Complete electrochemical dechlorination of chlorobenzenes in the presence of various arene mediators
Electrochemical dechlorination of chlorobenzenes in the presence of various arene mediators such as naphthalene, biphenyl, phenanthrene, anthracene, and pyrene, was studied. The amount of mediator required was able to be reduced to 0.01 equiv. for all mediators except for anthracene, with the comple...
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| Format: | Article |
| Language: | en |
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Elsevier
2010
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| Online Access: | http://eprints.utm.my/10083/2/AishahAJalil2010_Complete_electrochemical_dechlorination_of_chlorobenzenes.pdf http://eprints.utm.my/10083/ http://dx.doi.org/10.1016/j.jhazmat.2009.09.091 |
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| author | A. Jalil, Aishah Triwahyono, Sugeng M. Razali, N. Aini H. Hairom, N. Hanis Idris, Ani M. Muhid, M. Nazlan Ismail, Azlyana M. Yahaya, N. Aisyah L. Ahmad, N. Akma Dzinun, Hazlini |
| author_facet | A. Jalil, Aishah Triwahyono, Sugeng M. Razali, N. Aini H. Hairom, N. Hanis Idris, Ani M. Muhid, M. Nazlan Ismail, Azlyana M. Yahaya, N. Aisyah L. Ahmad, N. Akma Dzinun, Hazlini |
| author_sort | A. Jalil, Aishah |
| building | UTM Library |
| collection | Institutional Repository |
| content_provider | Universiti Teknologi Malaysia |
| content_source | UTM Institutional Repository |
| continent | Asia |
| country | Malaysia |
| description | Electrochemical dechlorination of chlorobenzenes in the presence of various arene mediators such as naphthalene, biphenyl, phenanthrene, anthracene, and pyrene, was studied. The amount of mediator required was able to be reduced to 0.01 equiv. for all mediators except for anthracene, with the complete dechlorination of mono-, 1,3-di- and 1,2,4-trichlorobenzene still achieved. This catalytic amount of mediator plays an important role in accelerating the dechlorination through the rapid formation of radical anions prior to reduction of the chlorobenzenes. |
| format | Article |
| id | my.utm.eprints-10083 |
| institution | Universiti Teknologi Malaysia |
| language | en |
| publishDate | 2010 |
| publisher | Elsevier |
| record_format | eprints |
| spelling | my.utm.eprints-100832017-02-15T01:20:03Z http://eprints.utm.my/10083/ Complete electrochemical dechlorination of chlorobenzenes in the presence of various arene mediators A. Jalil, Aishah Triwahyono, Sugeng M. Razali, N. Aini H. Hairom, N. Hanis Idris, Ani M. Muhid, M. Nazlan Ismail, Azlyana M. Yahaya, N. Aisyah L. Ahmad, N. Akma Dzinun, Hazlini QD Chemistry TP Chemical technology Electrochemical dechlorination of chlorobenzenes in the presence of various arene mediators such as naphthalene, biphenyl, phenanthrene, anthracene, and pyrene, was studied. The amount of mediator required was able to be reduced to 0.01 equiv. for all mediators except for anthracene, with the complete dechlorination of mono-, 1,3-di- and 1,2,4-trichlorobenzene still achieved. This catalytic amount of mediator plays an important role in accelerating the dechlorination through the rapid formation of radical anions prior to reduction of the chlorobenzenes. Elsevier 2010-02-15 Article PeerReviewed application/pdf en http://eprints.utm.my/10083/2/AishahAJalil2010_Complete_electrochemical_dechlorination_of_chlorobenzenes.pdf A. Jalil, Aishah and Triwahyono, Sugeng and M. Razali, N. Aini and H. Hairom, N. Hanis and Idris, Ani and M. Muhid, M. Nazlan and Ismail, Azlyana and M. Yahaya, N. Aisyah and L. Ahmad, N. Akma and Dzinun, Hazlini (2010) Complete electrochemical dechlorination of chlorobenzenes in the presence of various arene mediators. Journal of Hazardous Materials, 174 (1-3). pp. 581-585. ISSN 0304-3894 http://dx.doi.org/10.1016/j.jhazmat.2009.09.091 doi:10.1016/j.jhazmat.2009.09.091 |
| spellingShingle | QD Chemistry TP Chemical technology A. Jalil, Aishah Triwahyono, Sugeng M. Razali, N. Aini H. Hairom, N. Hanis Idris, Ani M. Muhid, M. Nazlan Ismail, Azlyana M. Yahaya, N. Aisyah L. Ahmad, N. Akma Dzinun, Hazlini Complete electrochemical dechlorination of chlorobenzenes in the presence of various arene mediators |
| title | Complete electrochemical dechlorination of chlorobenzenes in the presence of various arene mediators |
| title_full | Complete electrochemical dechlorination of chlorobenzenes in the presence of various arene mediators |
| title_fullStr | Complete electrochemical dechlorination of chlorobenzenes in the presence of various arene mediators |
| title_full_unstemmed | Complete electrochemical dechlorination of chlorobenzenes in the presence of various arene mediators |
| title_short | Complete electrochemical dechlorination of chlorobenzenes in the presence of various arene mediators |
| title_sort | complete electrochemical dechlorination of chlorobenzenes in the presence of various arene mediators |
| topic | QD Chemistry TP Chemical technology |
| url | http://eprints.utm.my/10083/2/AishahAJalil2010_Complete_electrochemical_dechlorination_of_chlorobenzenes.pdf http://eprints.utm.my/10083/ http://dx.doi.org/10.1016/j.jhazmat.2009.09.091 |
| url_provider | http://eprints.utm.my/ |