Cover Image

Effect of Water on Removal Efficiency of Sulfur-Containing Compounds from Crude Oil Models Using Ionic Liquids

The objective of the project is to determine the effect of water on sulfur-compounds removal efficiency of ionic liquids from crude oil models using ionic liquids. Six types of Ionic Liquids (ILs) were employed: - Bmim OcSO4 (1-butyl-3-methylimidazolium octylsulfate) - Bmim OTf (1-butyl-3-methyli...

Full description

Saved in:
Bibliographic Details
Main Author: NURUL NADIAH BINTI NOOR AZLI, NURUL NADIAH
Format: Final Year Project
Language:English
Published: Universiti Teknologi Petronas 2009
Subjects:
TP Chemical technology
Online Access:http://utpedia.utp.edu.my/943/1/NURUL_NADIAH_BINTI_NOOR_AZLI_FYP_2.pdf
http://utpedia.utp.edu.my/943/
Tags: Add Tag
No Tags, Be the first to tag this record!
id my-utp-utpedia.943
record_format eprints
spelling my-utp-utpedia.9432017-01-25T09:44:35Z http://utpedia.utp.edu.my/943/ Effect of Water on Removal Efficiency of Sulfur-Containing Compounds from Crude Oil Models Using Ionic Liquids NURUL NADIAH BINTI NOOR AZLI, NURUL NADIAH TP Chemical technology The objective of the project is to determine the effect of water on sulfur-compounds removal efficiency of ionic liquids from crude oil models using ionic liquids. Six types of Ionic Liquids (ILs) were employed: - Bmim OcSO4 (1-butyl-3-methylimidazolium octylsulfate) - Bmim OTf (1-butyl-3-methylimidazolium trifluoromethanesulfonate) - Hmim NTf2 (1-hexyl-3-methylimidazolium bis {(trifluoromethyl) sulfonyl} amide ) - Mmim DMP (1-methyl-3-methylimidazolium dimethylphosphate) - Emim DEP (1-ethyl-3-methylimidazolium diethyl phosphate) - Bmim DBP (1-butyl-3-methylimidazolium-dibutyl-phosphate) All ILs were exposed to the surroundings for four hours, and the water content of each IL were monitored as a fraction of time using Karl-Fisher Titration. The sulfur removal efficiency was also determined. After four hours of exposure, the water content for all the ionic liquids increased by 36.2%, 43.5%, 211.7%, 396.6%, 487.1%, and 1192.9% for Bmim OcSO4, Bmim DBP, Mmim DMP, Emim DEP, Hmim NTf2 and Bmim OTf. After four hours of exposure, all ILs showed that the sulfur removal efficiency decreased by 25.5%, 33.4%, 1.6%, 10.9%, 5.4% and 3.2% for Emim DEP, Hmim NTf2, Bmim OTf, Bmim OcSO4, Bmim DBP and Mmim DMP. Bmim OTf although has the highest capacity to absorb water, it displayed the lowest sensitivity to the effect of water on sulfur of water on sulfur removal efficiency. Thus, further work can be done to test on the capability of Bmim Otf to remove sulfur with the presence of water. Universiti Teknologi Petronas 2009 Final Year Project NonPeerReviewed application/pdf en http://utpedia.utp.edu.my/943/1/NURUL_NADIAH_BINTI_NOOR_AZLI_FYP_2.pdf NURUL NADIAH BINTI NOOR AZLI, NURUL NADIAH (2009) Effect of Water on Removal Efficiency of Sulfur-Containing Compounds from Crude Oil Models Using Ionic Liquids. Universiti Teknologi Petronas, Seri Iskandar,Tronoh,Perak. (Unpublished)
institution Universiti Teknologi Petronas
building UTP Resource Centre
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Teknologi Petronas
content_source UTP Electronic and Digitized Intellectual Asset
url_provider http://utpedia.utp.edu.my/
language English
topic TP Chemical technology
spellingShingle TP Chemical technology
NURUL NADIAH BINTI NOOR AZLI, NURUL NADIAH
Effect of Water on Removal Efficiency of Sulfur-Containing Compounds from Crude Oil Models Using Ionic Liquids
description The objective of the project is to determine the effect of water on sulfur-compounds removal efficiency of ionic liquids from crude oil models using ionic liquids. Six types of Ionic Liquids (ILs) were employed: - Bmim OcSO4 (1-butyl-3-methylimidazolium octylsulfate) - Bmim OTf (1-butyl-3-methylimidazolium trifluoromethanesulfonate) - Hmim NTf2 (1-hexyl-3-methylimidazolium bis {(trifluoromethyl) sulfonyl} amide ) - Mmim DMP (1-methyl-3-methylimidazolium dimethylphosphate) - Emim DEP (1-ethyl-3-methylimidazolium diethyl phosphate) - Bmim DBP (1-butyl-3-methylimidazolium-dibutyl-phosphate) All ILs were exposed to the surroundings for four hours, and the water content of each IL were monitored as a fraction of time using Karl-Fisher Titration. The sulfur removal efficiency was also determined. After four hours of exposure, the water content for all the ionic liquids increased by 36.2%, 43.5%, 211.7%, 396.6%, 487.1%, and 1192.9% for Bmim OcSO4, Bmim DBP, Mmim DMP, Emim DEP, Hmim NTf2 and Bmim OTf. After four hours of exposure, all ILs showed that the sulfur removal efficiency decreased by 25.5%, 33.4%, 1.6%, 10.9%, 5.4% and 3.2% for Emim DEP, Hmim NTf2, Bmim OTf, Bmim OcSO4, Bmim DBP and Mmim DMP. Bmim OTf although has the highest capacity to absorb water, it displayed the lowest sensitivity to the effect of water on sulfur of water on sulfur removal efficiency. Thus, further work can be done to test on the capability of Bmim Otf to remove sulfur with the presence of water.
format Final Year Project
author NURUL NADIAH BINTI NOOR AZLI, NURUL NADIAH
author_facet NURUL NADIAH BINTI NOOR AZLI, NURUL NADIAH
author_sort NURUL NADIAH BINTI NOOR AZLI, NURUL NADIAH
title Effect of Water on Removal Efficiency of Sulfur-Containing Compounds from Crude Oil Models Using Ionic Liquids
title_short Effect of Water on Removal Efficiency of Sulfur-Containing Compounds from Crude Oil Models Using Ionic Liquids
title_full Effect of Water on Removal Efficiency of Sulfur-Containing Compounds from Crude Oil Models Using Ionic Liquids
title_fullStr Effect of Water on Removal Efficiency of Sulfur-Containing Compounds from Crude Oil Models Using Ionic Liquids
title_full_unstemmed Effect of Water on Removal Efficiency of Sulfur-Containing Compounds from Crude Oil Models Using Ionic Liquids
title_sort effect of water on removal efficiency of sulfur-containing compounds from crude oil models using ionic liquids
publisher Universiti Teknologi Petronas
publishDate 2009
url http://utpedia.utp.edu.my/943/1/NURUL_NADIAH_BINTI_NOOR_AZLI_FYP_2.pdf
http://utpedia.utp.edu.my/943/
_version_ 1739830726676709376
score 13.211869

Similar Items