Effect of electrolyte thickness manipulation on enhancing carbon deposition resistance of methane-fueled solid oxide fuel cell

Dual-layer hollow fiber (DLHF) micro-tubular solid oxide fuel cell (MT-SOFC) consisting of nickel oxide-yttria-stabilized zirconia (NiO-YSZ) anode/YSZ elec�trolyte was fabricated via a single-step phase inversion-based co-extrusion/co�sintering technique in order to investigate the effect of differ...

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Main Authors: Ab Rahman, Mazlinda, Othman, Mohd Hafiz Dzarfan, Wibisono, Yusuf, Harun, Zawati, F. Omar, Ahmad F., Shabri, Hazrul A., Deraman, Shahirah, Rahman, Mukhlis A., Jaafar, Juhana, Ismail, Ahmad F.
Format: Article
Language:en
Published: Wiley 2020
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Online Access:http://eprints.uthm.edu.my/6861/1/J12950_c445aa43c4c52d52e0cad60d42a6a5d6.pdf
http://eprints.uthm.edu.my/6861/
https://doi.org/ 10.1002/er.5981
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author Ab Rahman, Mazlinda
Othman, Mohd Hafiz Dzarfan
Wibisono, Yusuf
Harun, Zawati
F. Omar, Ahmad F.
Shabri, Hazrul A.
Deraman, Shahirah
Rahman, Mukhlis A.
Jaafar, Juhana
Ismail, Ahmad F.
author_facet Ab Rahman, Mazlinda
Othman, Mohd Hafiz Dzarfan
Wibisono, Yusuf
Harun, Zawati
F. Omar, Ahmad F.
Shabri, Hazrul A.
Deraman, Shahirah
Rahman, Mukhlis A.
Jaafar, Juhana
Ismail, Ahmad F.
author_sort Ab Rahman, Mazlinda
building UTHM Library
collection Institutional Repository
content_provider Universiti Tun Hussein Onn Malaysia
content_source UTHM Institutional Repository
continent Asia
country Malaysia
description Dual-layer hollow fiber (DLHF) micro-tubular solid oxide fuel cell (MT-SOFC) consisting of nickel oxide-yttria-stabilized zirconia (NiO-YSZ) anode/YSZ elec�trolyte was fabricated via a single-step phase inversion-based co-extrusion/co�sintering technique in order to investigate the effect of different electrolyte extrusion rates (1-5 mL min−1 ) at different sintering temperature (1350�C, 1400�C, and 1450�C) under methane (CH4) condition. The DLHF co-sintered at 1450�C was chosen as optimum temperature due to the good mechanical strength and gas-tight property. Meanwhile, 18 to 34 μm of electrolyte thick�ness was achieved when electrolyte extrusion rate increase from 1 to 5 mL min−1 . Power density as high as 0.32 W cm−2 was obtained on the cell with the electrolyte layer of 18 μm in thickness (DLHF1) which is 20% higher than the cell with an electrolyte layer of 34 μm (DLHF5) which was only 0.12 W cm−2 when operated at 850�C. However, DLHF1 had suffered cracking formation that originated from anode site which shortened the stability test duration to only 8 hours of survival under 750�C. While DLHF5 can operate up to 15 hours but an increase in electrolyte thickness had resulted in higher ohmic area-specific resistance that lowering the power density. Fifty-seven per�cent reduction in cell performance was observed under methane condition when compared to the cell that performs using hydrogen gas due to the carbon deposition as proven by Raman spectroscopy and carbon, hydrogen, nitrogen, and sulfur analyzer.
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spelling my.uthm.eprints-68612022-04-05T06:24:39Z http://eprints.uthm.edu.my/6861/ Effect of electrolyte thickness manipulation on enhancing carbon deposition resistance of methane-fueled solid oxide fuel cell Ab Rahman, Mazlinda Othman, Mohd Hafiz Dzarfan Wibisono, Yusuf Harun, Zawati F. Omar, Ahmad F. Shabri, Hazrul A. Deraman, Shahirah Rahman, Mukhlis A. Jaafar, Juhana Ismail, Ahmad F. TP315-360 Fuel Dual-layer hollow fiber (DLHF) micro-tubular solid oxide fuel cell (MT-SOFC) consisting of nickel oxide-yttria-stabilized zirconia (NiO-YSZ) anode/YSZ elec�trolyte was fabricated via a single-step phase inversion-based co-extrusion/co�sintering technique in order to investigate the effect of different electrolyte extrusion rates (1-5 mL min−1 ) at different sintering temperature (1350�C, 1400�C, and 1450�C) under methane (CH4) condition. The DLHF co-sintered at 1450�C was chosen as optimum temperature due to the good mechanical strength and gas-tight property. Meanwhile, 18 to 34 μm of electrolyte thick�ness was achieved when electrolyte extrusion rate increase from 1 to 5 mL min−1 . Power density as high as 0.32 W cm−2 was obtained on the cell with the electrolyte layer of 18 μm in thickness (DLHF1) which is 20% higher than the cell with an electrolyte layer of 34 μm (DLHF5) which was only 0.12 W cm−2 when operated at 850�C. However, DLHF1 had suffered cracking formation that originated from anode site which shortened the stability test duration to only 8 hours of survival under 750�C. While DLHF5 can operate up to 15 hours but an increase in electrolyte thickness had resulted in higher ohmic area-specific resistance that lowering the power density. Fifty-seven per�cent reduction in cell performance was observed under methane condition when compared to the cell that performs using hydrogen gas due to the carbon deposition as proven by Raman spectroscopy and carbon, hydrogen, nitrogen, and sulfur analyzer. Wiley 2020 Article PeerReviewed text en http://eprints.uthm.edu.my/6861/1/J12950_c445aa43c4c52d52e0cad60d42a6a5d6.pdf Ab Rahman, Mazlinda and Othman, Mohd Hafiz Dzarfan and Wibisono, Yusuf and Harun, Zawati and F. Omar, Ahmad F. and Shabri, Hazrul A. and Deraman, Shahirah and Rahman, Mukhlis A. and Jaafar, Juhana and Ismail, Ahmad F. (2020) Effect of electrolyte thickness manipulation on enhancing carbon deposition resistance of methane-fueled solid oxide fuel cell. International Journal of Energy Research. pp. 1-19. ISSN 0363-907X https://doi.org/ 10.1002/er.5981
spellingShingle TP315-360 Fuel
Ab Rahman, Mazlinda
Othman, Mohd Hafiz Dzarfan
Wibisono, Yusuf
Harun, Zawati
F. Omar, Ahmad F.
Shabri, Hazrul A.
Deraman, Shahirah
Rahman, Mukhlis A.
Jaafar, Juhana
Ismail, Ahmad F.
Effect of electrolyte thickness manipulation on enhancing carbon deposition resistance of methane-fueled solid oxide fuel cell
title Effect of electrolyte thickness manipulation on enhancing carbon deposition resistance of methane-fueled solid oxide fuel cell
title_full Effect of electrolyte thickness manipulation on enhancing carbon deposition resistance of methane-fueled solid oxide fuel cell
title_fullStr Effect of electrolyte thickness manipulation on enhancing carbon deposition resistance of methane-fueled solid oxide fuel cell
title_full_unstemmed Effect of electrolyte thickness manipulation on enhancing carbon deposition resistance of methane-fueled solid oxide fuel cell
title_short Effect of electrolyte thickness manipulation on enhancing carbon deposition resistance of methane-fueled solid oxide fuel cell
title_sort effect of electrolyte thickness manipulation on enhancing carbon deposition resistance of methane-fueled solid oxide fuel cell
topic TP315-360 Fuel
url http://eprints.uthm.edu.my/6861/1/J12950_c445aa43c4c52d52e0cad60d42a6a5d6.pdf
http://eprints.uthm.edu.my/6861/
https://doi.org/ 10.1002/er.5981
url_provider http://eprints.uthm.edu.my/