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Oxidative Dusulfurization of Dibenzothiophene from Model Oil (dodecane) using [bmim][Cl] as an Extracting Agent

The oxidative desulfurization of dibenzothiophene (DBT) from model oil (in dodecane) was carried out using ionic liquid as the extractant and catalyst, and hydrogen peroxide in combustion as an oxidant. The ionic liquid used were 1-Butyl-3-Methylimidazolium Chlorine [bmim]Cl. The effect of the amoun...

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Main Author: Jinal, Mohd. Ridzhuan
Format: Final Year Project
Language:English
Published: Universiti Teknologi PETRONAS 2013
Subjects:
TP Chemical technology
Online Access:http://utpedia.utp.edu.my/8480/1/My%20FYP%20Final%20Dissertation.pdf
http://utpedia.utp.edu.my/8480/
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spelling my-utp-utpedia.84802013-10-09T11:07:24Z http://utpedia.utp.edu.my/8480/ Oxidative Dusulfurization of Dibenzothiophene from Model Oil (dodecane) using [bmim][Cl] as an Extracting Agent Jinal, Mohd. Ridzhuan TP Chemical technology The oxidative desulfurization of dibenzothiophene (DBT) from model oil (in dodecane) was carried out using ionic liquid as the extractant and catalyst, and hydrogen peroxide in combustion as an oxidant. The ionic liquid used were 1-Butyl-3-Methylimidazolium Chlorine [bmim]Cl. The effect of the amount of hydrogen peroxide on oxidative desulfurization was first investigated without usage of ionic liquid at room temperature. The result indicate that greater amount of hydrogen peroxide yield higher desulfurization and the maximum desulfurization in this study were 17.32% removal at the molar ratio of hydrogen peroxide to S-content was 10:1. With the usage of ionic liquid and the molar ratio 10:1(hydrogen peroxide to S-content), the efficiency of sulfur removal from model oil was enhanced to 21.02% removal, it was increase significantly in term of sulfur removal and removal time. The mixing time was 300 minutes at room temperature. The result indicates the potential of ionic liquids as the extractant and catalyst for oxidative desulfurization of hydrocarbon fuels. Universiti Teknologi PETRONAS 2013-05 Final Year Project NonPeerReviewed application/pdf en http://utpedia.utp.edu.my/8480/1/My%20FYP%20Final%20Dissertation.pdf Jinal, Mohd. Ridzhuan (2013) Oxidative Dusulfurization of Dibenzothiophene from Model Oil (dodecane) using [bmim][Cl] as an Extracting Agent. Universiti Teknologi PETRONAS. (Unpublished)
institution Universiti Teknologi Petronas
building UTP Resource Centre
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Teknologi Petronas
content_source UTP Electronic and Digitized Intellectual Asset
url_provider http://utpedia.utp.edu.my/
language English
topic TP Chemical technology
spellingShingle TP Chemical technology
Jinal, Mohd. Ridzhuan
Oxidative Dusulfurization of Dibenzothiophene from Model Oil (dodecane) using [bmim][Cl] as an Extracting Agent
description The oxidative desulfurization of dibenzothiophene (DBT) from model oil (in dodecane) was carried out using ionic liquid as the extractant and catalyst, and hydrogen peroxide in combustion as an oxidant. The ionic liquid used were 1-Butyl-3-Methylimidazolium Chlorine [bmim]Cl. The effect of the amount of hydrogen peroxide on oxidative desulfurization was first investigated without usage of ionic liquid at room temperature. The result indicate that greater amount of hydrogen peroxide yield higher desulfurization and the maximum desulfurization in this study were 17.32% removal at the molar ratio of hydrogen peroxide to S-content was 10:1. With the usage of ionic liquid and the molar ratio 10:1(hydrogen peroxide to S-content), the efficiency of sulfur removal from model oil was enhanced to 21.02% removal, it was increase significantly in term of sulfur removal and removal time. The mixing time was 300 minutes at room temperature. The result indicates the potential of ionic liquids as the extractant and catalyst for oxidative desulfurization of hydrocarbon fuels.
format Final Year Project
author Jinal, Mohd. Ridzhuan
author_facet Jinal, Mohd. Ridzhuan
author_sort Jinal, Mohd. Ridzhuan
title Oxidative Dusulfurization of Dibenzothiophene from Model Oil (dodecane) using [bmim][Cl] as an Extracting Agent
title_short Oxidative Dusulfurization of Dibenzothiophene from Model Oil (dodecane) using [bmim][Cl] as an Extracting Agent
title_full Oxidative Dusulfurization of Dibenzothiophene from Model Oil (dodecane) using [bmim][Cl] as an Extracting Agent
title_fullStr Oxidative Dusulfurization of Dibenzothiophene from Model Oil (dodecane) using [bmim][Cl] as an Extracting Agent
title_full_unstemmed Oxidative Dusulfurization of Dibenzothiophene from Model Oil (dodecane) using [bmim][Cl] as an Extracting Agent
title_sort oxidative dusulfurization of dibenzothiophene from model oil (dodecane) using [bmim][cl] as an extracting agent
publisher Universiti Teknologi PETRONAS
publishDate 2013
url http://utpedia.utp.edu.my/8480/1/My%20FYP%20Final%20Dissertation.pdf
http://utpedia.utp.edu.my/8480/
_version_ 1739831580274196480
score 13.211869

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