Synthesis of novel CaF2−CaO−Na2O−B2O3−SiO2 bioglass system: phase transformation, surface reaction and mechanical properties

This research aims to investigate the potential of novel CaF2−CaO−Na2O−B2O3−SiO2 glass systems and converted to bioactive glass-ceramics. The study involves examining the effects of different heat treatment temperatures and immersion periods, with the goal of exploring these materials as viable alt...

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Main Authors: Loh, Zhi Wei, Mohd Zaid, Mohd Hafiz, Matori, Khamirul Amin, Cheong, Wei Mun, Mayzan, Mohd Zul Hilmi, Hisam, Rosdiyana
Format: Article
Language:en
Published: Springer 2024
Subjects:
Online Access:http://eprints.uthm.edu.my/12361/1/J17808_c5321a20fd72472511b10603abd5bb7c.pdf
http://eprints.uthm.edu.my/12361/
https://doi.org/10.1007/s00339-024-07591-8
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author Loh, Zhi Wei
Mohd Zaid, Mohd Hafiz
Matori, Khamirul Amin
Cheong, Wei Mun
Mayzan, Mohd Zul Hilmi
Hisam, Rosdiyana
author_facet Loh, Zhi Wei
Mohd Zaid, Mohd Hafiz
Matori, Khamirul Amin
Cheong, Wei Mun
Mayzan, Mohd Zul Hilmi
Hisam, Rosdiyana
author_sort Loh, Zhi Wei
building UTHM Library
collection Institutional Repository
content_provider Universiti Tun Hussein Onn Malaysia
content_source UTHM Institutional Repository
continent Asia
country Malaysia
description This research aims to investigate the potential of novel CaF2−CaO−Na2O−B2O3−SiO2 glass systems and converted to bioactive glass-ceramics. The study involves examining the effects of different heat treatment temperatures and immersion periods, with the goal of exploring these materials as viable alternatives for various biomedical applications. A typical melt-quenching technique was used to synthesize the glass samples, followed by a controlled heat treatment. The main crystalline phases are cuspidine and wollastonite, which have the potential to promote bioactivity, especially in dental and bone-related applications. The sample heat-treated at 700 °C showed an increased microhardness and fracture toughness by more than 116% and 36%, compared to the initial value. Furthermore, the increase in pH and the observed weight loss/ gain demonstrated the reactivity of the samples with the phosphate buffer-saline medium, indicating their bioactive properties. Remarkably, the microhardness and fracture toughness exhibited notable improvements after 14 days of immersion, with an enhancement of 4.71% and 4.66%, highlighting their potential durability and longevity in high-strength dental crown applications. Consequently, this research presents a promising method for developing sustainable novel glass and glass-ceramic materials devoid of phosphates. These materials boast enhanced mechanical properties while preserving bioactivity, making them well-suited for dental implants and restorative purposes.
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spelling my.uthm.eprints-123612025-04-24T01:11:45Z http://eprints.uthm.edu.my/12361/ Synthesis of novel CaF2−CaO−Na2O−B2O3−SiO2 bioglass system: phase transformation, surface reaction and mechanical properties Loh, Zhi Wei Mohd Zaid, Mohd Hafiz Matori, Khamirul Amin Cheong, Wei Mun Mayzan, Mohd Zul Hilmi Hisam, Rosdiyana TA Engineering (General). Civil engineering (General) This research aims to investigate the potential of novel CaF2−CaO−Na2O−B2O3−SiO2 glass systems and converted to bioactive glass-ceramics. The study involves examining the effects of different heat treatment temperatures and immersion periods, with the goal of exploring these materials as viable alternatives for various biomedical applications. A typical melt-quenching technique was used to synthesize the glass samples, followed by a controlled heat treatment. The main crystalline phases are cuspidine and wollastonite, which have the potential to promote bioactivity, especially in dental and bone-related applications. The sample heat-treated at 700 °C showed an increased microhardness and fracture toughness by more than 116% and 36%, compared to the initial value. Furthermore, the increase in pH and the observed weight loss/ gain demonstrated the reactivity of the samples with the phosphate buffer-saline medium, indicating their bioactive properties. Remarkably, the microhardness and fracture toughness exhibited notable improvements after 14 days of immersion, with an enhancement of 4.71% and 4.66%, highlighting their potential durability and longevity in high-strength dental crown applications. Consequently, this research presents a promising method for developing sustainable novel glass and glass-ceramic materials devoid of phosphates. These materials boast enhanced mechanical properties while preserving bioactivity, making them well-suited for dental implants and restorative purposes. Springer 2024 Article PeerReviewed text en http://eprints.uthm.edu.my/12361/1/J17808_c5321a20fd72472511b10603abd5bb7c.pdf Loh, Zhi Wei and Mohd Zaid, Mohd Hafiz and Matori, Khamirul Amin and Cheong, Wei Mun and Mayzan, Mohd Zul Hilmi and Hisam, Rosdiyana (2024) Synthesis of novel CaF2−CaO−Na2O−B2O3−SiO2 bioglass system: phase transformation, surface reaction and mechanical properties. Applied Physics A. pp. 1-12. https://doi.org/10.1007/s00339-024-07591-8
spellingShingle TA Engineering (General). Civil engineering (General)
Loh, Zhi Wei
Mohd Zaid, Mohd Hafiz
Matori, Khamirul Amin
Cheong, Wei Mun
Mayzan, Mohd Zul Hilmi
Hisam, Rosdiyana
Synthesis of novel CaF2−CaO−Na2O−B2O3−SiO2 bioglass system: phase transformation, surface reaction and mechanical properties
title Synthesis of novel CaF2−CaO−Na2O−B2O3−SiO2 bioglass system: phase transformation, surface reaction and mechanical properties
title_full Synthesis of novel CaF2−CaO−Na2O−B2O3−SiO2 bioglass system: phase transformation, surface reaction and mechanical properties
title_fullStr Synthesis of novel CaF2−CaO−Na2O−B2O3−SiO2 bioglass system: phase transformation, surface reaction and mechanical properties
title_full_unstemmed Synthesis of novel CaF2−CaO−Na2O−B2O3−SiO2 bioglass system: phase transformation, surface reaction and mechanical properties
title_short Synthesis of novel CaF2−CaO−Na2O−B2O3−SiO2 bioglass system: phase transformation, surface reaction and mechanical properties
title_sort synthesis of novel caf2−cao−na2o−b2o3−sio2 bioglass system: phase transformation, surface reaction and mechanical properties
topic TA Engineering (General). Civil engineering (General)
url http://eprints.uthm.edu.my/12361/1/J17808_c5321a20fd72472511b10603abd5bb7c.pdf
http://eprints.uthm.edu.my/12361/
https://doi.org/10.1007/s00339-024-07591-8
url_provider http://eprints.uthm.edu.my/