Decontamination of chlorobenzene by electrochemical method
A new decontamination system of chlorobenzene was carried out by electrolysis of an N,N-dimethylformamide (DMF) solution containing monochlorobenzene as a substrate and supporting electrolyte in a one-compartment cell fitted with a platinum cathode and a metal anode. In this system, monochlorobenzen...
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| Format: | Conference or Workshop Item |
| Language: | en |
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2004
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| Online Access: | http://eprints.utm.my/5241/1/AishahAbdulJalil2004_DecontaminationOfChlorobenzeneByElectrochemicalMethod.pdf http://eprints.utm.my/5241/ |
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| _version_ | 1845471324200239104 |
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| author | Abdul Jalil, Aishah Idris, Ani Triwahyono, Sugeng Tokuda, Masao |
| author_facet | Abdul Jalil, Aishah Idris, Ani Triwahyono, Sugeng Tokuda, Masao |
| author_sort | Abdul Jalil, Aishah |
| building | UTM Library |
| collection | Institutional Repository |
| content_provider | Universiti Teknologi Malaysia |
| content_source | UTM Institutional Repository |
| continent | Asia |
| country | Malaysia |
| description | A new decontamination system of chlorobenzene was carried out by electrolysis of an N,N-dimethylformamide (DMF) solution containing monochlorobenzene as a substrate and supporting electrolyte in a one-compartment cell fitted with a platinum cathode and a metal anode. In this system, monochlorobenzene was dechlorinated to benzene where the progress of the reaction was analyzed by gas chromatography. Effect of temperature, type of anode material and solvent was investigated and it was also found that the rate and current efficiency for the benzene production were greatly improved when naphthalene was used as a mediator. In the presence of naphthalene, the reduction of chlorobenzene occurs indirectly compared to its direct reduction at the platinum cathode to give complete dechlorination. |
| format | Conference or Workshop Item |
| id | my.utm.eprints-5241 |
| institution | Universiti Teknologi Malaysia |
| language | en |
| publishDate | 2004 |
| record_format | eprints |
| spelling | my.utm.eprints-52412017-09-10T06:38:32Z http://eprints.utm.my/5241/ Decontamination of chlorobenzene by electrochemical method Abdul Jalil, Aishah Idris, Ani Triwahyono, Sugeng Tokuda, Masao T Technology (General) A new decontamination system of chlorobenzene was carried out by electrolysis of an N,N-dimethylformamide (DMF) solution containing monochlorobenzene as a substrate and supporting electrolyte in a one-compartment cell fitted with a platinum cathode and a metal anode. In this system, monochlorobenzene was dechlorinated to benzene where the progress of the reaction was analyzed by gas chromatography. Effect of temperature, type of anode material and solvent was investigated and it was also found that the rate and current efficiency for the benzene production were greatly improved when naphthalene was used as a mediator. In the presence of naphthalene, the reduction of chlorobenzene occurs indirectly compared to its direct reduction at the platinum cathode to give complete dechlorination. 2004 Conference or Workshop Item PeerReviewed application/pdf en http://eprints.utm.my/5241/1/AishahAbdulJalil2004_DecontaminationOfChlorobenzeneByElectrochemicalMethod.pdf Abdul Jalil, Aishah and Idris, Ani and Triwahyono, Sugeng and Tokuda, Masao (2004) Decontamination of chlorobenzene by electrochemical method. In: Simposium Kimia Analisis Malaysia Ke-17 (SKAM-17), 24-26 Ogos 2004, Swiss-Garden Resort, Pantai Balok, Kuantan. |
| spellingShingle | T Technology (General) Abdul Jalil, Aishah Idris, Ani Triwahyono, Sugeng Tokuda, Masao Decontamination of chlorobenzene by electrochemical method |
| title | Decontamination of chlorobenzene by electrochemical method
|
| title_full | Decontamination of chlorobenzene by electrochemical method
|
| title_fullStr | Decontamination of chlorobenzene by electrochemical method
|
| title_full_unstemmed | Decontamination of chlorobenzene by electrochemical method
|
| title_short | Decontamination of chlorobenzene by electrochemical method
|
| title_sort | decontamination of chlorobenzene by electrochemical method |
| topic | T Technology (General) |
| url | http://eprints.utm.my/5241/1/AishahAbdulJalil2004_DecontaminationOfChlorobenzeneByElectrochemicalMethod.pdf http://eprints.utm.my/5241/ |
| url_provider | http://eprints.utm.my/ |