The effect of persulfate oxidation on the biodegradability of concentrated anaerobic stabilized leachate

Anaerobic stabilized landfill leachate was treated by persulfate (S2O82−) oxidation. The effect of three factors namely; persulfate dosage, pH and reaction time on COD and NH3-N removals; was studied. The results of analysis of variance (ANOVA) showed that the selected factors significantly affected...

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Bibliographic Details
Main Authors: Hilles, Ahmed H., Abu Amr, Salem S, Alkarkhi, Abbas F.M., Hossain, Md Sohrab
Format: Article
Language:English
Published: Penerbit Universiti Kebangsaan Malaysia 2019
Online Access:http://journalarticle.ukm.my/14421/1/09%20Ahmed%20H.%20Hilles.pdf
http://journalarticle.ukm.my/14421/
http://www.ukm.my/jsm/malay_journals/jilid48bil11_2019/KandunganJilid48Bil11_2019.html
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Summary:Anaerobic stabilized landfill leachate was treated by persulfate (S2O82−) oxidation. The effect of three factors namely; persulfate dosage, pH and reaction time on COD and NH3-N removals; was studied. The results of analysis of variance (ANOVA) showed that the selected factors significantly affected the percentage of COD and NH3-N removals. Furthermore, the maximum removal was achieved at 60 min of persulfate oxidation, a COD/S2O82− ratio (1 g/4.2 g), and pH7, the percentage of removals for COD and NH3-N were 45% and 55%, respectively. The effect of persulfate oxidation on the biodegradability of leachate was also investigated. The results showed that the BOD5/COD ratio improved from 0.09 to 0.1. The oxidation enhanced the biodegradable (CODbi) from 36% to 57%. Hence, persulfate is suitable to pre-treat highly-concentrated stabilized leachate. This process should follow the organic degradation and ammonia removal followed by biological treatment processes.