Ruthenium oxide: a near 0.8 µm epsilon-near-zero medium for multipurpose nonlinear photonics
The intriguing optical response associated with the vanishingly small dielectric primitivity in epsilon-near-zero (ENZ) materials has offered unprecedented opportunities for photonics. Due to the high-limit of doping concentration, current homogeneous ENZ materials based on heavily doped conductive...
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| Main Authors: | , , , , , , , , , , , , |
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| Format: | Article |
| Published: |
John Wiley and Sons Inc
2025
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| Subjects: | |
| Online Access: | http://psasir.upm.edu.my/id/eprint/122412/ https://onlinelibrary.wiley.com/doi/10.1002/lpor.202401181 |
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| Summary: | The intriguing optical response associated with the vanishingly small dielectric primitivity in epsilon-near-zero (ENZ) materials has offered unprecedented opportunities for photonics. Due to the high-limit of doping concentration, current homogeneous ENZ materials based on heavily doped conductive oxide including ITO usually exhibit a zero-permittivity wavelength (λ0) longer than 1200 nm. Here, this is identified with combined theoretical and experimental investigations that stoichiometric rutile-type RuO2 (r-RuO2) exhibits the shortest λ0 of near 800 nm among conductive oxides, benefiting from the high free electron concentration with characteristic Drude-type response. The ENZ effect is manifested by the strong field enhancement and the large nonlinear optical (NLO) response in colloidal processed r-RuO2 nanoparticles (NPs) and thin films. By ultrafast transient spectroscopy, the strong NLO response in r-RuO2 NPs is revealed to be the result of rapid thermalization/cooling of free electrons in the strong hybridized Ru-4d/O-2p orbitals. The ultrafast optical nonlinearity is exploited further for the development of multi-purpose all-optical switches that enable stable pulse laser generation in four mode-locked and Q-switched fiber lasers. Our results underscore the potential of stoichiometric metallic metal oxides as alternative ENZ materials for nonlinear photonics applications in the visible and NIR regions. |
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