Incorporating 1-butyl-3-methylimidazolium chloride ionic liquid into iota carrageenan solid biopolymer electrolyte for electrochemical devices application
Solid biopolymer electrolyte based on iota carrageenan and 1-butyl-3-methylimidazolium chloride, [Bmim]Cl were successfully prepared by solution casting technique. Weight percentage (wt. %) of [Bmim]Cl was varied from 0 wt. % to 100 wt. % and the highest ionic conductivity achieved was 2.70 × 10-3 S...
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Penerbit Universiti Kebangsaan Malaysia
2020
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Online Access: | http://journalarticle.ukm.my/14762/1/ARTIKEL%208.pdf http://journalarticle.ukm.my/14762/ http://www.ukm.my/jsm/malay_journals/jilid49bil2_2020/KandunganJilid49Bil2_2020.html |
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my-ukm.journal.147622020-06-22T08:09:41Z http://journalarticle.ukm.my/14762/ Incorporating 1-butyl-3-methylimidazolium chloride ionic liquid into iota carrageenan solid biopolymer electrolyte for electrochemical devices application Nur Azlina Abdul Ghani, Farah Hannan Anuar, Azizan Ahmad, Nadhratun Naiim Mobarak, Intan Juliana Shamsudin, Mariah Zuliana Dzulkipli, Nur Hasyareeda Hassan, Solid biopolymer electrolyte based on iota carrageenan and 1-butyl-3-methylimidazolium chloride, [Bmim]Cl were successfully prepared by solution casting technique. Weight percentage (wt. %) of [Bmim]Cl was varied from 0 wt. % to 100 wt. % and the highest ionic conductivity achieved was 2.70 × 10-3 S cm-1 for 70 wt. % [Bmim]Cl at ambient temperature. The interaction between iota carrageenan and [Bmim]Cl was confirmed by the formation of new peak on the ATR-FTIR spectrum. The reduction in crystallinity of iota carrageenan as the inclusion of [Bmim]Cl was observed based on X-ray diffraction (XRD) spectroscopy. FESEM morphology showed the compatibility and homogeneity between iota carrageenan and [Bmim]Cl while the LSV analysis showed that solid biopolymer electrolyte-based iota carrageenan-[Bmim]Cl possess high electrochemical stability up to 3.0 V. The transference number (TN) analysis indicated that ions are the main contributor for the ionic conduction. Penerbit Universiti Kebangsaan Malaysia 2020-02 Article PeerReviewed application/pdf en http://journalarticle.ukm.my/14762/1/ARTIKEL%208.pdf Nur Azlina Abdul Ghani, and Farah Hannan Anuar, and Azizan Ahmad, and Nadhratun Naiim Mobarak, and Intan Juliana Shamsudin, and Mariah Zuliana Dzulkipli, and Nur Hasyareeda Hassan, (2020) Incorporating 1-butyl-3-methylimidazolium chloride ionic liquid into iota carrageenan solid biopolymer electrolyte for electrochemical devices application. Sains Malaysiana, 49 (2). pp. 305-313. ISSN 0126-6039 http://www.ukm.my/jsm/malay_journals/jilid49bil2_2020/KandunganJilid49Bil2_2020.html |
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Solid biopolymer electrolyte based on iota carrageenan and 1-butyl-3-methylimidazolium chloride, [Bmim]Cl were successfully prepared by solution casting technique. Weight percentage (wt. %) of [Bmim]Cl was varied from 0 wt. % to 100 wt. % and the highest ionic conductivity achieved was 2.70 × 10-3 S cm-1 for 70 wt. % [Bmim]Cl at ambient temperature. The interaction between iota carrageenan and [Bmim]Cl was confirmed by the formation of new peak on the ATR-FTIR spectrum. The reduction in crystallinity of iota carrageenan as the inclusion of [Bmim]Cl was observed based on X-ray diffraction (XRD) spectroscopy. FESEM morphology showed the compatibility and homogeneity between iota carrageenan and [Bmim]Cl while the LSV analysis showed that solid biopolymer electrolyte-based iota carrageenan-[Bmim]Cl possess high electrochemical stability up to 3.0 V. The transference number (TN) analysis indicated that ions are the main contributor for the ionic conduction. |
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Nur Azlina Abdul Ghani, Farah Hannan Anuar, Azizan Ahmad, Nadhratun Naiim Mobarak, Intan Juliana Shamsudin, Mariah Zuliana Dzulkipli, Nur Hasyareeda Hassan, |
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Nur Azlina Abdul Ghani, Farah Hannan Anuar, Azizan Ahmad, Nadhratun Naiim Mobarak, Intan Juliana Shamsudin, Mariah Zuliana Dzulkipli, Nur Hasyareeda Hassan, Incorporating 1-butyl-3-methylimidazolium chloride ionic liquid into iota carrageenan solid biopolymer electrolyte for electrochemical devices application |
author_facet |
Nur Azlina Abdul Ghani, Farah Hannan Anuar, Azizan Ahmad, Nadhratun Naiim Mobarak, Intan Juliana Shamsudin, Mariah Zuliana Dzulkipli, Nur Hasyareeda Hassan, |
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Nur Azlina Abdul Ghani, |
title |
Incorporating 1-butyl-3-methylimidazolium chloride ionic liquid into iota carrageenan solid biopolymer electrolyte for electrochemical devices application |
title_short |
Incorporating 1-butyl-3-methylimidazolium chloride ionic liquid into iota carrageenan solid biopolymer electrolyte for electrochemical devices application |
title_full |
Incorporating 1-butyl-3-methylimidazolium chloride ionic liquid into iota carrageenan solid biopolymer electrolyte for electrochemical devices application |
title_fullStr |
Incorporating 1-butyl-3-methylimidazolium chloride ionic liquid into iota carrageenan solid biopolymer electrolyte for electrochemical devices application |
title_full_unstemmed |
Incorporating 1-butyl-3-methylimidazolium chloride ionic liquid into iota carrageenan solid biopolymer electrolyte for electrochemical devices application |
title_sort |
incorporating 1-butyl-3-methylimidazolium chloride ionic liquid into iota carrageenan solid biopolymer electrolyte for electrochemical devices application |
publisher |
Penerbit Universiti Kebangsaan Malaysia |
publishDate |
2020 |
url |
http://journalarticle.ukm.my/14762/1/ARTIKEL%208.pdf http://journalarticle.ukm.my/14762/ http://www.ukm.my/jsm/malay_journals/jilid49bil2_2020/KandunganJilid49Bil2_2020.html |
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1671340601041223680 |
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13.211869 |