High temperature liquid chromatography of triazole fungicides on polybutadiene-coated zirconia stationary phase
High temperature liquid chromatography using water-rich and superheated water eluent is evaluated as a new approach for the separation of selected triazole fungicides, hexaconazole, tebuconazole, propiconazole, and difenoconazole. Using a polybutadiene-coated zirconia column at temperatures of 100â€...
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| Format: | Article |
| Language: | en |
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Elsevier Science B.V.
2004
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| Online Access: | http://eprints.utm.my/6860/1/MMSanagi2004_HighTemperatureLiquidChromatography.pdf http://eprints.utm.my/6860/ http://dx.doi.org/10.1016/j.chroma.2004.10.053 |
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| _version_ | 1845471707437989888 |
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| author | Sanagi, M. Marsin See, H. H. Wan Ibrahim, Wan Aini Abu Naim, Ahmedy |
| author_facet | Sanagi, M. Marsin See, H. H. Wan Ibrahim, Wan Aini Abu Naim, Ahmedy |
| author_sort | Sanagi, M. Marsin |
| building | UTM Library |
| collection | Institutional Repository |
| content_provider | Universiti Teknologi Malaysia |
| content_source | UTM Institutional Repository |
| continent | Asia |
| country | Malaysia |
| description | High temperature liquid chromatography using water-rich and superheated water eluent is evaluated as a new approach for the separation of selected triazole fungicides, hexaconazole, tebuconazole, propiconazole, and difenoconazole. Using a polybutadiene-coated zirconia column at temperatures of 100–150 oC, clear separations were achieved when 100% purified water was utilized as organic-free eluent. Excellent limits of detection down to pg level were obtained for the separation of the triazole fungicides under optimum conditions. Van’t Hoff plots for the separations were linear suggesting that no changes occurred in the retention mechanism over the temperature range studied. |
| format | Article |
| id | my.utm.eprints-6860 |
| institution | Universiti Teknologi Malaysia |
| language | en |
| publishDate | 2004 |
| publisher | Elsevier Science B.V. |
| record_format | eprints |
| spelling | my.utm.eprints-68602017-10-11T01:24:14Z http://eprints.utm.my/6860/ High temperature liquid chromatography of triazole fungicides on polybutadiene-coated zirconia stationary phase Sanagi, M. Marsin See, H. H. Wan Ibrahim, Wan Aini Abu Naim, Ahmedy QD Chemistry High temperature liquid chromatography using water-rich and superheated water eluent is evaluated as a new approach for the separation of selected triazole fungicides, hexaconazole, tebuconazole, propiconazole, and difenoconazole. Using a polybutadiene-coated zirconia column at temperatures of 100–150 oC, clear separations were achieved when 100% purified water was utilized as organic-free eluent. Excellent limits of detection down to pg level were obtained for the separation of the triazole fungicides under optimum conditions. Van’t Hoff plots for the separations were linear suggesting that no changes occurred in the retention mechanism over the temperature range studied. Elsevier Science B.V. 2004 Article PeerReviewed application/pdf en http://eprints.utm.my/6860/1/MMSanagi2004_HighTemperatureLiquidChromatography.pdf Sanagi, M. Marsin and See, H. H. and Wan Ibrahim, Wan Aini and Abu Naim, Ahmedy (2004) High temperature liquid chromatography of triazole fungicides on polybutadiene-coated zirconia stationary phase. Journal of Chromatography A, 1059 . pp. 95-101. ISSN 0021-9673 http://dx.doi.org/10.1016/j.chroma.2004.10.053 10.1016/j.chroma.2004.10.053 |
| spellingShingle | QD Chemistry Sanagi, M. Marsin See, H. H. Wan Ibrahim, Wan Aini Abu Naim, Ahmedy High temperature liquid chromatography of triazole fungicides on polybutadiene-coated zirconia stationary phase |
| title | High temperature liquid chromatography of triazole fungicides on polybutadiene-coated zirconia stationary phase |
| title_full | High temperature liquid chromatography of triazole fungicides on polybutadiene-coated zirconia stationary phase |
| title_fullStr | High temperature liquid chromatography of triazole fungicides on polybutadiene-coated zirconia stationary phase |
| title_full_unstemmed | High temperature liquid chromatography of triazole fungicides on polybutadiene-coated zirconia stationary phase |
| title_short | High temperature liquid chromatography of triazole fungicides on polybutadiene-coated zirconia stationary phase |
| title_sort | high temperature liquid chromatography of triazole fungicides on polybutadiene-coated zirconia stationary phase |
| topic | QD Chemistry |
| url | http://eprints.utm.my/6860/1/MMSanagi2004_HighTemperatureLiquidChromatography.pdf http://eprints.utm.my/6860/ http://dx.doi.org/10.1016/j.chroma.2004.10.053 |
| url_provider | http://eprints.utm.my/ |