Effect of clay composite derived hydroxyapatite on activated carbon for biogas production

Hydroxyapatite (HAp), a calcium phosphate-based nanomaterial, has gained significant attention due to its exceptional biocompatibility. The integration of HAp into Clay-Hydroxyapatite with activated carbon (CHAp) composite offers a novel solution to improve microbial retention, biofilm formation,...

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Bibliographic Details
Main Authors: Jamali, N. S., Ismail, S. F., Ibrahim, M. F., Che Man, H., Wan Abdul Karim Ghani, W. A., Abdul Rashid, S.
Format: Conference or Workshop Item
Language:en
Published: 2025
Subjects:
Online Access:http://psasir.upm.edu.my/id/eprint/123545/1/123545.pdf
http://psasir.upm.edu.my/id/eprint/123545/
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Summary:Hydroxyapatite (HAp), a calcium phosphate-based nanomaterial, has gained significant attention due to its exceptional biocompatibility. The integration of HAp into Clay-Hydroxyapatite with activated carbon (CHAp) composite offers a novel solution to improve microbial retention, biofilm formation, and overall process stability in biomethane production systems. This study evaluates the effects of clay-hydroxyapatite as bio-media for biomethane production and biofilm formation within a Sequencing Batch Reactor (SBR). The fermentation process utilized synthetic media and cattle dung at 37°C with a hydraulic retention time of 40 days and assessed the effect of CHAp influences microbial performance in Scanning Electron Microscopy (SEM). The results indicated that formulated CHAp achieving a methane productivity rate of 15.9 mmol CH4/L·d, 344 mL/L.d and a methane yield of 8.32 mol CH4/mol TC. The carrier shows stabilization and indicate the capability of bacteria to stabilize from control (229.2 mL/L.d) to formulated CHAp media (344.4 mL/L.d) for biogas production rate and 292.2 mL/L.d to 388.9 mL/L.d to methane production rate, along with biofilm growth from 23.9 g/g CHAp to 44.4 g/g CHAp, when the HRT was reduced from 40 to 14 days. SEM images confirmed the presence of methanogenic microorganisms and this formulation is promising for enhancing biomethane production in SBR systems.