Spin-coated high mobility MoO3 thin film for designing highly efficient lead-free perovskite solar cells
Among the thin film-photovoltaics, perovskite solar cells (PSCs) are one of the most developing topics of research in recent times. Research records reveal that around 26 % efficiency in PSCs has already been achieved so far. However, the commercialization of those PSCs is hindered due to the toxici...
Saved in:
| Main Authors: | , , , , , , , |
|---|---|
| Other Authors: | |
| Format: | Article |
| Published: |
Elsevier Ltd
2025
|
| Subjects: | |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1833351670959964160 |
|---|---|
| author | Islam M.A. Siddiquee I.A. Wahab Y.A. Hatta S.F.W. Imam J.M. Low F.W. Ahamed A. Alam M.N.-E. |
| author2 | 57220973693 |
| author_facet | 57220973693 Islam M.A. Siddiquee I.A. Wahab Y.A. Hatta S.F.W. Imam J.M. Low F.W. Ahamed A. Alam M.N.-E. |
| author_sort | Islam M.A. |
| building | UNITEN Library |
| collection | Institutional Repository |
| content_provider | Universiti Tenaga Nasional |
| content_source | UNITEN Institutional Repository |
| continent | Asia |
| country | Malaysia |
| description | Among the thin film-photovoltaics, perovskite solar cells (PSCs) are one of the most developing topics of research in recent times. Research records reveal that around 26 % efficiency in PSCs has already been achieved so far. However, the commercialization of those PSCs is hindered due to the toxicity of lead (Pb), and the instability of organic cations as well as structural volatility. Several inorganic materials including inorganic hole transport layer (HTL) have recently been proposed and developed to reduce the organic part in the device structure. We fabricate MoO3 thin film materials and conduct a detailed study to realize the potential of MoO3 as a unique HTL for application in PSCs. The synthesis of MoO3 thin film includes several characterization techniques e.g. XRD, FESEM, EDX, UV?Vis, and Hall Effect measurement. We design a MoO3 thin film-based, lead-free PSC structure of FTO/MoO3/PTAA/(FA)2BiCuI6/ZnO/Ag and perform numerical analysis using the SCAPS-1D simulation tool. In the device simulation process, we use the experimentally obtained optoelectrical properties of the MoO3 film and achieve a maximum efficiency of around 22.28 % in a contained lead-free PSC. ? 2024 The Author(s) |
| format | Article |
| id | my.uniten.dspace-36536 |
| institution | Universiti Tenaga Nasional |
| publishDate | 2025 |
| publisher | Elsevier Ltd |
| record_format | dspace |
| spelling | my.uniten.dspace-365362025-03-03T15:42:56Z Spin-coated high mobility MoO3 thin film for designing highly efficient lead-free perovskite solar cells Islam M.A. Siddiquee I.A. Wahab Y.A. Hatta S.F.W. Imam J.M. Low F.W. Ahamed A. Alam M.N.-E. 57220973693 58988620000 57203353903 22634464300 58131585300 56513524700 58988047700 57189273443 Efficiency Lead compounds Molybdenum oxide Perovskite Silver compounds Solar power generation Thin films Zinc compounds Cell-be Cell/B.E Cell/BE High mobility Higher efficiency Hole transport layer layer Hole transport layers Lead-free perovskites Thin film photovoltaics Thin-films Perovskite solar cells Among the thin film-photovoltaics, perovskite solar cells (PSCs) are one of the most developing topics of research in recent times. Research records reveal that around 26 % efficiency in PSCs has already been achieved so far. However, the commercialization of those PSCs is hindered due to the toxicity of lead (Pb), and the instability of organic cations as well as structural volatility. Several inorganic materials including inorganic hole transport layer (HTL) have recently been proposed and developed to reduce the organic part in the device structure. We fabricate MoO3 thin film materials and conduct a detailed study to realize the potential of MoO3 as a unique HTL for application in PSCs. The synthesis of MoO3 thin film includes several characterization techniques e.g. XRD, FESEM, EDX, UV?Vis, and Hall Effect measurement. We design a MoO3 thin film-based, lead-free PSC structure of FTO/MoO3/PTAA/(FA)2BiCuI6/ZnO/Ag and perform numerical analysis using the SCAPS-1D simulation tool. In the device simulation process, we use the experimentally obtained optoelectrical properties of the MoO3 film and achieve a maximum efficiency of around 22.28 % in a contained lead-free PSC. ? 2024 The Author(s) Final 2025-03-03T07:42:56Z 2025-03-03T07:42:56Z 2024 Article 10.1016/j.ceramint.2024.04.111 2-s2.0-85190537600 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85190537600&doi=10.1016%2fj.ceramint.2024.04.111&partnerID=40&md5=b2cca7b06fbf037705a20892d4d78e8d https://irepository.uniten.edu.my/handle/123456789/36536 50 13 23847 23854 All Open Access; Hybrid Gold Open Access Elsevier Ltd Scopus |
| spellingShingle | Efficiency Lead compounds Molybdenum oxide Perovskite Silver compounds Solar power generation Thin films Zinc compounds Cell-be Cell/B.E Cell/BE High mobility Higher efficiency Hole transport layer layer Hole transport layers Lead-free perovskites Thin film photovoltaics Thin-films Perovskite solar cells Islam M.A. Siddiquee I.A. Wahab Y.A. Hatta S.F.W. Imam J.M. Low F.W. Ahamed A. Alam M.N.-E. Spin-coated high mobility MoO3 thin film for designing highly efficient lead-free perovskite solar cells |
| title | Spin-coated high mobility MoO3 thin film for designing highly efficient lead-free perovskite solar cells |
| title_full | Spin-coated high mobility MoO3 thin film for designing highly efficient lead-free perovskite solar cells |
| title_fullStr | Spin-coated high mobility MoO3 thin film for designing highly efficient lead-free perovskite solar cells |
| title_full_unstemmed | Spin-coated high mobility MoO3 thin film for designing highly efficient lead-free perovskite solar cells |
| title_short | Spin-coated high mobility MoO3 thin film for designing highly efficient lead-free perovskite solar cells |
| title_sort | spin-coated high mobility moo3 thin film for designing highly efficient lead-free perovskite solar cells |
| topic | Efficiency Lead compounds Molybdenum oxide Perovskite Silver compounds Solar power generation Thin films Zinc compounds Cell-be Cell/B.E Cell/BE High mobility Higher efficiency Hole transport layer layer Hole transport layers Lead-free perovskites Thin film photovoltaics Thin-films Perovskite solar cells |
| url_provider | http://dspace.uniten.edu.my/ |