Structural, morphological and optical properties of CuAl2O4 nanoparticles and their applications for photocatalytic and antibacterial activities

Nanostructured CuAl2O4 nanoparticles (NPs) were prepared by the hydrothermal method using aluminum nitrate and copper nitrate precursors. The X-ray diffraction (XRD) confirms the formation of spinel CuAl2O4 NPs. The average crystallite size of synthesized NPs decreased with increasing reaction time....

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Main Authors: Chitra V.P., Vasantharani P., Sivakumar G., Arif Dar M., Majid S.R., Rezaul Karim M., Arularasan P., Guganathan L.
Other Authors: 59149739300
Format: Article
Published: Elsevier B.V. 2025
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author Chitra V.P.
Vasantharani P.
Sivakumar G.
Arif Dar M.
Majid S.R.
Rezaul Karim M.
Arularasan P.
Guganathan L.
author2 59149739300
author_facet 59149739300
Chitra V.P.
Vasantharani P.
Sivakumar G.
Arif Dar M.
Majid S.R.
Rezaul Karim M.
Arularasan P.
Guganathan L.
author_sort Chitra V.P.
building UNITEN Library
collection Institutional Repository
content_provider Universiti Tenaga Nasional
content_source UNITEN Institutional Repository
continent Asia
country Malaysia
description Nanostructured CuAl2O4 nanoparticles (NPs) were prepared by the hydrothermal method using aluminum nitrate and copper nitrate precursors. The X-ray diffraction (XRD) confirms the formation of spinel CuAl2O4 NPs. The average crystallite size of synthesized NPs decreased with increasing reaction time. The field emission scanning electron microscopy (FESEM) and high-resolution transmission electron microscopy (HRTEM) studies revealed the cubic structure of CuAl2O4 NPs. The binding energy of Cu2+ and Al3+ ions was identified by X-ray photoelectron spectroscopy (XPS). The bandgap of synthesized NPS was found to increase with increasing reaction time. For photocatalytic measurements, the synthesized NPs were examined by degradation of Rhodamine B dye, and a maximum efficiency of 75 % was found for calcinated NPs synthesized at a reaction time of 12 h. Moreover, antibacterial activity results revealed that a better inhibition rate was found in S. aureus against human pathogenic bacteria. ? 2024 Elsevier B.V.
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institution Universiti Tenaga Nasional
publishDate 2025
publisher Elsevier B.V.
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spelling my.uniten.dspace-364232025-03-03T15:42:21Z Structural, morphological and optical properties of CuAl2O4 nanoparticles and their applications for photocatalytic and antibacterial activities Chitra V.P. Vasantharani P. Sivakumar G. Arif Dar M. Majid S.R. Rezaul Karim M. Arularasan P. Guganathan L. 59149739300 8307373100 57212122374 57225189642 7006566259 56820318000 55920228400 58876663300 Nanostructured CuAl2O4 nanoparticles (NPs) were prepared by the hydrothermal method using aluminum nitrate and copper nitrate precursors. The X-ray diffraction (XRD) confirms the formation of spinel CuAl2O4 NPs. The average crystallite size of synthesized NPs decreased with increasing reaction time. The field emission scanning electron microscopy (FESEM) and high-resolution transmission electron microscopy (HRTEM) studies revealed the cubic structure of CuAl2O4 NPs. The binding energy of Cu2+ and Al3+ ions was identified by X-ray photoelectron spectroscopy (XPS). The bandgap of synthesized NPS was found to increase with increasing reaction time. For photocatalytic measurements, the synthesized NPs were examined by degradation of Rhodamine B dye, and a maximum efficiency of 75 % was found for calcinated NPs synthesized at a reaction time of 12 h. Moreover, antibacterial activity results revealed that a better inhibition rate was found in S. aureus against human pathogenic bacteria. ? 2024 Elsevier B.V. Final 2025-03-03T07:42:21Z 2025-03-03T07:42:21Z 2024 Article 10.1016/j.inoche.2024.112658 2-s2.0-85194533210 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85194533210&doi=10.1016%2fj.inoche.2024.112658&partnerID=40&md5=db18d4d43c6af596f184b6b0434ace47 https://irepository.uniten.edu.my/handle/123456789/36423 166 112658 Elsevier B.V. Scopus
spellingShingle Chitra V.P.
Vasantharani P.
Sivakumar G.
Arif Dar M.
Majid S.R.
Rezaul Karim M.
Arularasan P.
Guganathan L.
Structural, morphological and optical properties of CuAl2O4 nanoparticles and their applications for photocatalytic and antibacterial activities
title Structural, morphological and optical properties of CuAl2O4 nanoparticles and their applications for photocatalytic and antibacterial activities
title_full Structural, morphological and optical properties of CuAl2O4 nanoparticles and their applications for photocatalytic and antibacterial activities
title_fullStr Structural, morphological and optical properties of CuAl2O4 nanoparticles and their applications for photocatalytic and antibacterial activities
title_full_unstemmed Structural, morphological and optical properties of CuAl2O4 nanoparticles and their applications for photocatalytic and antibacterial activities
title_short Structural, morphological and optical properties of CuAl2O4 nanoparticles and their applications for photocatalytic and antibacterial activities
title_sort structural, morphological and optical properties of cual2o4 nanoparticles and their applications for photocatalytic and antibacterial activities
url_provider http://dspace.uniten.edu.my/