Adsorption isotherms and kinetic studies of nitrogen-doped porous carbon by sodium amide activation from natural rubber for CO2 capture
This study seeks to provide straightforward and renewable nitrogen-doped porous carbonaceous adsorbents with superior carbon dioxide (CO2) adsorption capabilities. Nitrogen-enriched porous carbons were synthesised using a single-step sodium amide activation of carbonized natural rubber. The activati...
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| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | en |
| Published: |
Elsevier
2025
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| Online Access: | http://psasir.upm.edu.my/id/eprint/120620/1/120620.pdf http://psasir.upm.edu.my/id/eprint/120620/ https://linkinghub.elsevier.com/retrieve/pii/S0254058425007047 |
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| Summary: | This study seeks to provide straightforward and renewable nitrogen-doped porous carbonaceous adsorbents with superior carbon dioxide (CO2) adsorption capabilities. Nitrogen-enriched porous carbons were synthesised using a single-step sodium amide activation of carbonized natural rubber. The activation temperature of the adsorbent (400–600 °C) and the AC/NaNH2 ratios (1:1–1:4) were applied to optimize the pore shape and nitrogen concentration for enhanced CO2 adsorption performance. The optimal sample, NRAC-NaNH2-600-2, had the maximum CO2 adsorption capacity of 2.95 mmol/g at 25 °C and 1 bar. The ideal sample demonstrated reusability for up to 8 consecutive cycles, exhibiting remarkable stability with only a 5.5 % in adsorption capacity compared to the initial. Two parameters were identified: specific surface area and nitrogen content, which significantly influence the CO2 adsorption capability of these adsorbents. The CO2 adsorption isotherm at 25 °C was evaluated using the Freundlich isotherm model, which exhibited the best fit (R2 = 0.9856), indicating multilayer adsorption on a heterogeneous surface. Additionally, the adsorption kinetic data were well fitted to the pseudo-first-order kinetic which deduce physical adsorption dominated during the CO2 loading. This research may foster novel concepts for nitrogen-doped adsorbents characterized by low activation temperatures, renewable precursors as a potential CO2 adsorption material. |
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