Synthesis,characterization and reactivity of mixed-metal cluster carbonyls.
Series of RU3(CO)g(arphos)(L) complexes where L = PCY3. PPh3. P(C6H4F-mh, P(C6H4F-ph. P(C6H4CIph and PPh(C6H40Me-ph. and complexes of the type LAuCI where L= AS(C 21H2rP). AS(C21H21-m), Ph2As(CH2hAsPh2 and As(C30H21 ) were synthesized and characterized by spectroscopic and analytical techniques. The...
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Universiti Sains Malaysia
2017
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| Online Access: | http://eprints.usm.my/36889/ |
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| _version_ | 1834501083891761152 |
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| author | Shawkataly, Omar |
| author_facet | Shawkataly, Omar |
| author_sort | Shawkataly, Omar |
| building | Hamzah Sendut Library |
| collection | Institutional Repository |
| content_provider | Universiti Sains Malaysia |
| content_source | USM Institutional Repository |
| continent | Asia |
| country | Malaysia |
| description | Series of RU3(CO)g(arphos)(L) complexes where L = PCY3. PPh3. P(C6H4F-mh, P(C6H4F-ph. P(C6H4CIph and PPh(C6H40Me-ph. and complexes of the type LAuCI where L= AS(C 21H2rP). AS(C21H21-m), Ph2As(CH2hAsPh2 and As(C30H21 ) were synthesized and characterized by spectroscopic and analytical techniques. The molecular structures of complexes have been determined by single X-ray diffraction analysis. The geometry structural and reactivity of the complexes are discussed. The elongation of Ru-Ru bonds within the RU3(CO)g(arphos)(L)is controlled by steric interaction between the group 15 monodentate ligand and CO on the adjacent Ru atom. Besides, the electronic effects accounting for this phenomenon are discussed. The Ru-P bond lengths can be attributed to the different electronic and the size of the cone angle.
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| format | Monograph |
| id | my.usm.eprints.36889 |
| institution | Universiti Sains Malaysia |
| publishDate | 2017 |
| publisher | Universiti Sains Malaysia |
| record_format | eprints |
| spelling | my.usm.eprints.36889 http://eprints.usm.my/36889/ Synthesis,characterization and reactivity of mixed-metal cluster carbonyls. Shawkataly, Omar LC5800-5808 Distance education. Series of RU3(CO)g(arphos)(L) complexes where L = PCY3. PPh3. P(C6H4F-mh, P(C6H4F-ph. P(C6H4CIph and PPh(C6H40Me-ph. and complexes of the type LAuCI where L= AS(C 21H2rP). AS(C21H21-m), Ph2As(CH2hAsPh2 and As(C30H21 ) were synthesized and characterized by spectroscopic and analytical techniques. The molecular structures of complexes have been determined by single X-ray diffraction analysis. The geometry structural and reactivity of the complexes are discussed. The elongation of Ru-Ru bonds within the RU3(CO)g(arphos)(L)is controlled by steric interaction between the group 15 monodentate ligand and CO on the adjacent Ru atom. Besides, the electronic effects accounting for this phenomenon are discussed. The Ru-P bond lengths can be attributed to the different electronic and the size of the cone angle. Universiti Sains Malaysia 2017 Monograph NonPeerReviewed Shawkataly, Omar (2017) Synthesis,characterization and reactivity of mixed-metal cluster carbonyls. Technical Report. Universiti Sains Malaysia. |
| spellingShingle | LC5800-5808 Distance education. Shawkataly, Omar Synthesis,characterization and reactivity of mixed-metal cluster carbonyls. |
| title | Synthesis,characterization and reactivity of mixed-metal cluster carbonyls. |
| title_full | Synthesis,characterization and reactivity of mixed-metal cluster carbonyls. |
| title_fullStr | Synthesis,characterization and reactivity of mixed-metal cluster carbonyls. |
| title_full_unstemmed | Synthesis,characterization and reactivity of mixed-metal cluster carbonyls. |
| title_short | Synthesis,characterization and reactivity of mixed-metal cluster carbonyls. |
| title_sort | synthesis,characterization and reactivity of mixed-metal cluster carbonyls. |
| topic | LC5800-5808 Distance education. |
| url | http://eprints.usm.my/36889/ |
| url_provider | http://eprints.usm.my/ |