Gold nanoplates for a localized surface plasmon resonance-based boric acid sensor

Localized surface plasmon resonance (LSPR) properties of metallic nanostructures, such as gold, are very sensitive to the dielectric environment of the material, which can simply be adjusted by changing its shape and size through modification of the synthesizing process. Thus, these unique propertie...

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Main Authors: Morsin, Marlia, Mat Salleh, Muhamad, Umar, Akrajas Ali, Sahdan, Mohd Zainizan
Format: Article
Language:en
Published: MDPI 2017
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Online Access:http://eprints.uthm.edu.my/4197/1/AJ%202017%20%28117%29%20Gold%20nanoplates%20for%20a%20localized%20surface%20plasmon.pdf
http://eprints.uthm.edu.my/4197/
http://dx.doi.org/10.3390/s17050947
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author Morsin, Marlia
Mat Salleh, Muhamad
Umar, Akrajas Ali
Sahdan, Mohd Zainizan
author_facet Morsin, Marlia
Mat Salleh, Muhamad
Umar, Akrajas Ali
Sahdan, Mohd Zainizan
author_sort Morsin, Marlia
building UTHM Library
collection Institutional Repository
content_provider Universiti Tun Hussein Onn Malaysia
content_source UTHM Institutional Repository
continent Asia
country Malaysia
description Localized surface plasmon resonance (LSPR) properties of metallic nanostructures, such as gold, are very sensitive to the dielectric environment of the material, which can simply be adjusted by changing its shape and size through modification of the synthesizing process. Thus, these unique properties are very promising, particularly for the detection of various types of chemicals, for example boric acid which is a non-permitted preservative employed in food preparations. For the sensing material, gold (Au) nanoplates with a variety of shapes, i.e., triangular, hexagonal, truncated pentagon and flat rod, were prepared using a seed-mediated growth method. The yield of Au nanoplates was estimated to be ca. 63% over all areas of the sensing material. The nanoplates produced two absorption bands, i.e., the transverse surface plasmon resonance (t-SPR) and the longitudinal surface plasmon resonance (l-SPR) at 545 nm and 710 nm, respectively. In the sensing study, these two bands were used to examine the response of gold nanoplates to the presence of boric acid in an aqueous environment. In a typical process, when the sample is immersed into an aqueous solution containing boric acid, these two bands may change their intensity and peak centers as a result of the interaction between the boric acid and the gold nanoplates. The changes in the intensities and peak positions of t-SPR and l-SPR linearly correlated with the change in the boric acid concentration in the solution.
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spelling my.uthm.eprints-41972021-11-28T07:51:19Z http://eprints.uthm.edu.my/4197/ Gold nanoplates for a localized surface plasmon resonance-based boric acid sensor Morsin, Marlia Mat Salleh, Muhamad Umar, Akrajas Ali Sahdan, Mohd Zainizan QC170-197 Atomic physics. Constitution and properties of matter. Including molecular physics, relativity, quantum theory, and solid state physics TK7800-8360 Electronics Localized surface plasmon resonance (LSPR) properties of metallic nanostructures, such as gold, are very sensitive to the dielectric environment of the material, which can simply be adjusted by changing its shape and size through modification of the synthesizing process. Thus, these unique properties are very promising, particularly for the detection of various types of chemicals, for example boric acid which is a non-permitted preservative employed in food preparations. For the sensing material, gold (Au) nanoplates with a variety of shapes, i.e., triangular, hexagonal, truncated pentagon and flat rod, were prepared using a seed-mediated growth method. The yield of Au nanoplates was estimated to be ca. 63% over all areas of the sensing material. The nanoplates produced two absorption bands, i.e., the transverse surface plasmon resonance (t-SPR) and the longitudinal surface plasmon resonance (l-SPR) at 545 nm and 710 nm, respectively. In the sensing study, these two bands were used to examine the response of gold nanoplates to the presence of boric acid in an aqueous environment. In a typical process, when the sample is immersed into an aqueous solution containing boric acid, these two bands may change their intensity and peak centers as a result of the interaction between the boric acid and the gold nanoplates. The changes in the intensities and peak positions of t-SPR and l-SPR linearly correlated with the change in the boric acid concentration in the solution. MDPI 2017 Article PeerReviewed text en http://eprints.uthm.edu.my/4197/1/AJ%202017%20%28117%29%20Gold%20nanoplates%20for%20a%20localized%20surface%20plasmon.pdf Morsin, Marlia and Mat Salleh, Muhamad and Umar, Akrajas Ali and Sahdan, Mohd Zainizan (2017) Gold nanoplates for a localized surface plasmon resonance-based boric acid sensor. Sensors, 17 (947). pp. 1-9. ISSN 1424-8220 http://dx.doi.org/10.3390/s17050947
spellingShingle QC170-197 Atomic physics. Constitution and properties of matter. Including molecular physics, relativity, quantum theory, and solid state physics
TK7800-8360 Electronics
Morsin, Marlia
Mat Salleh, Muhamad
Umar, Akrajas Ali
Sahdan, Mohd Zainizan
Gold nanoplates for a localized surface plasmon resonance-based boric acid sensor
title Gold nanoplates for a localized surface plasmon resonance-based boric acid sensor
title_full Gold nanoplates for a localized surface plasmon resonance-based boric acid sensor
title_fullStr Gold nanoplates for a localized surface plasmon resonance-based boric acid sensor
title_full_unstemmed Gold nanoplates for a localized surface plasmon resonance-based boric acid sensor
title_short Gold nanoplates for a localized surface plasmon resonance-based boric acid sensor
title_sort gold nanoplates for a localized surface plasmon resonance-based boric acid sensor
topic QC170-197 Atomic physics. Constitution and properties of matter. Including molecular physics, relativity, quantum theory, and solid state physics
TK7800-8360 Electronics
url http://eprints.uthm.edu.my/4197/1/AJ%202017%20%28117%29%20Gold%20nanoplates%20for%20a%20localized%20surface%20plasmon.pdf
http://eprints.uthm.edu.my/4197/
http://dx.doi.org/10.3390/s17050947
url_provider http://eprints.uthm.edu.my/