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Kinetic Parameter Estimation in Alkylation of Benzene with 1-Decene through Hybrid Particle Swarm Optimization

In this project, a kinetic model for alkylation of benzene with 1-decene over acid catalyst is presented. The desirable product from this alkylation process is 2- phenyldecane which is formed via double bond isomerization and aromatic alkylation reaction. 2-phenyldecane is formed by alkylation of...

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Main Author: Mohd Zulkefle, Nurul Farihah
Format: Final Year Project
Language:English
Published: UNIVERSITI TEKNOLOGI PETRONAS 2012
Subjects:
TP Chemical technology
Online Access:http://utpedia.utp.edu.my/6178/1/FYPII_NURUL_FARIHAH_12164.pdf
http://utpedia.utp.edu.my/6178/
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spelling my-utp-utpedia.61782017-01-25T09:40:08Z http://utpedia.utp.edu.my/6178/ Kinetic Parameter Estimation in Alkylation of Benzene with 1-Decene through Hybrid Particle Swarm Optimization Mohd Zulkefle, Nurul Farihah TP Chemical technology In this project, a kinetic model for alkylation of benzene with 1-decene over acid catalyst is presented. The desirable product from this alkylation process is 2- phenyldecane which is formed via double bond isomerization and aromatic alkylation reaction. 2-phenyldecane is formed by alkylation of benzene with alkylcarbenium ion. Alkylcarbenium ions are produced from protonation and deprotonation reaction of 1- decene isomers. In this reaction, kinetic constants follow Arhenius equation. Preexponantial factors of the elementary step were calculated from first principle. Activation energies of elementary steps were estimated by using Hybrid Particle Swarm Optimization (HPSO) algorithm. Parameter estimation was performed by varying the initial guess of PSO algorithm which will conduct global search of the parameters. Afterwards, the solution obtained using PSO algorithm is given as initial guesses to the Levenberg–Marquardt algorithm to determine the improved optimal solution. Parameter estimation was carried out using simulated data and the activation energies are constant with the assumed values. UNIVERSITI TEKNOLOGI PETRONAS 2012-09 Final Year Project NonPeerReviewed application/pdf en http://utpedia.utp.edu.my/6178/1/FYPII_NURUL_FARIHAH_12164.pdf Mohd Zulkefle, Nurul Farihah (2012) Kinetic Parameter Estimation in Alkylation of Benzene with 1-Decene through Hybrid Particle Swarm Optimization. UNIVERSITI TEKNOLOGI PETRONAS, UNIVERSITI TEKNOLOGI PETRONAS. (Unpublished)
institution Universiti Teknologi Petronas
building UTP Resource Centre
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Teknologi Petronas
content_source UTP Electronic and Digitized Intellectual Asset
url_provider http://utpedia.utp.edu.my/
language English
topic TP Chemical technology
spellingShingle TP Chemical technology
Mohd Zulkefle, Nurul Farihah
Kinetic Parameter Estimation in Alkylation of Benzene with 1-Decene through Hybrid Particle Swarm Optimization
description In this project, a kinetic model for alkylation of benzene with 1-decene over acid catalyst is presented. The desirable product from this alkylation process is 2- phenyldecane which is formed via double bond isomerization and aromatic alkylation reaction. 2-phenyldecane is formed by alkylation of benzene with alkylcarbenium ion. Alkylcarbenium ions are produced from protonation and deprotonation reaction of 1- decene isomers. In this reaction, kinetic constants follow Arhenius equation. Preexponantial factors of the elementary step were calculated from first principle. Activation energies of elementary steps were estimated by using Hybrid Particle Swarm Optimization (HPSO) algorithm. Parameter estimation was performed by varying the initial guess of PSO algorithm which will conduct global search of the parameters. Afterwards, the solution obtained using PSO algorithm is given as initial guesses to the Levenberg–Marquardt algorithm to determine the improved optimal solution. Parameter estimation was carried out using simulated data and the activation energies are constant with the assumed values.
format Final Year Project
author Mohd Zulkefle, Nurul Farihah
author_facet Mohd Zulkefle, Nurul Farihah
author_sort Mohd Zulkefle, Nurul Farihah
title Kinetic Parameter Estimation in Alkylation of Benzene with 1-Decene through Hybrid Particle Swarm Optimization
title_short Kinetic Parameter Estimation in Alkylation of Benzene with 1-Decene through Hybrid Particle Swarm Optimization
title_full Kinetic Parameter Estimation in Alkylation of Benzene with 1-Decene through Hybrid Particle Swarm Optimization
title_fullStr Kinetic Parameter Estimation in Alkylation of Benzene with 1-Decene through Hybrid Particle Swarm Optimization
title_full_unstemmed Kinetic Parameter Estimation in Alkylation of Benzene with 1-Decene through Hybrid Particle Swarm Optimization
title_sort kinetic parameter estimation in alkylation of benzene with 1-decene through hybrid particle swarm optimization
publisher UNIVERSITI TEKNOLOGI PETRONAS
publishDate 2012
url http://utpedia.utp.edu.my/6178/1/FYPII_NURUL_FARIHAH_12164.pdf
http://utpedia.utp.edu.my/6178/
_version_ 1739831319649583104
score 13.211869

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