Sustainable Waste Oils Polymer Doped with Titanium Dioxide as Ultraviolet Stabilizer
Waste oils for biopolymer conversion process namely as sustainable monomers with biodegradable properties that are prepared in a multi-stage synthesis route from vegetable oils. These sustainable monomers from virgin oil (VO) and waste oil (WO) were mixed with hardener to form virgin oil sustainable...
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semarak ilmu
2025
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| Online Access: | http://eprints.uthm.edu.my/12768/1/J19333_77742220e207e1e689c3ffb9ad63314b.pdf http://eprints.uthm.edu.my/12768/ https://doi.org/10.37934/armne.27.1.5875 |
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| author | Mohd Rus, Anika Zafiah Salim, Nurul Syamimi Abd Wahab, Hanani Marsi, Noraini Mat Hassan, Nik Normunira Saryanto, Hendi Sulong, Nurulsaidatulsyida Nik Yusuf, Nik Alnur Auli Alamsyah, Muhammad Hafizh Mariza, Ita |
| author_facet | Mohd Rus, Anika Zafiah Salim, Nurul Syamimi Abd Wahab, Hanani Marsi, Noraini Mat Hassan, Nik Normunira Saryanto, Hendi Sulong, Nurulsaidatulsyida Nik Yusuf, Nik Alnur Auli Alamsyah, Muhammad Hafizh Mariza, Ita |
| author_sort | Mohd Rus, Anika Zafiah |
| building | UTHM Library |
| collection | Institutional Repository |
| content_provider | Universiti Tun Hussein Onn Malaysia |
| content_source | UTHM Institutional Repository |
| continent | Asia |
| country | Malaysia |
| description | Waste oils for biopolymer conversion process namely as sustainable monomers with biodegradable properties that are prepared in a multi-stage synthesis route from vegetable oils. These sustainable monomers from virgin oil (VO) and waste oil (WO) were mixed with hardener to form virgin oil sustainable polymer (VOP) and waste oil sustainable polymer (WOP). VOP and WOP were left to cure at ambient temperature for at least 6 hours and removed from the mould. The steps were repeated to fabricate sustainable polymer composite (SPC) doped with different percentages of TiO2. The samples of biopolymer (BP) are based on VOP and WOP, while biopolymer composites (BPC) were based on TiO2 percentage. The thickness of the prepared sample is from 110 to 250 µm according to ASTM D1005-95. The study on the thermal stability property of
these polymers in oven thermal exposure shows a significant stability of these polymer films which was determined by calculating the carbonyl index (CI) of polymer films. The VOP shows the leaststability upon thermal exposure which its molecular chains contain many reactive sites, thus providing more potential for degradation, resulting in lower thermal and bio-stability. Also, it is revealed that polymers are susceptible to photodegradation initiated by heat or UV light during processing or long-term use. Therefore, UV accelerated weathering test was conducted according to ASTM D 4587- Standard practice for fluorescent UV-condensation exposures of paint and related coatings. Furthermore, a tensile test was conducted to determine the strength and ductility of a material. The mechanical properties of polymer thin films were significantly reduced by UV irradiation exposure. As opposed to WOP, VOP gives better results for tensile strength and elongation at break. |
| format | Article |
| id | my.uthm.eprints-12768 |
| institution | Universiti Tun Hussein Onn Malaysia |
| language | en |
| publishDate | 2025 |
| publisher | semarak ilmu |
| record_format | eprints |
| spelling | my.uthm.eprints-127682025-07-01T23:56:02Z http://eprints.uthm.edu.my/12768/ Sustainable Waste Oils Polymer Doped with Titanium Dioxide as Ultraviolet Stabilizer Mohd Rus, Anika Zafiah Salim, Nurul Syamimi Abd Wahab, Hanani Marsi, Noraini Mat Hassan, Nik Normunira Saryanto, Hendi Sulong, Nurulsaidatulsyida Nik Yusuf, Nik Alnur Auli Alamsyah, Muhammad Hafizh Mariza, Ita TP Chemical technology Waste oils for biopolymer conversion process namely as sustainable monomers with biodegradable properties that are prepared in a multi-stage synthesis route from vegetable oils. These sustainable monomers from virgin oil (VO) and waste oil (WO) were mixed with hardener to form virgin oil sustainable polymer (VOP) and waste oil sustainable polymer (WOP). VOP and WOP were left to cure at ambient temperature for at least 6 hours and removed from the mould. The steps were repeated to fabricate sustainable polymer composite (SPC) doped with different percentages of TiO2. The samples of biopolymer (BP) are based on VOP and WOP, while biopolymer composites (BPC) were based on TiO2 percentage. The thickness of the prepared sample is from 110 to 250 µm according to ASTM D1005-95. The study on the thermal stability property of these polymers in oven thermal exposure shows a significant stability of these polymer films which was determined by calculating the carbonyl index (CI) of polymer films. The VOP shows the leaststability upon thermal exposure which its molecular chains contain many reactive sites, thus providing more potential for degradation, resulting in lower thermal and bio-stability. Also, it is revealed that polymers are susceptible to photodegradation initiated by heat or UV light during processing or long-term use. Therefore, UV accelerated weathering test was conducted according to ASTM D 4587- Standard practice for fluorescent UV-condensation exposures of paint and related coatings. Furthermore, a tensile test was conducted to determine the strength and ductility of a material. The mechanical properties of polymer thin films were significantly reduced by UV irradiation exposure. As opposed to WOP, VOP gives better results for tensile strength and elongation at break. semarak ilmu 2025 Article PeerReviewed text en http://eprints.uthm.edu.my/12768/1/J19333_77742220e207e1e689c3ffb9ad63314b.pdf Mohd Rus, Anika Zafiah and Salim, Nurul Syamimi and Abd Wahab, Hanani and Marsi, Noraini and Mat Hassan, Nik Normunira and Saryanto, Hendi and Sulong, Nurulsaidatulsyida and Nik Yusuf, Nik Alnur Auli and Alamsyah, Muhammad Hafizh and Mariza, Ita (2025) Sustainable Waste Oils Polymer Doped with Titanium Dioxide as Ultraviolet Stabilizer. Journal of Advanced Research in Micro and Nano Engineering, 27 (1). pp. 58-75. ISSN 2756-8210 https://doi.org/10.37934/armne.27.1.5875 |
| spellingShingle | TP Chemical technology Mohd Rus, Anika Zafiah Salim, Nurul Syamimi Abd Wahab, Hanani Marsi, Noraini Mat Hassan, Nik Normunira Saryanto, Hendi Sulong, Nurulsaidatulsyida Nik Yusuf, Nik Alnur Auli Alamsyah, Muhammad Hafizh Mariza, Ita Sustainable Waste Oils Polymer Doped with Titanium Dioxide as Ultraviolet Stabilizer |
| title | Sustainable Waste Oils Polymer Doped with Titanium Dioxide as Ultraviolet Stabilizer |
| title_full | Sustainable Waste Oils Polymer Doped with Titanium Dioxide as Ultraviolet Stabilizer |
| title_fullStr | Sustainable Waste Oils Polymer Doped with Titanium Dioxide as Ultraviolet Stabilizer |
| title_full_unstemmed | Sustainable Waste Oils Polymer Doped with Titanium Dioxide as Ultraviolet Stabilizer |
| title_short | Sustainable Waste Oils Polymer Doped with Titanium Dioxide as Ultraviolet Stabilizer |
| title_sort | sustainable waste oils polymer doped with titanium dioxide as ultraviolet stabilizer |
| topic | TP Chemical technology |
| url | http://eprints.uthm.edu.my/12768/1/J19333_77742220e207e1e689c3ffb9ad63314b.pdf http://eprints.uthm.edu.my/12768/ https://doi.org/10.37934/armne.27.1.5875 |
| url_provider | http://eprints.uthm.edu.my/ |