Effects of nano eggshell powder as a sustainable bio-filler on the physical, rheological, and microstructure properties of bitumen

Improving bitumen properties to withstand traffic loads and environmental conditions is essential for prolonging pavement life. Given that nanomaterials stand as potential candidates to fulfil these requirements, this study focused on the potential use of nano eggshell powder (NESP) as a sustainabl...

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Main Authors: Chfat, Alattafi Hadi Zghair, Yaacob, Haryati, Mohd Kamaruddin, Nurul Hidayah, Al-Saffar, Zaid Hazim Al-Saffar, Putra Jaya, Ramadhansyah
Format: Article
Language:en
Published: Elsevier 2024
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Online Access:http://eprints.uthm.edu.my/12137/1/J17692_d44db9f02db2e343ae3cbfc478bb2f72.pdf
http://eprints.uthm.edu.my/12137/
https://doi.org/10.1016/j.rineng.2024.102061
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author Chfat, Alattafi Hadi Zghair
Yaacob, Haryati
Mohd Kamaruddin, Nurul Hidayah
Al-Saffar, Zaid Hazim Al-Saffar
Putra Jaya, Ramadhansyah
author_facet Chfat, Alattafi Hadi Zghair
Yaacob, Haryati
Mohd Kamaruddin, Nurul Hidayah
Al-Saffar, Zaid Hazim Al-Saffar
Putra Jaya, Ramadhansyah
author_sort Chfat, Alattafi Hadi Zghair
building UTHM Library
collection Institutional Repository
content_provider Universiti Tun Hussein Onn Malaysia
content_source UTHM Institutional Repository
continent Asia
country Malaysia
description Improving bitumen properties to withstand traffic loads and environmental conditions is essential for prolonging pavement life. Given that nanomaterials stand as potential candidates to fulfil these requirements, this study focused on the potential use of nano eggshell powder (NESP) as a sustainable additive in bitumen. NESP was produced using a top-down approach with a ball milling machine. Then, 0% (control), 1%, 3%, 5%, 7%, and 9% NESP by weight of bitumen PEN 60/70 was added. Storage stability and X-Ray Diffraction (XRD) tests were performed to assess the compatibility and dispersion of NESP within the bitumen matrix. Penetration, softening point, ductility, viscosity, and dynamic shear rheometer (DSR) tests were performed to assess the physical and rheological properties of the modified bitumen. Fourier Transform Infrared (FTIR), Atomic Force Microscopy (AFM), contact angle, and thermal analysis (TGA) tests were conducted to analyze the microstructure properties. The results from storage stability tests and XRD patterns suggested that NESP was effectively integrated and evenly dispersed within the bitumen matrix. The incorporation of NESP led to improvement in the hardness and cohesion of the bitumen, as evidenced by reductions in penetration and increase in the softening point. However, higher concentrations of NESP resulted in decreased ductility of the bitumen. The addition of NESP into the bitumen resulted in increased viscosity and improved resistance to aging and rutting. Furthermore, the adhesion and thermal properties of bitumen improved with higher NESP content. Notably, the most effective concen tration for enhancing bitumen properties was found to be 9% NESP.
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spelling my.uthm.eprints-121372025-04-24T03:11:25Z http://eprints.uthm.edu.my/12137/ Effects of nano eggshell powder as a sustainable bio-filler on the physical, rheological, and microstructure properties of bitumen Chfat, Alattafi Hadi Zghair Yaacob, Haryati Mohd Kamaruddin, Nurul Hidayah Al-Saffar, Zaid Hazim Al-Saffar Putra Jaya, Ramadhansyah TE Highway engineering. Roads and pavements Improving bitumen properties to withstand traffic loads and environmental conditions is essential for prolonging pavement life. Given that nanomaterials stand as potential candidates to fulfil these requirements, this study focused on the potential use of nano eggshell powder (NESP) as a sustainable additive in bitumen. NESP was produced using a top-down approach with a ball milling machine. Then, 0% (control), 1%, 3%, 5%, 7%, and 9% NESP by weight of bitumen PEN 60/70 was added. Storage stability and X-Ray Diffraction (XRD) tests were performed to assess the compatibility and dispersion of NESP within the bitumen matrix. Penetration, softening point, ductility, viscosity, and dynamic shear rheometer (DSR) tests were performed to assess the physical and rheological properties of the modified bitumen. Fourier Transform Infrared (FTIR), Atomic Force Microscopy (AFM), contact angle, and thermal analysis (TGA) tests were conducted to analyze the microstructure properties. The results from storage stability tests and XRD patterns suggested that NESP was effectively integrated and evenly dispersed within the bitumen matrix. The incorporation of NESP led to improvement in the hardness and cohesion of the bitumen, as evidenced by reductions in penetration and increase in the softening point. However, higher concentrations of NESP resulted in decreased ductility of the bitumen. The addition of NESP into the bitumen resulted in increased viscosity and improved resistance to aging and rutting. Furthermore, the adhesion and thermal properties of bitumen improved with higher NESP content. Notably, the most effective concen tration for enhancing bitumen properties was found to be 9% NESP. Elsevier 2024 Article PeerReviewed text en http://eprints.uthm.edu.my/12137/1/J17692_d44db9f02db2e343ae3cbfc478bb2f72.pdf Chfat, Alattafi Hadi Zghair and Yaacob, Haryati and Mohd Kamaruddin, Nurul Hidayah and Al-Saffar, Zaid Hazim Al-Saffar and Putra Jaya, Ramadhansyah (2024) Effects of nano eggshell powder as a sustainable bio-filler on the physical, rheological, and microstructure properties of bitumen. Results in Engineering, 22. pp. 1-16. https://doi.org/10.1016/j.rineng.2024.102061
spellingShingle TE Highway engineering. Roads and pavements
Chfat, Alattafi Hadi Zghair
Yaacob, Haryati
Mohd Kamaruddin, Nurul Hidayah
Al-Saffar, Zaid Hazim Al-Saffar
Putra Jaya, Ramadhansyah
Effects of nano eggshell powder as a sustainable bio-filler on the physical, rheological, and microstructure properties of bitumen
title Effects of nano eggshell powder as a sustainable bio-filler on the physical, rheological, and microstructure properties of bitumen
title_full Effects of nano eggshell powder as a sustainable bio-filler on the physical, rheological, and microstructure properties of bitumen
title_fullStr Effects of nano eggshell powder as a sustainable bio-filler on the physical, rheological, and microstructure properties of bitumen
title_full_unstemmed Effects of nano eggshell powder as a sustainable bio-filler on the physical, rheological, and microstructure properties of bitumen
title_short Effects of nano eggshell powder as a sustainable bio-filler on the physical, rheological, and microstructure properties of bitumen
title_sort effects of nano eggshell powder as a sustainable bio-filler on the physical, rheological, and microstructure properties of bitumen
topic TE Highway engineering. Roads and pavements
url http://eprints.uthm.edu.my/12137/1/J17692_d44db9f02db2e343ae3cbfc478bb2f72.pdf
http://eprints.uthm.edu.my/12137/
https://doi.org/10.1016/j.rineng.2024.102061
url_provider http://eprints.uthm.edu.my/