problems. In thi...

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Main Authors: Nasaruddin, Ricca Rahman, Alam, Md. Zahangir, Jami, Mohammed Saedi
Format: Conference or Workshop Item
Language:English
English
Published: 2012
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Online Access:http://irep.iium.edu.my/42416/1/Full_Paper_-_ID_O124.pdf
http://irep.iium.edu.my/42416/4/42416.pdf
http://irep.iium.edu.my/42416/
http://icbbvap2012.ump.edu.my/program.html
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spelling my.iium.irep.424162015-05-18T04:00:36Z http://irep.iium.edu.my/42416/ Study of solvent system for biodiesel production from Sludge Palm Oil (SPO) by enzymatic transesterification Nasaruddin, Ricca Rahman Alam, Md. Zahangir Jami, Mohammed Saedi TP155 Chemical engineering Biodiesel is a non-toxic renewable fuel that has been highly demanded because it reduces the emission of air pollutants, thus a good alternative for the petroleum-derived fuel which is now having depletion, unstable price escalation and causes environmental problems. In this study, sludge palm oil (SPO) which is a low cost and abundantly produced waste oil was investigated to produce biodiesel by direct enzymatic transesterification using lipase. The lipase was produced locally by Candida cylindracea from a low cost basal medium, palm oil mill effluent (POME) in order to eliminate the higher cost of commercial lipases. Several factors in solvent system were studied to enhance the biodiesel production. Ethanol was selected as the acyl acceptor because it gave higherpercentage of yield and conversion of free fatty acids (FFAs) into biodiesel than the methanol. The optimum ethanol-to-SPO molar ratio was found to be 4:1 while the increasing of water content reduced the activity of the lipase thus it gave lower percentage of yield and conversion of FFAs into biodiesel.Thus, enzyme loading investigation was done to limit the use of water. It was found that enzyme loading at 10U with water content of 7% volume of water per volume of SPO (v/v SPO) gave higher percentage of yield and conversion of FFAs into biodiesel. It was also found that the addition of tert-butanol with 1:1 tert-butanol-to-SPO molar ratio increased the percentage of the yield and conversion of FFAs into biodiesel by 80.54% and 25.68% respectively. 2012 Conference or Workshop Item REM application/pdf en http://irep.iium.edu.my/42416/1/Full_Paper_-_ID_O124.pdf application/pdf en http://irep.iium.edu.my/42416/4/42416.pdf Nasaruddin, Ricca Rahman and Alam, Md. Zahangir and Jami, Mohammed Saedi (2012) Study of solvent system for biodiesel production from Sludge Palm Oil (SPO) by enzymatic transesterification. In: International Conference on Biomass for Biofuels and Value-Added Products (ICBBVAP) 2012, 23-24 October 2012, Kuala Lumpur, Malaysia. http://icbbvap2012.ump.edu.my/program.html
institution Universiti Islam Antarabangsa Malaysia
building IIUM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider International Islamic University Malaysia
content_source IIUM Repository (IREP)
url_provider http://irep.iium.edu.my/
language English
English
topic TP155 Chemical engineering
spellingShingle TP155 Chemical engineering
Nasaruddin, Ricca Rahman
Alam, Md. Zahangir
Jami, Mohammed Saedi
Study of solvent system for biodiesel production from Sludge Palm Oil (SPO) by enzymatic transesterification
description Biodiesel is a non-toxic renewable fuel that has been highly demanded because it reduces the emission of air pollutants, thus a good alternative for the petroleum-derived fuel which is now having depletion, unstable price escalation and causes environmental problems. In this study, sludge palm oil (SPO) which is a low cost and abundantly produced waste oil was investigated to produce biodiesel by direct enzymatic transesterification using lipase. The lipase was produced locally by Candida cylindracea from a low cost basal medium, palm oil mill effluent (POME) in order to eliminate the higher cost of commercial lipases. Several factors in solvent system were studied to enhance the biodiesel production. Ethanol was selected as the acyl acceptor because it gave higherpercentage of yield and conversion of free fatty acids (FFAs) into biodiesel than the methanol. The optimum ethanol-to-SPO molar ratio was found to be 4:1 while the increasing of water content reduced the activity of the lipase thus it gave lower percentage of yield and conversion of FFAs into biodiesel.Thus, enzyme loading investigation was done to limit the use of water. It was found that enzyme loading at 10U with water content of 7% volume of water per volume of SPO (v/v SPO) gave higher percentage of yield and conversion of FFAs into biodiesel. It was also found that the addition of tert-butanol with 1:1 tert-butanol-to-SPO molar ratio increased the percentage of the yield and conversion of FFAs into biodiesel by 80.54% and 25.68% respectively.
format Conference or Workshop Item
author Nasaruddin, Ricca Rahman
Alam, Md. Zahangir
Jami, Mohammed Saedi
author_facet Nasaruddin, Ricca Rahman
Alam, Md. Zahangir
Jami, Mohammed Saedi
author_sort Nasaruddin, Ricca Rahman
title Study of solvent system for biodiesel production from Sludge Palm Oil (SPO) by enzymatic transesterification
title_short Study of solvent system for biodiesel production from Sludge Palm Oil (SPO) by enzymatic transesterification
title_full Study of solvent system for biodiesel production from Sludge Palm Oil (SPO) by enzymatic transesterification
title_fullStr Study of solvent system for biodiesel production from Sludge Palm Oil (SPO) by enzymatic transesterification
title_full_unstemmed Study of solvent system for biodiesel production from Sludge Palm Oil (SPO) by enzymatic transesterification
title_sort study of solvent system for biodiesel production from sludge palm oil (spo) by enzymatic transesterification
publishDate 2012
url http://irep.iium.edu.my/42416/1/Full_Paper_-_ID_O124.pdf
http://irep.iium.edu.my/42416/4/42416.pdf
http://irep.iium.edu.my/42416/
http://icbbvap2012.ump.edu.my/program.html
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score 13.211869