The Uv-Shielding Property Of Zr0.7ce0.3o2-Kaolinite/Exfoliated Kaolinite Composites Prepared By Differentsynthesis Methods
Kaolinite was obtained by elutriation of tin slime, which was then exfoliated by planetary ball milling with 40 wt. % of urea for 1, 3 and 5 hours. Then the kaolinite and urea-treated kaolinite samples were characterized by using XRD, XRF, SEM, FTIR, and BET. The characterization results of kaoli...
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| Language: | en |
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2013
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| Online Access: | http://eprints.usm.my/43559/1/Kry%20Nallis24.pdf http://eprints.usm.my/43559/ |
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| author | Nallis, Kry |
| author_facet | Nallis, Kry |
| author_sort | Nallis, Kry |
| building | Hamzah Sendut Library |
| collection | Institutional Repository |
| content_provider | Universiti Sains Malaysia |
| content_source | USM Institutional Repository |
| continent | Asia |
| country | Malaysia |
| description | Kaolinite was obtained by elutriation of tin slime, which was then exfoliated by
planetary ball milling with 40 wt. % of urea for 1, 3 and 5 hours. Then the kaolinite
and urea-treated kaolinite samples were characterized by using XRD, XRF, SEM,
FTIR, and BET. The characterization results of kaolinite and urea-treated kaolinite
samples for 1, 3 and 5 hours proved that kaolinite was successfully exfoliated by urea
treatment for 5 hours and the XRD result of kaolinite showed minor gibbsite and
muscovite as impurities. Composites of Zr0.7Ce0.3O2-kaolinite/exfoliated kaolinite
were prepared by three different in-situ synthesis methods and one solid mixing
method. The first in-situ synthesis method was a citric acid complexing method, with
and without NH3 added; the second in-situ synthesis method was a soft solution
chemical method; and the third in-situ synthesis method was a hydrothermal
treatment method with and without sodium oleate added. For the solid mixing
method, Zr0.7Ce0.3O2, which was prepared by the three different synthesis methods
such as a citric acid complexing method without NH3 added, a soft solution chemical
method and a hydrothermal treatment without sodium oleate added, was solid mixed
with kaolinite/exfoliated kaolinite using an agate mortar and pestle. The resulting
composites were characterized by using XRD, FESEM and UV-Vis. |
| format | Thesis |
| id | my.usm.eprints.43559 |
| institution | Universiti Sains Malaysia |
| language | en |
| publishDate | 2013 |
| record_format | eprints |
| spelling | my.usm.eprints.43559 http://eprints.usm.my/43559/ The Uv-Shielding Property Of Zr0.7ce0.3o2-Kaolinite/Exfoliated Kaolinite Composites Prepared By Differentsynthesis Methods Nallis, Kry TN1-997 Mining engineering. Metallurgy Kaolinite was obtained by elutriation of tin slime, which was then exfoliated by planetary ball milling with 40 wt. % of urea for 1, 3 and 5 hours. Then the kaolinite and urea-treated kaolinite samples were characterized by using XRD, XRF, SEM, FTIR, and BET. The characterization results of kaolinite and urea-treated kaolinite samples for 1, 3 and 5 hours proved that kaolinite was successfully exfoliated by urea treatment for 5 hours and the XRD result of kaolinite showed minor gibbsite and muscovite as impurities. Composites of Zr0.7Ce0.3O2-kaolinite/exfoliated kaolinite were prepared by three different in-situ synthesis methods and one solid mixing method. The first in-situ synthesis method was a citric acid complexing method, with and without NH3 added; the second in-situ synthesis method was a soft solution chemical method; and the third in-situ synthesis method was a hydrothermal treatment method with and without sodium oleate added. For the solid mixing method, Zr0.7Ce0.3O2, which was prepared by the three different synthesis methods such as a citric acid complexing method without NH3 added, a soft solution chemical method and a hydrothermal treatment without sodium oleate added, was solid mixed with kaolinite/exfoliated kaolinite using an agate mortar and pestle. The resulting composites were characterized by using XRD, FESEM and UV-Vis. 2013-05 Thesis NonPeerReviewed application/pdf en http://eprints.usm.my/43559/1/Kry%20Nallis24.pdf Nallis, Kry (2013) The Uv-Shielding Property Of Zr0.7ce0.3o2-Kaolinite/Exfoliated Kaolinite Composites Prepared By Differentsynthesis Methods. PhD thesis, Universiti Sains Malaysia. |
| spellingShingle | TN1-997 Mining engineering. Metallurgy Nallis, Kry The Uv-Shielding Property Of Zr0.7ce0.3o2-Kaolinite/Exfoliated Kaolinite Composites Prepared By Differentsynthesis Methods |
| title | The Uv-Shielding Property Of
Zr0.7ce0.3o2-Kaolinite/Exfoliated Kaolinite
Composites Prepared By Differentsynthesis
Methods |
| title_full | The Uv-Shielding Property Of
Zr0.7ce0.3o2-Kaolinite/Exfoliated Kaolinite
Composites Prepared By Differentsynthesis
Methods |
| title_fullStr | The Uv-Shielding Property Of
Zr0.7ce0.3o2-Kaolinite/Exfoliated Kaolinite
Composites Prepared By Differentsynthesis
Methods |
| title_full_unstemmed | The Uv-Shielding Property Of
Zr0.7ce0.3o2-Kaolinite/Exfoliated Kaolinite
Composites Prepared By Differentsynthesis
Methods |
| title_short | The Uv-Shielding Property Of
Zr0.7ce0.3o2-Kaolinite/Exfoliated Kaolinite
Composites Prepared By Differentsynthesis
Methods |
| title_sort | uv-shielding property of
zr0.7ce0.3o2-kaolinite/exfoliated kaolinite
composites prepared by differentsynthesis
methods |
| topic | TN1-997 Mining engineering. Metallurgy |
| url | http://eprints.usm.my/43559/1/Kry%20Nallis24.pdf http://eprints.usm.my/43559/ |
| url_provider | http://eprints.usm.my/ |