N,N'-bi-(5-methyl-methylsalicylidene)-2,2-dimethylpropane-1, 3-diamine palladium(ii): catalyst for heck reaction
A new palladium(II) complex of a Schiff base ligand, “N,N’-bis-(5-methyl-methylsalicylidene)-2,2-dimethylpropane-1,3-diamine� has been synthesized and characterized by analytical and spectroscopic data such as FTIR, 1H and 13C NMR spectroscopy, X-ray crystallography and CHN elemental analysis....
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| Format: | Article |
| Language: | en |
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The Malaysian Analytical Sciences Society (ANALIS)
2007
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| Online Access: | http://eprints.utm.my/8157/1/MustaffaShamsuddin2007_NNBis5MethylMethylsalicylidene.pdf http://eprints.utm.my/8157/ http://www.ukm.my/mjas/v11_n1/15_25PC1-MYCATpaper-1.pdf |
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| author | Wan Ibrahim, Wan Nazihah Shamsuddin, Mustaffa M. Yamin, Bohari |
| author_facet | Wan Ibrahim, Wan Nazihah Shamsuddin, Mustaffa M. Yamin, Bohari |
| author_sort | Wan Ibrahim, Wan Nazihah |
| building | UTM Library |
| collection | Institutional Repository |
| content_provider | Universiti Teknologi Malaysia |
| content_source | UTM Institutional Repository |
| continent | Asia |
| country | Malaysia |
| description | A new palladium(II) complex of a Schiff base ligand, “N,N’-bis-(5-methyl-methylsalicylidene)-2,2-dimethylpropane-1,3-diamine� has been synthesized and characterized by analytical and spectroscopic data such as FTIR, 1H and 13C NMR spectroscopy, X-ray crystallography and CHN elemental analysis. The ligand acted as a N,N,O,O tetradentate ligand which the metal is coordinated to the azomethine nitrogen and phenolic oxygen. The palladium complex was tested as catalyst in the Heck reaction of iodobenzene with methyl acrylate in the presence of sodium hydrogen carbonate as base N,N-dimethylacetamide at reflux temperature (120°C). The activity of the catalyst was monitored by 1H NMR |
| format | Article |
| id | my.utm.eprints-8157 |
| institution | Universiti Teknologi Malaysia |
| language | en |
| publishDate | 2007 |
| publisher | The Malaysian Analytical Sciences Society (ANALIS) |
| record_format | eprints |
| spelling | my.utm.eprints-81572012-11-19T05:05:16Z http://eprints.utm.my/8157/ N,N'-bi-(5-methyl-methylsalicylidene)-2,2-dimethylpropane-1, 3-diamine palladium(ii): catalyst for heck reaction Wan Ibrahim, Wan Nazihah Shamsuddin, Mustaffa M. Yamin, Bohari QD Chemistry A new palladium(II) complex of a Schiff base ligand, “N,N’-bis-(5-methyl-methylsalicylidene)-2,2-dimethylpropane-1,3-diamine� has been synthesized and characterized by analytical and spectroscopic data such as FTIR, 1H and 13C NMR spectroscopy, X-ray crystallography and CHN elemental analysis. The ligand acted as a N,N,O,O tetradentate ligand which the metal is coordinated to the azomethine nitrogen and phenolic oxygen. The palladium complex was tested as catalyst in the Heck reaction of iodobenzene with methyl acrylate in the presence of sodium hydrogen carbonate as base N,N-dimethylacetamide at reflux temperature (120°C). The activity of the catalyst was monitored by 1H NMR The Malaysian Analytical Sciences Society (ANALIS) 2007 Article PeerReviewed application/pdf en http://eprints.utm.my/8157/1/MustaffaShamsuddin2007_NNBis5MethylMethylsalicylidene.pdf Wan Ibrahim, Wan Nazihah and Shamsuddin, Mustaffa and M. Yamin, Bohari (2007) N,N'-bi-(5-methyl-methylsalicylidene)-2,2-dimethylpropane-1, 3-diamine palladium(ii): catalyst for heck reaction. The Malaysian Journal of Analytical Sciences, 11 (1). pp. 98-104. ISSN 1394-2506 http://www.ukm.my/mjas/v11_n1/15_25PC1-MYCATpaper-1.pdf |
| spellingShingle | QD Chemistry Wan Ibrahim, Wan Nazihah Shamsuddin, Mustaffa M. Yamin, Bohari N,N'-bi-(5-methyl-methylsalicylidene)-2,2-dimethylpropane-1, 3-diamine palladium(ii): catalyst for heck reaction |
| title | N,N'-bi-(5-methyl-methylsalicylidene)-2,2-dimethylpropane-1,
3-diamine palladium(ii): catalyst for heck reaction
|
| title_full | N,N'-bi-(5-methyl-methylsalicylidene)-2,2-dimethylpropane-1,
3-diamine palladium(ii): catalyst for heck reaction
|
| title_fullStr | N,N'-bi-(5-methyl-methylsalicylidene)-2,2-dimethylpropane-1,
3-diamine palladium(ii): catalyst for heck reaction
|
| title_full_unstemmed | N,N'-bi-(5-methyl-methylsalicylidene)-2,2-dimethylpropane-1,
3-diamine palladium(ii): catalyst for heck reaction
|
| title_short | N,N'-bi-(5-methyl-methylsalicylidene)-2,2-dimethylpropane-1,
3-diamine palladium(ii): catalyst for heck reaction
|
| title_sort | n,n'-bi-(5-methyl-methylsalicylidene)-2,2-dimethylpropane-1,
3-diamine palladium(ii): catalyst for heck reaction |
| topic | QD Chemistry |
| url | http://eprints.utm.my/8157/1/MustaffaShamsuddin2007_NNBis5MethylMethylsalicylidene.pdf http://eprints.utm.my/8157/ http://www.ukm.my/mjas/v11_n1/15_25PC1-MYCATpaper-1.pdf |
| url_provider | http://eprints.utm.my/ |