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Synthesis and characterizations of ethylbutyldithiocarbamate compounds: crystal structure of bismuth(III) ethylbutyldithiocarbamate

A new series of ethylbutyldithiocarbamate compounds have been synthesized. The compounds made of Zn(II), Cu(II), Ni(II), Pb(II), Sb(III) and Bi(III) were prepared by reacting the respective metal salts with ethylbutylamine and carbon disulphide using "in situ" method. Results of elemental...

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Main Authors: Karimah Kassim,, Ibrahim Baba,, Yang Farina ,, Abdul Hamid Othman,, H.K. Fun,
Format: Article
Published: Universiti Kebangsaan Malaysia 2002
Online Access:http://journalarticle.ukm.my/3827/
http://www.ukm.my/jsm/english_journals/vol31_2002/vol31_02page101-108.html
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spelling my-ukm.journal.38272012-05-04T04:14:55Z http://journalarticle.ukm.my/3827/ Synthesis and characterizations of ethylbutyldithiocarbamate compounds: crystal structure of bismuth(III) ethylbutyldithiocarbamate Karimah Kassim, Ibrahim Baba, Yang Farina , Abdul Hamid Othman, H.K. Fun, A new series of ethylbutyldithiocarbamate compounds have been synthesized. The compounds made of Zn(II), Cu(II), Ni(II), Pb(II), Sb(III) and Bi(III) were prepared by reacting the respective metal salts with ethylbutylamine and carbon disulphide using "in situ" method. Results of elemental analysis showed that the isolated compounds have the general formula, M[S2CNR1RZ2]n (n = 2; M = Zn(II), Cu(II), Ni(II), Pb(II), and n = 3; M = Sb(III) and Bi(III)). Infrared spectra of the compounds showed the thioureido v(C-N) bands in the regions 1468 – 1497 cm-1. The (C-S) bands appeared in the region 956 – 997 cm-1 while the v(M-S) bands appeared in the region 300 – 400 cm-1. The 1H NMR signals indicated ethyl- and butyl- in the region 0.40 – 3.85 ppm. The 13C NMR spectra of zinc(II) and lead(II) showed a resonance in the region 202.0 ppm, which attributed to the carbon atom of NCS2 group. Tris(N-ethyl-N-butyldithiocarbamato-S) bismuth(III) is pentagonal pyramid distorted with triclinic system with P1, a = 10.5120(1)Å, b = 10.5128(1)Å, b = 10.5128(1)Å, c = 14.5755(1)Å, α = 99.927(1)o, γ = 103.3383(1) and Z = 2. Universiti Kebangsaan Malaysia 2002 Article PeerReviewed Karimah Kassim, and Ibrahim Baba, and Yang Farina , and Abdul Hamid Othman, and H.K. Fun, (2002) Synthesis and characterizations of ethylbutyldithiocarbamate compounds: crystal structure of bismuth(III) ethylbutyldithiocarbamate. Sains Malaysiana, 31 . pp. 101-108. ISSN 0126-6039 http://www.ukm.my/jsm/english_journals/vol31_2002/vol31_02page101-108.html
institution Universiti Kebangsaan Malaysia
building Perpustakaan Tun Sri Lanang Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Kebangsaan Malaysia
content_source UKM Journal Article Repository
url_provider http://journalarticle.ukm.my/
description A new series of ethylbutyldithiocarbamate compounds have been synthesized. The compounds made of Zn(II), Cu(II), Ni(II), Pb(II), Sb(III) and Bi(III) were prepared by reacting the respective metal salts with ethylbutylamine and carbon disulphide using "in situ" method. Results of elemental analysis showed that the isolated compounds have the general formula, M[S2CNR1RZ2]n (n = 2; M = Zn(II), Cu(II), Ni(II), Pb(II), and n = 3; M = Sb(III) and Bi(III)). Infrared spectra of the compounds showed the thioureido v(C-N) bands in the regions 1468 – 1497 cm-1. The (C-S) bands appeared in the region 956 – 997 cm-1 while the v(M-S) bands appeared in the region 300 – 400 cm-1. The 1H NMR signals indicated ethyl- and butyl- in the region 0.40 – 3.85 ppm. The 13C NMR spectra of zinc(II) and lead(II) showed a resonance in the region 202.0 ppm, which attributed to the carbon atom of NCS2 group. Tris(N-ethyl-N-butyldithiocarbamato-S) bismuth(III) is pentagonal pyramid distorted with triclinic system with P1, a = 10.5120(1)Å, b = 10.5128(1)Å, b = 10.5128(1)Å, c = 14.5755(1)Å, α = 99.927(1)o, γ = 103.3383(1) and Z = 2.
format Article
author Karimah Kassim,
Ibrahim Baba,
Yang Farina ,
Abdul Hamid Othman,
H.K. Fun,
spellingShingle Karimah Kassim,
Ibrahim Baba,
Yang Farina ,
Abdul Hamid Othman,
H.K. Fun,
Synthesis and characterizations of ethylbutyldithiocarbamate compounds: crystal structure of bismuth(III) ethylbutyldithiocarbamate
author_facet Karimah Kassim,
Ibrahim Baba,
Yang Farina ,
Abdul Hamid Othman,
H.K. Fun,
author_sort Karimah Kassim,
title Synthesis and characterizations of ethylbutyldithiocarbamate compounds: crystal structure of bismuth(III) ethylbutyldithiocarbamate
title_short Synthesis and characterizations of ethylbutyldithiocarbamate compounds: crystal structure of bismuth(III) ethylbutyldithiocarbamate
title_full Synthesis and characterizations of ethylbutyldithiocarbamate compounds: crystal structure of bismuth(III) ethylbutyldithiocarbamate
title_fullStr Synthesis and characterizations of ethylbutyldithiocarbamate compounds: crystal structure of bismuth(III) ethylbutyldithiocarbamate
title_full_unstemmed Synthesis and characterizations of ethylbutyldithiocarbamate compounds: crystal structure of bismuth(III) ethylbutyldithiocarbamate
title_sort synthesis and characterizations of ethylbutyldithiocarbamate compounds: crystal structure of bismuth(iii) ethylbutyldithiocarbamate
publisher Universiti Kebangsaan Malaysia
publishDate 2002
url http://journalarticle.ukm.my/3827/
http://www.ukm.my/jsm/english_journals/vol31_2002/vol31_02page101-108.html
_version_ 1643735863604019200
score 13.211869

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